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Effect of indifferent anions on reactions of cadmium ferrocyanide precipitation

Journal Article:

Abstract

To clarify the effect of indifferent anions on the processes of cadmium ferrocyanide precipitation the interaction in six systems of the type CdXsub(m)-Msub(4)R-Hsub(2)O (X-Cl/sup -/, CH/sub 3/COO/sup -/, SO/sub 4//sup 2 -/; M-K/sup +/, NH/sub 4//sup +/; R-(Fe(CN)/sub 6/)/sup 4 -/) is studied using the methods of physicochemical analysis (the method of residual concentrations, refractometry). Composition and formation regions of low-soluble interaction products are determined. Effect of anion X nature on interaction character is stated in the series Cl/sup -/, CH/sub 3/COO/sup -/, SO/sub 4//sup 2 -/ in mixtures with incomplete Cd/sup 2 +/ precipitation a tendency for the increase of Cd/sup 2 +/:R/sup 4 -/ ratios in precipitates formed is observed.
Authors:
Gyunner, Eh A; Mel'nichenko, L M; Vel'mozhnyj, I S [1] 
  1. Simferopol'skij Gosudarstvennyj Univ. (Ukrainian SSR)
Publication Date:
Aug 01, 1982
Product Type:
Journal Article
Reference Number:
AIX-14-753933; EDB-83-103891
Resource Relation:
Journal Name: Zh. Neorg. Khim.; (USSR); Journal Volume: 27:8; Other Information: For English translation see the journal Russian Journal of Inorganic Chemistry (UK)
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CADMIUM COMPOUNDS; PRECIPITATION; FERROCYANIDES; ACETATES; AMMONIUM COMPOUNDS; ANIONS; CADMIUM CHLORIDES; CADMIUM SULFATES; CHEMICAL COMPOSITION; POTASSIUM COMPOUNDS; QUANTITY RATIO; ALKALI METAL COMPOUNDS; CADMIUM HALIDES; CARBOXYLIC ACID SALTS; CHARGED PARTICLES; CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; IONS; IRON COMPLEXES; OXYGEN COMPOUNDS; SEPARATION PROCESSES; SULFATES; SULFUR COMPOUNDS; TRANSITION ELEMENT COMPLEXES; 400201* - Chemical & Physicochemical Properties
OSTI ID:
6058901
Country of Origin:
USSR
Language:
Russian
Other Identifying Numbers:
Journal ID: CODEN: ZNOKA
Submitting Site:
HEDB
Size:
Pages: 2022-2025
Announcement Date:

Journal Article:

Citation Formats

Gyunner, Eh A, Mel'nichenko, L M, and Vel'mozhnyj, I S. Effect of indifferent anions on reactions of cadmium ferrocyanide precipitation. USSR: N. p., 1982. Web.
Gyunner, Eh A, Mel'nichenko, L M, & Vel'mozhnyj, I S. Effect of indifferent anions on reactions of cadmium ferrocyanide precipitation. USSR.
Gyunner, Eh A, Mel'nichenko, L M, and Vel'mozhnyj, I S. 1982. "Effect of indifferent anions on reactions of cadmium ferrocyanide precipitation." USSR.
@misc{etde_6058901,
title = {Effect of indifferent anions on reactions of cadmium ferrocyanide precipitation}
author = {Gyunner, Eh A, Mel'nichenko, L M, and Vel'mozhnyj, I S}
abstractNote = {To clarify the effect of indifferent anions on the processes of cadmium ferrocyanide precipitation the interaction in six systems of the type CdXsub(m)-Msub(4)R-Hsub(2)O (X-Cl/sup -/, CH/sub 3/COO/sup -/, SO/sub 4//sup 2 -/; M-K/sup +/, NH/sub 4//sup +/; R-(Fe(CN)/sub 6/)/sup 4 -/) is studied using the methods of physicochemical analysis (the method of residual concentrations, refractometry). Composition and formation regions of low-soluble interaction products are determined. Effect of anion X nature on interaction character is stated in the series Cl/sup -/, CH/sub 3/COO/sup -/, SO/sub 4//sup 2 -/ in mixtures with incomplete Cd/sup 2 +/ precipitation a tendency for the increase of Cd/sup 2 +/:R/sup 4 -/ ratios in precipitates formed is observed.}
journal = {Zh. Neorg. Khim.; (USSR)}
volume = {27:8}
journal type = {AC}
place = {USSR}
year = {1982}
month = {Aug}
}