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Absolute rate measurement by light modulation - ESR technique

Abstract

A rate constant is deduced for the reaction of tert-butoxy radicals and trimethylsilane from the measurement of the phase shift between the modulated light source and the ESR signal of trimethylsilyl radical. The rate constant was found to be 3 x 10/sup -2/M/sup -1/. sec/sup -1/ at -50/sup 0/C.
Publication Date:
Jan 01, 1977
Product Type:
Journal Article
Reference Number:
EDB-79-132111
Resource Relation:
Journal Name: Daehan Hwahak Hwoejee; (Korea, South); Journal Volume: 21:4
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; SILANES; PHOTOLYSIS; ELECTRON SPIN RESONANCE; CHEMICAL REACTIONS; DECOMPOSITION; HYDRIDES; HYDROGEN COMPOUNDS; MAGNETIC RESONANCE; PHOTOCHEMICAL REACTIONS; RESONANCE; SILICON COMPOUNDS; 400500* - Photochemistry
OSTI ID:
6050589
Research Organizations:
Seoul National Univ., Korea
Country of Origin:
Korea, Republic of
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: DHWHA
Submitting Site:
TIC
Size:
Pages: 270-275
Announcement Date:
Nov 01, 1979

Citation Formats

Choo, K Y, and Gaspar, P P. Absolute rate measurement by light modulation - ESR technique. Korea, Republic of: N. p., 1977. Web.
Choo, K Y, & Gaspar, P P. Absolute rate measurement by light modulation - ESR technique. Korea, Republic of.
Choo, K Y, and Gaspar, P P. 1977. "Absolute rate measurement by light modulation - ESR technique." Korea, Republic of.
@misc{etde_6050589,
title = {Absolute rate measurement by light modulation - ESR technique}
author = {Choo, K Y, and Gaspar, P P}
abstractNote = {A rate constant is deduced for the reaction of tert-butoxy radicals and trimethylsilane from the measurement of the phase shift between the modulated light source and the ESR signal of trimethylsilyl radical. The rate constant was found to be 3 x 10/sup -2/M/sup -1/. sec/sup -1/ at -50/sup 0/C.}
journal = []
volume = {21:4}
journal type = {AC}
place = {Korea, Republic of}
year = {1977}
month = {Jan}
}