You need JavaScript to view this

Spectroscopic analysis of lithium hydroxide and carbonate in solid state lithium oxide

Abstract

Infrared spectra of LiOH and Li2CO3 suspended on KBr discs were measured over the concentration range 20 g/100 mg KBr to 600 g/100 mg KBr. The absorbance of a selected infrared band of each sample was carefully determined. The empirical equation, which expresses a correlation between the absorbance and the concentration, was given for each lithium compound. The feasibility of independent and direct determination of the LiOH and Li2CO3 content in Li2O was shown, and the spectroscopic technique was applied to a typical Li2O sample. It was shown that the detection limit of the analysis was improved by low-temperature measurements of the infrared spectra. (orig.).
Publication Date:
Aug 01, 1985
Product Type:
Conference
Report Number:
CONF-841246-
Reference Number:
NLN-86-000060; EDB-86-047006
Resource Relation:
Journal Name: J. Nucl. Mater.; (Netherlands); Journal Volume: 133/134; Conference: 1. international conference on fusion reactor materials, Tokyo, Japan, 3 Dec 1984
Subject:
70 PLASMA PHYSICS AND FUSION TECHNOLOGY; LITHIUM CARBONATES; INFRARED SPECTRA; LITHIUM HYDROXIDES; ABSORPTION SPECTRA; EXPERIMENTAL DATA; LITHIUM OXIDES; LOW TEMPERATURE; MATRIX MATERIALS; MEDIUM TEMPERATURE; SAMPLE PREPARATION; SUSPENSIONS; ALKALI METAL COMPOUNDS; CARBON COMPOUNDS; CARBONATES; CHALCOGENIDES; DATA; DISPERSIONS; HYDROGEN COMPOUNDS; HYDROXIDES; INFORMATION; LITHIUM COMPOUNDS; MATERIALS; NUMERICAL DATA; OXIDES; OXYGEN COMPOUNDS; SPECTRA; 700209* - Fusion Power Plant Technology- Component Development & Materials Testing
OSTI ID:
6027201
Research Organizations:
Tokyo Inst. of Tech., Japan. Research Lab. of Nuclear Reactor; National Defence Academy, Hashirimizu, Yokosuka, Japan. Dept. of Chemistry
Country of Origin:
Netherlands
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: JNUMA
Submitting Site:
HEDB
Size:
Pages: vp
Announcement Date:
Jan 01, 1986

Citation Formats

Oohira, Shigeru, Fujii, Yasuhiko, Okamoto, Makoto, Kakihana, Masato, and Nagumo, Tadashi. Spectroscopic analysis of lithium hydroxide and carbonate in solid state lithium oxide. Netherlands: N. p., 1985. Web.
Oohira, Shigeru, Fujii, Yasuhiko, Okamoto, Makoto, Kakihana, Masato, & Nagumo, Tadashi. Spectroscopic analysis of lithium hydroxide and carbonate in solid state lithium oxide. Netherlands.
Oohira, Shigeru, Fujii, Yasuhiko, Okamoto, Makoto, Kakihana, Masato, and Nagumo, Tadashi. 1985. "Spectroscopic analysis of lithium hydroxide and carbonate in solid state lithium oxide." Netherlands.
@misc{etde_6027201,
title = {Spectroscopic analysis of lithium hydroxide and carbonate in solid state lithium oxide}
author = {Oohira, Shigeru, Fujii, Yasuhiko, Okamoto, Makoto, Kakihana, Masato, and Nagumo, Tadashi}
abstractNote = {Infrared spectra of LiOH and Li2CO3 suspended on KBr discs were measured over the concentration range 20 g/100 mg KBr to 600 g/100 mg KBr. The absorbance of a selected infrared band of each sample was carefully determined. The empirical equation, which expresses a correlation between the absorbance and the concentration, was given for each lithium compound. The feasibility of independent and direct determination of the LiOH and Li2CO3 content in Li2O was shown, and the spectroscopic technique was applied to a typical Li2O sample. It was shown that the detection limit of the analysis was improved by low-temperature measurements of the infrared spectra. (orig.).}
journal = []
volume = {133/134}
place = {Netherlands}
year = {1985}
month = {Aug}
}