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Rhenium(5) and molybdenum(5) complexes with 4',4[sup (]5[sup )]-divaleryldibenzo-18-crown-6. Kompleksnye soedineniya reniya(5) i molibdena(5) s 4',4[sup (]5[sup )]-divalerildibenzo-18-kraun-6

Journal Article:

Abstract

Methods for synthesizing oxohalide complexes of rhenium and molybdenum with +5 oxidation degree with 4',4[sup (5)]-divaleryldibenzo-18-crown-6 were developed. Content and composition of prepared compounds were investigated by the methods of element analysis, crystal optics, conductometry, IR spectroscopy in the near and far regions, thermogravimetry. Oxidation degree of the complex-forming metal was determined. It was established that composition of the compounds coressponded to the general formula MOLX [sub [center dot]] H[sub 2]O, where M - Re, Mo; L -4',4[sup (5)]-divaleryldibenzo-18-crown-6; X -Cl[sup -], Br[sup -].
Authors:
Ashurova, N Kh; Yakubov, K G; Tashmukhamedova, A K; Basitova, S M [1] 
  1. Tadzhikskij Gosudarstvennyj Univ., Dushanbe (Tajikistan)
Publication Date:
Feb 01, 1993
Product Type:
Journal Article
Reference Number:
AIX-24-074079; EDB-93-150540
Resource Relation:
Journal Name: Zhurnal Neorganicheskoj Khimii; (USSR); Journal Volume: 38:2
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; MOLYBDENUM COMPLEXES; CHEMICAL PREPARATION; MOLECULAR STRUCTURE; RHENIUM COMPLEXES; CHEMICAL REACTION YIELD; CROWN ETHERS; ELECTRIC CONDUCTIVITY; INFRARED SPECTRA; OXYHALIDES; SOLUTIONS; VALENCE; COMPLEXES; DISPERSIONS; ELECTRICAL PROPERTIES; ETHERS; HALOGEN COMPOUNDS; MIXTURES; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; YIELDS; 400201* - Chemical & Physicochemical Properties
OSTI ID:
5969948
Country of Origin:
Russian Federation
Language:
Russian
Other Identifying Numbers:
Journal ID: ISSN 0044-457X; CODEN: ZNOKAQ
Submitting Site:
INIS
Size:
Pages: 278-282
Announcement Date:
Dec 01, 1993

Journal Article:

Citation Formats

Ashurova, N Kh, Yakubov, K G, Tashmukhamedova, A K, and Basitova, S M. Rhenium(5) and molybdenum(5) complexes with 4',4[sup (]5[sup )]-divaleryldibenzo-18-crown-6. Kompleksnye soedineniya reniya(5) i molibdena(5) s 4',4[sup (]5[sup )]-divalerildibenzo-18-kraun-6. Russian Federation: N. p., 1993. Web.
Ashurova, N Kh, Yakubov, K G, Tashmukhamedova, A K, & Basitova, S M. Rhenium(5) and molybdenum(5) complexes with 4',4[sup (]5[sup )]-divaleryldibenzo-18-crown-6. Kompleksnye soedineniya reniya(5) i molibdena(5) s 4',4[sup (]5[sup )]-divalerildibenzo-18-kraun-6. Russian Federation.
Ashurova, N Kh, Yakubov, K G, Tashmukhamedova, A K, and Basitova, S M. 1993. "Rhenium(5) and molybdenum(5) complexes with 4',4[sup (]5[sup )]-divaleryldibenzo-18-crown-6. Kompleksnye soedineniya reniya(5) i molibdena(5) s 4',4[sup (]5[sup )]-divalerildibenzo-18-kraun-6." Russian Federation.
@misc{etde_5969948,
title = {Rhenium(5) and molybdenum(5) complexes with 4',4[sup (]5[sup )]-divaleryldibenzo-18-crown-6. Kompleksnye soedineniya reniya(5) i molibdena(5) s 4',4[sup (]5[sup )]-divalerildibenzo-18-kraun-6}
author = {Ashurova, N Kh, Yakubov, K G, Tashmukhamedova, A K, and Basitova, S M}
abstractNote = {Methods for synthesizing oxohalide complexes of rhenium and molybdenum with +5 oxidation degree with 4',4[sup (5)]-divaleryldibenzo-18-crown-6 were developed. Content and composition of prepared compounds were investigated by the methods of element analysis, crystal optics, conductometry, IR spectroscopy in the near and far regions, thermogravimetry. Oxidation degree of the complex-forming metal was determined. It was established that composition of the compounds coressponded to the general formula MOLX [sub [center dot]] H[sub 2]O, where M - Re, Mo; L -4',4[sup (5)]-divaleryldibenzo-18-crown-6; X -Cl[sup -], Br[sup -].}
journal = {Zhurnal Neorganicheskoj Khimii; (USSR)}
volume = {38:2}
journal type = {AC}
place = {Russian Federation}
year = {1993}
month = {Feb}
}