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Solid-state interaction between nickel and YBa/sub 2/Cu/sub 3/O/sub x/

Abstract

As part of a search for suitable metals for use in composite cables made up of high-temperature superconductors in a metallic matrix, the solid-state reaction between nickel and YBa/sub 2/Cu/sub 3/O/sub x/ was studied. Green compacts of YBa/sub 2/Cu/sub 3/O/sub x/ were hot isostatically pressed (HIPed) in nickel. The microstructure, density and nature of phases present in HIPed parts were characterized. Resistivity measurements indicated that HIPed parts are not superconducting owing to the loss of oxygen and required an annealing step in oxygen for restoring superconductivity. The diffusion of nickel into YBa/sub 2/Cu/sub 3/O/sub x/ as well as the diffusion of Ba, Cu and Y into nickel was very limited. However, a thin interaction zone consisting of a nickel-rich oxide compound was formed at the Ni-YBa/sub 2/Cu/sub 3/O/sub x/ interface. The presence of such an interaction zone could have a detrimental effect on the thermal stabilization of Ni-YBa/sub 2/Cu/sub 3/O/sub x/ composite wires. 7 refs., 6 figs., 1 tab.
Publication Date:
Jan 01, 1989
Product Type:
Technical Report
Report Number:
NRCC/IMR-29447; MICROLOG-89-00580
Reference Number:
CANM-89-001798; EDB-89-100454
Subject:
36 MATERIALS SCIENCE; NICKEL; ATOM TRANSPORT; TYPE-II SUPERCONDUCTORS; HOT PRESSING; SOLID STATE PHYSICS; BARIUM OXIDES; BENCH-SCALE EXPERIMENTS; COMPOSITE MATERIALS; COPPER OXIDES; DENSITY; ELECTRIC CONDUCTIVITY; INTERFACES; MICROSTRUCTURE; PHASE STUDIES; YTTRIUM OXIDES; ALKALINE EARTH METAL COMPOUNDS; BARIUM COMPOUNDS; CHALCOGENIDES; COPPER COMPOUNDS; CRYSTAL STRUCTURE; ELECTRICAL PROPERTIES; ELEMENTS; FABRICATION; MATERIALS; MATERIALS WORKING; METALS; NEUTRAL-PARTICLE TRANSPORT; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; PHYSICS; PRESSING; RADIATION TRANSPORT; SUPERCONDUCTORS; TRANSITION ELEMENT COMPOUNDS; TRANSITION ELEMENTS; YTTRIUM COMPOUNDS; 360202* - Ceramics, Cermets, & Refractories- Structure & Phase Studies; 360204 - Ceramics, Cermets, & Refractories- Physical Properties
OSTI ID:
5929826
Research Organizations:
National Research Council of Canada, Boucherville, PQ (Canada). Industrial Materials Research Inst.
Country of Origin:
Canada
Language:
English
Availability:
Canada Institute for Scientific and Technical Information, Montreal Rd., Ottawa, ON, Canada K1A 0S2; $N/C; MF CANMET/TID, Energy, Mines and Resources Canada, 555 Booth St., Ottawa, Ont., Canada K1A 0G1; $10 CAN.
Submitting Site:
CANM
Size:
Pages: 13
Announcement Date:
May 13, 2001

Citation Formats

Champagne, B, Parent, L, and Moreau, C. Solid-state interaction between nickel and YBa/sub 2/Cu/sub 3/O/sub x/. Canada: N. p., 1989. Web.
Champagne, B, Parent, L, & Moreau, C. Solid-state interaction between nickel and YBa/sub 2/Cu/sub 3/O/sub x/. Canada.
Champagne, B, Parent, L, and Moreau, C. 1989. "Solid-state interaction between nickel and YBa/sub 2/Cu/sub 3/O/sub x/." Canada.
@misc{etde_5929826,
title = {Solid-state interaction between nickel and YBa/sub 2/Cu/sub 3/O/sub x/}
author = {Champagne, B, Parent, L, and Moreau, C}
abstractNote = {As part of a search for suitable metals for use in composite cables made up of high-temperature superconductors in a metallic matrix, the solid-state reaction between nickel and YBa/sub 2/Cu/sub 3/O/sub x/ was studied. Green compacts of YBa/sub 2/Cu/sub 3/O/sub x/ were hot isostatically pressed (HIPed) in nickel. The microstructure, density and nature of phases present in HIPed parts were characterized. Resistivity measurements indicated that HIPed parts are not superconducting owing to the loss of oxygen and required an annealing step in oxygen for restoring superconductivity. The diffusion of nickel into YBa/sub 2/Cu/sub 3/O/sub x/ as well as the diffusion of Ba, Cu and Y into nickel was very limited. However, a thin interaction zone consisting of a nickel-rich oxide compound was formed at the Ni-YBa/sub 2/Cu/sub 3/O/sub x/ interface. The presence of such an interaction zone could have a detrimental effect on the thermal stabilization of Ni-YBa/sub 2/Cu/sub 3/O/sub x/ composite wires. 7 refs., 6 figs., 1 tab.}
place = {Canada}
year = {1989}
month = {Jan}
}