You need JavaScript to view this

Roentgenographic and derivatographic investigation of gallium and indium complexes with azo compounds on the base of pyrogallol

Journal Article:

Abstract

Seven complexes of gallium and indium with N-donor ligands obtained on the base of pyrogallol are synthesized. Their chemical composition is established. Nitrogen-containing ligands and their complexes are investigated by the methods of roentgenographic and thermogravimetric analyses. It is shown that gallium and indium complexes are amorphous compounds. An assumption is made on the thermolysis character that complexes have a similar structure: structural complex nucleus constitutes a six-term chelate ring. Para-substitutors in the ligand do not participate in complexing, possibly they participate in H-bonds formation. It is established by spectrophotometric methods that in solutions stoichiometric ratio metal: ligand is the same as in the solid phase.
Publication Date:
Jan 01, 1985
Product Type:
Journal Article
Reference Number:
AIX-17-021209; EDB-86-073389
Resource Relation:
Journal Name: Zh. Neorg. Khim.; (USSR); Journal Volume: 30:1; Other Information: For English translation see the journal Russian Journal of Inorganic Chemistry (UK)
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; GALLIUM COMPLEXES; CHEMICAL PREPARATION; PYROLYSIS; INDIUM COMPLEXES; AZO COMPOUNDS; CHEMICAL BONDS; CHEMICAL COMPOSITION; COORDINATION VALENCES; LIGANDS; MOLECULAR STRUCTURE; PYROGALLOL; PYROLYSIS PRODUCTS; SOLIDS; SOLUTIONS; AROMATICS; CHEMICAL REACTIONS; COMPLEXES; DECOMPOSITION; DEVELOPERS; DISPERSIONS; HYDROXY COMPOUNDS; MIXTURES; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PHENOLS; POLYPHENOLS; SYNTHESIS; THERMOCHEMICAL PROCESSES; VALENCE; 400201* - Chemical & Physicochemical Properties; 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
OSTI ID:
5900221
Research Organizations:
Azerbajdzhanskij Gosudarstvennyj Univ., Baku, USSR
Country of Origin:
USSR
Language:
Russian
Other Identifying Numbers:
Journal ID: CODEN: ZNOKA
Submitting Site:
INIS
Size:
Pages: 72-77
Announcement Date:

Journal Article:

Citation Formats

Gambarov, D G, Rzaev, R Z, Musaev, F N, Musaeva, A N, and Chyragov, F M. Roentgenographic and derivatographic investigation of gallium and indium complexes with azo compounds on the base of pyrogallol. USSR: N. p., 1985. Web.
Gambarov, D G, Rzaev, R Z, Musaev, F N, Musaeva, A N, & Chyragov, F M. Roentgenographic and derivatographic investigation of gallium and indium complexes with azo compounds on the base of pyrogallol. USSR.
Gambarov, D G, Rzaev, R Z, Musaev, F N, Musaeva, A N, and Chyragov, F M. 1985. "Roentgenographic and derivatographic investigation of gallium and indium complexes with azo compounds on the base of pyrogallol." USSR.
@misc{etde_5900221,
title = {Roentgenographic and derivatographic investigation of gallium and indium complexes with azo compounds on the base of pyrogallol}
author = {Gambarov, D G, Rzaev, R Z, Musaev, F N, Musaeva, A N, and Chyragov, F M}
abstractNote = {Seven complexes of gallium and indium with N-donor ligands obtained on the base of pyrogallol are synthesized. Their chemical composition is established. Nitrogen-containing ligands and their complexes are investigated by the methods of roentgenographic and thermogravimetric analyses. It is shown that gallium and indium complexes are amorphous compounds. An assumption is made on the thermolysis character that complexes have a similar structure: structural complex nucleus constitutes a six-term chelate ring. Para-substitutors in the ligand do not participate in complexing, possibly they participate in H-bonds formation. It is established by spectrophotometric methods that in solutions stoichiometric ratio metal: ligand is the same as in the solid phase.}
journal = {Zh. Neorg. Khim.; (USSR)}
volume = {30:1}
journal type = {AC}
place = {USSR}
year = {1985}
month = {Jan}
}