Abstract
In Raman spectra of molybdenum pentachloride solutions in liquid chlorine lines were recorded in case of 397, 312, 410, 217 and 180 cm[sup -]1 vibrations of [nu][sub 1](A[sub 1]'), [nu][sub 2](A[sub 1]'), [nu][sub 5](E'), [nu][sub 6](E') and [nu][sub 8](E'') monomer (symmetry D[sub 3h]) molecules of MoCl[sub 5]. Interaction of molten molybdenum pentachloride with chlorine at increased (up to 6 MPa) pressures of Cl[sub 2] was studied. In Raman spectra of its vapour distillation in liquid chlorine alongside with MoCl[sub 5] lines appearance of new lines at 363 and 272 cm[sup -1], similar in their frequency to the ones calculated for the vibrations [nu][sub 1](A[sub 1g]) and [nu][sub 2](E[sub g]) of MoCl[sub 6] molecules (symmetry O[sub h]), was observed.
Citation Formats
Salyulev, A B, Vovkotrub, Eh G, and Strekalovskij, V N.
Investigation of molybdenum pentachloride interaction with chlorine. Issledovanie vzaimodejstviya pentakhlorida molibdena s khlorom.
Russian Federation: N. p.,
1993.
Web.
Salyulev, A B, Vovkotrub, Eh G, & Strekalovskij, V N.
Investigation of molybdenum pentachloride interaction with chlorine. Issledovanie vzaimodejstviya pentakhlorida molibdena s khlorom.
Russian Federation.
Salyulev, A B, Vovkotrub, Eh G, and Strekalovskij, V N.
1993.
"Investigation of molybdenum pentachloride interaction with chlorine. Issledovanie vzaimodejstviya pentakhlorida molibdena s khlorom."
Russian Federation.
@misc{etde_5866128,
title = {Investigation of molybdenum pentachloride interaction with chlorine. Issledovanie vzaimodejstviya pentakhlorida molibdena s khlorom}
author = {Salyulev, A B, Vovkotrub, Eh G, and Strekalovskij, V N}
abstractNote = {In Raman spectra of molybdenum pentachloride solutions in liquid chlorine lines were recorded in case of 397, 312, 410, 217 and 180 cm[sup -]1 vibrations of [nu][sub 1](A[sub 1]'), [nu][sub 2](A[sub 1]'), [nu][sub 5](E'), [nu][sub 6](E') and [nu][sub 8](E'') monomer (symmetry D[sub 3h]) molecules of MoCl[sub 5]. Interaction of molten molybdenum pentachloride with chlorine at increased (up to 6 MPa) pressures of Cl[sub 2] was studied. In Raman spectra of its vapour distillation in liquid chlorine alongside with MoCl[sub 5] lines appearance of new lines at 363 and 272 cm[sup -1], similar in their frequency to the ones calculated for the vibrations [nu][sub 1](A[sub 1g]) and [nu][sub 2](E[sub g]) of MoCl[sub 6] molecules (symmetry O[sub h]), was observed.}
journal = []
volume = {38:1}
journal type = {AC}
place = {Russian Federation}
year = {1993}
month = {Jan}
}
title = {Investigation of molybdenum pentachloride interaction with chlorine. Issledovanie vzaimodejstviya pentakhlorida molibdena s khlorom}
author = {Salyulev, A B, Vovkotrub, Eh G, and Strekalovskij, V N}
abstractNote = {In Raman spectra of molybdenum pentachloride solutions in liquid chlorine lines were recorded in case of 397, 312, 410, 217 and 180 cm[sup -]1 vibrations of [nu][sub 1](A[sub 1]'), [nu][sub 2](A[sub 1]'), [nu][sub 5](E'), [nu][sub 6](E') and [nu][sub 8](E'') monomer (symmetry D[sub 3h]) molecules of MoCl[sub 5]. Interaction of molten molybdenum pentachloride with chlorine at increased (up to 6 MPa) pressures of Cl[sub 2] was studied. In Raman spectra of its vapour distillation in liquid chlorine alongside with MoCl[sub 5] lines appearance of new lines at 363 and 272 cm[sup -1], similar in their frequency to the ones calculated for the vibrations [nu][sub 1](A[sub 1g]) and [nu][sub 2](E[sub g]) of MoCl[sub 6] molecules (symmetry O[sub h]), was observed.}
journal = []
volume = {38:1}
journal type = {AC}
place = {Russian Federation}
year = {1993}
month = {Jan}
}