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Structural studies on actinides carboxylates. 3. Preparation, properties and crystal structure of lithium glutarate hydrogenglutarate dioxouranate(VI)tetrahydrate UO/sub 2/(C/sub 5/H/sub 6/O/sub 4/)Li(C/sub 5/H/sub 7/O/sub 4/). 4H/sub 2/O

Abstract

The synthesis, thermal behaviour and crystal structure of lithium glutaratehydrogenglutaratedioxouranate(VI) tetrahydrate is described. The compound crystallizes in the monoclinic system, space group P2/sub 1//n. The two glutarato ligands behave differently; one is bridging the uranyl groups in infinite chains running approximately in the a axis direction, the second is bridging the uranyl and the lithium ions. The carboxylic groups are chelated on the uranium and monodentate on the lithium. The structure is linked through a network of hydrogen bonding involving water molecules and oxygen atoms from the carboxylato groups. The geometry around the uranium is approximately hexagonal bipyramidal while the lithium is tetrahedrally coordinated with one glutarate oxygen and 3 water oxygens.
Authors:
Benetollo, F; Bombieri, G; [1]  Herrero, J A; Rojas, R M
  1. Consiglio Nazionale delle Ricerche, Padua (Italy). Lab. di Chimica e Tecnologia dei Radioelementi
Publication Date:
Jan 01, 1979
Product Type:
Journal Article
Reference Number:
AIX-10-462754; EDB-79-131991
Resource Relation:
Journal Name: J. Inorg. Nucl. Chem.; (United Kingdom); Journal Volume: 41:2
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; URANYL COMPLEXES; BOND ANGLE; BOND LENGTHS; CHELATES; CHEMICAL PREPARATION; COORDINATION NUMBER; DIFFERENTIAL THERMAL ANALYSIS; EXPERIMENTAL DATA; GLUTARIC ACID; GRAPHS; HYDRATES; INFRARED SPECTRA; ISOLATED VALUES; LATTICE PARAMETERS; LIGANDS; LITHIUM COMPLEXES; MOLECULAR STRUCTURE; MONOCLINIC LATTICES; SPACE GROUPS; TABLES; THERMAL GRAVIMETRIC ANALYSIS; X-RAY DIFFRACTION; ACTINIDE COMPLEXES; CARBOXYLIC ACIDS; CHEMICAL ANALYSIS; COHERENT SCATTERING; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DATA; DATA FORMS; DICARBOXYLIC ACIDS; DIFFRACTION; GRAVIMETRIC ANALYSIS; INFORMATION; NUMERICAL DATA; ORGANIC ACIDS; ORGANIC COMPOUNDS; QUANTITATIVE CHEMICAL ANALYSIS; SCATTERING; SPECTRA; SYNTHESIS; THERMAL ANALYSIS; URANIUM COMPLEXES; 400201* - Chemical & Physicochemical Properties
OSTI ID:
5833622
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: JINCA
Submitting Site:
INIS
Size:
Pages: 195-199
Announcement Date:

Citation Formats

Benetollo, F, Bombieri, G, Herrero, J A, and Rojas, R M. Structural studies on actinides carboxylates. 3. Preparation, properties and crystal structure of lithium glutarate hydrogenglutarate dioxouranate(VI)tetrahydrate UO/sub 2/(C/sub 5/H/sub 6/O/sub 4/)Li(C/sub 5/H/sub 7/O/sub 4/). 4H/sub 2/O. United Kingdom: N. p., 1979. Web. doi:10.1016/0022-1902(79)80512-6.
Benetollo, F, Bombieri, G, Herrero, J A, & Rojas, R M. Structural studies on actinides carboxylates. 3. Preparation, properties and crystal structure of lithium glutarate hydrogenglutarate dioxouranate(VI)tetrahydrate UO/sub 2/(C/sub 5/H/sub 6/O/sub 4/)Li(C/sub 5/H/sub 7/O/sub 4/). 4H/sub 2/O. United Kingdom. doi:10.1016/0022-1902(79)80512-6.
Benetollo, F, Bombieri, G, Herrero, J A, and Rojas, R M. 1979. "Structural studies on actinides carboxylates. 3. Preparation, properties and crystal structure of lithium glutarate hydrogenglutarate dioxouranate(VI)tetrahydrate UO/sub 2/(C/sub 5/H/sub 6/O/sub 4/)Li(C/sub 5/H/sub 7/O/sub 4/). 4H/sub 2/O." United Kingdom. doi:10.1016/0022-1902(79)80512-6. https://www.osti.gov/servlets/purl/10.1016/0022-1902(79)80512-6.
@misc{etde_5833622,
title = {Structural studies on actinides carboxylates. 3. Preparation, properties and crystal structure of lithium glutarate hydrogenglutarate dioxouranate(VI)tetrahydrate UO/sub 2/(C/sub 5/H/sub 6/O/sub 4/)Li(C/sub 5/H/sub 7/O/sub 4/). 4H/sub 2/O}
author = {Benetollo, F, Bombieri, G, Herrero, J A, and Rojas, R M}
abstractNote = {The synthesis, thermal behaviour and crystal structure of lithium glutaratehydrogenglutaratedioxouranate(VI) tetrahydrate is described. The compound crystallizes in the monoclinic system, space group P2/sub 1//n. The two glutarato ligands behave differently; one is bridging the uranyl groups in infinite chains running approximately in the a axis direction, the second is bridging the uranyl and the lithium ions. The carboxylic groups are chelated on the uranium and monodentate on the lithium. The structure is linked through a network of hydrogen bonding involving water molecules and oxygen atoms from the carboxylato groups. The geometry around the uranium is approximately hexagonal bipyramidal while the lithium is tetrahedrally coordinated with one glutarate oxygen and 3 water oxygens.}
doi = {10.1016/0022-1902(79)80512-6}
journal = {J. Inorg. Nucl. Chem.; (United Kingdom)}
volume = {41:2}
journal type = {AC}
place = {United Kingdom}
year = {1979}
month = {Jan}
}