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Composition and stability of the thorium complexes with bromophenol- and bromochlorophenol blue

Abstract

Determined are composition, stability and molar quenching coefficient of thorium (4) complexes with bromophenol (BPC)- and bromochlorophenol blue (BCPB) on the basis of spectrophotometric investigations. pH medium being changed, BPC and BCPB behave as acid-base indicators. Within the range of pH values from 1.5 to 5.0 these compounds do not form coloured compounds with alkali and alkaline-earth metal ions, with copper subgroup elements, and also with La/sup 3 +/, Ca/sup 3 +/, Y/sup 3 +/, ZrO/sup 2 +/ and VO/sub 2//sup 2 +/. But interaction of sulfophthaleine with Th/sup 4 +/ is accompanied by change of solution colour. Thus, the investigated sulfophthaleines are specific reagents on Th/sup 4 +/ ions.
Publication Date:
Jan 01, 1978
Product Type:
Journal Article
Reference Number:
AIX-10-465397; EDB-80-029148
Resource Relation:
Journal Name: Zh. Neorg. Khim.; (USSR); Journal Volume: 23:1
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; THORIUM; CHEMICAL ANALYSIS; THORIUM COMPLEXES; STABILITY; CHEMICAL COMPOSITION; COLOR; INDICATORS; PH VALUE; PHENOLS; SPECTROPHOTOMETRY; SULFONATES; ACTINIDE COMPLEXES; ACTINIDES; AROMATICS; COMPLEXES; ELEMENTS; HYDROXY COMPOUNDS; METALS; OPTICAL PROPERTIES; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; ORGANOLEPTIC PROPERTIES; PHYSICAL PROPERTIES; 400100* - Analytical & Separations Chemistry
OSTI ID:
5660663
Country of Origin:
USSR
Language:
Russian
Other Identifying Numbers:
Journal ID: CODEN: ZNOKA
Submitting Site:
INIS
Size:
Pages: 121-125
Announcement Date:
Aug 01, 1979

Citation Formats

Sergeev, G M, and Korenman, I M. Composition and stability of the thorium complexes with bromophenol- and bromochlorophenol blue. USSR: N. p., 1978. Web.
Sergeev, G M, & Korenman, I M. Composition and stability of the thorium complexes with bromophenol- and bromochlorophenol blue. USSR.
Sergeev, G M, and Korenman, I M. 1978. "Composition and stability of the thorium complexes with bromophenol- and bromochlorophenol blue." USSR.
@misc{etde_5660663,
title = {Composition and stability of the thorium complexes with bromophenol- and bromochlorophenol blue}
author = {Sergeev, G M, and Korenman, I M}
abstractNote = {Determined are composition, stability and molar quenching coefficient of thorium (4) complexes with bromophenol (BPC)- and bromochlorophenol blue (BCPB) on the basis of spectrophotometric investigations. pH medium being changed, BPC and BCPB behave as acid-base indicators. Within the range of pH values from 1.5 to 5.0 these compounds do not form coloured compounds with alkali and alkaline-earth metal ions, with copper subgroup elements, and also with La/sup 3 +/, Ca/sup 3 +/, Y/sup 3 +/, ZrO/sup 2 +/ and VO/sub 2//sup 2 +/. But interaction of sulfophthaleine with Th/sup 4 +/ is accompanied by change of solution colour. Thus, the investigated sulfophthaleines are specific reagents on Th/sup 4 +/ ions.}
journal = []
volume = {23:1}
journal type = {AC}
place = {USSR}
year = {1978}
month = {Jan}
}