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Low-temperature tar and oil: properties and applications

Abstract

In Germany the value of low-temperature tar is largely dependent on its fuel fractions; these vary with the coal and the method of carbonization (external heating or recirculated gases). Brown-coal tars can be processed by distillation, cracking under pressure, hydrogenation under pressure (largest volume of tar is processed by this method) and by solvent extraction, with EtOH, SO/sub 2/, or phenol. Each of these processes is discussed in detail. In the pressure-hydrogenation process, 1.25 kilogram of brown-coal tar yields approximately 1 kilogram of gasoline with an octane number of 60 to 70. Low-temperature tars from bituminous coals can be hydrogenated readily but are not well adapted to solvent extraction. Attempts should be made to produce tar approximating the desired characteristics for fuel directly from the carbonizing apparatus. For laboratory carbonization tests, an approximation to results secured by externally heated retorts is secured by using an insert consisting of a series of perforated trays in the 200-gram Fischer aluminum retort; this reduces the capacity to 100 gram. Fractional condensation is used to separate heavy oil, middle oil, and liquor; low-boiling products are condensed at -20/sup 0/ by solid CO/sub 2/.
Authors:
Publication Date:
Jan 01, 1942
Product Type:
Journal Article
Reference Number:
EDB-80-032292
Resource Relation:
Journal Name: Gas- Wasserfach; (Germany, Federal Republic of); Journal Volume: 85
Subject:
01 COAL, LIGNITE, AND PEAT; BROWN COAL; CARBONIZATION; COAL TAR; PROCESSING; COAL TAR OILS; VAPOR CONDENSATION; GASOLINE; YIELDS; DISTILLATION; HYDROGENATION; SOLVENT EXTRACTION; THERMAL CRACKING; CARBONACEOUS MATERIALS; CHEMICAL REACTIONS; COAL; CRACKING; DECOMPOSITION; ENERGY SOURCES; EXTRACTION; FOSSIL FUELS; FUELS; OILS; ORGANIC COMPOUNDS; OTHER ORGANIC COMPOUNDS; PETROLEUM PRODUCTS; PYROLYSIS; SEPARATION PROCESSES; TAR; THERMOCHEMICAL PROCESSES; 010500* - Coal, Lignite, & Peat- Products & By-Products; 010401 - Coal & Coal Products- Carbonization- (-1987)
OSTI ID:
5538877
Country of Origin:
Germany
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: GAWFA
Submitting Site:
TIC
Size:
Pages: 413-425
Announcement Date:
Mar 01, 1980

Citation Formats

Heinze, R. Low-temperature tar and oil: properties and applications. Germany: N. p., 1942. Web.
Heinze, R. Low-temperature tar and oil: properties and applications. Germany.
Heinze, R. 1942. "Low-temperature tar and oil: properties and applications." Germany.
@misc{etde_5538877,
title = {Low-temperature tar and oil: properties and applications}
author = {Heinze, R}
abstractNote = {In Germany the value of low-temperature tar is largely dependent on its fuel fractions; these vary with the coal and the method of carbonization (external heating or recirculated gases). Brown-coal tars can be processed by distillation, cracking under pressure, hydrogenation under pressure (largest volume of tar is processed by this method) and by solvent extraction, with EtOH, SO/sub 2/, or phenol. Each of these processes is discussed in detail. In the pressure-hydrogenation process, 1.25 kilogram of brown-coal tar yields approximately 1 kilogram of gasoline with an octane number of 60 to 70. Low-temperature tars from bituminous coals can be hydrogenated readily but are not well adapted to solvent extraction. Attempts should be made to produce tar approximating the desired characteristics for fuel directly from the carbonizing apparatus. For laboratory carbonization tests, an approximation to results secured by externally heated retorts is secured by using an insert consisting of a series of perforated trays in the 200-gram Fischer aluminum retort; this reduces the capacity to 100 gram. Fractional condensation is used to separate heavy oil, middle oil, and liquor; low-boiling products are condensed at -20/sup 0/ by solid CO/sub 2/.}
journal = []
volume = {85}
journal type = {AC}
place = {Germany}
year = {1942}
month = {Jan}
}