Abstract
Complexes of piperazine with LaCl/sub 3/, CeCl/sub 3/, La(NO/sub 3/)/sub 3/, Ce(NO/sub 3/)/sub 3/, UO/sub 2/(OAc)/sub 2/, UO/sub 2/Cl/sub 2/, UO/sub 2/(NO/sub 3/)/sub 2/, UCl/sub 4/, ThCl/sub 4/ and Th(NO/sub 3/)/sub 4/ have been synthesized and characterized on the basis of elemental analyses, IR and electronic reflectance spectra and magnetic susceptibility measurements. IR data indicate (i) coordination of the ligand in the chair form (except in the case of uranyl chloride complex where at least some of the ligand molecules are present in boat conformation), (ii) coordination of the ethanol and methanol molecules and (iii) the presence of chelating bidentate acetate and nitrate groups.
Manhas, B S;
Trikha, A K;
[1]
Singh, M
[2]
- Punjabi Univ., Patiala (India). Dept. of Chemistry
- Guru Nanak Univ., Amritsar (India). Dept. of Chemistry
Citation Formats
Manhas, B S, Trikha, A K, and Singh, M.
Piperazine complexes of some lanthanides and actinides.
India: N. p.,
1981.
Web.
Manhas, B S, Trikha, A K, & Singh, M.
Piperazine complexes of some lanthanides and actinides.
India.
Manhas, B S, Trikha, A K, and Singh, M.
1981.
"Piperazine complexes of some lanthanides and actinides."
India.
@misc{etde_5530486,
title = {Piperazine complexes of some lanthanides and actinides}
author = {Manhas, B S, Trikha, A K, and Singh, M}
abstractNote = {Complexes of piperazine with LaCl/sub 3/, CeCl/sub 3/, La(NO/sub 3/)/sub 3/, Ce(NO/sub 3/)/sub 3/, UO/sub 2/(OAc)/sub 2/, UO/sub 2/Cl/sub 2/, UO/sub 2/(NO/sub 3/)/sub 2/, UCl/sub 4/, ThCl/sub 4/ and Th(NO/sub 3/)/sub 4/ have been synthesized and characterized on the basis of elemental analyses, IR and electronic reflectance spectra and magnetic susceptibility measurements. IR data indicate (i) coordination of the ligand in the chair form (except in the case of uranyl chloride complex where at least some of the ligand molecules are present in boat conformation), (ii) coordination of the ethanol and methanol molecules and (iii) the presence of chelating bidentate acetate and nitrate groups.}
journal = []
volume = {20:2}
journal type = {AC}
place = {India}
year = {1981}
month = {Feb}
}
title = {Piperazine complexes of some lanthanides and actinides}
author = {Manhas, B S, Trikha, A K, and Singh, M}
abstractNote = {Complexes of piperazine with LaCl/sub 3/, CeCl/sub 3/, La(NO/sub 3/)/sub 3/, Ce(NO/sub 3/)/sub 3/, UO/sub 2/(OAc)/sub 2/, UO/sub 2/Cl/sub 2/, UO/sub 2/(NO/sub 3/)/sub 2/, UCl/sub 4/, ThCl/sub 4/ and Th(NO/sub 3/)/sub 4/ have been synthesized and characterized on the basis of elemental analyses, IR and electronic reflectance spectra and magnetic susceptibility measurements. IR data indicate (i) coordination of the ligand in the chair form (except in the case of uranyl chloride complex where at least some of the ligand molecules are present in boat conformation), (ii) coordination of the ethanol and methanol molecules and (iii) the presence of chelating bidentate acetate and nitrate groups.}
journal = []
volume = {20:2}
journal type = {AC}
place = {India}
year = {1981}
month = {Feb}
}