You need JavaScript to view this

Influence of complexing on physicochemical properties of polymer-salt solutions. Vliyanie kompleksoobrazovaniya na fiziko-khimicheskie svojstva polimerno-solevykh rastvorov

Journal Article:

Abstract

Using the methods of spectrophotometry, viscosimetry, conductometry the influence of salt-polymer complexing processes on physicochemical prperties of aqueous solutions of yttrium, barium, copper nitrates and formates with polyvinyl alcohol was studied. Change of dynamic viscosity, specific electric conductivity of solutions in the process of complexing was shown. Thermal effects of salt-polymer interaction were measured. It is shown that decrease of transition temperature of polymer to plastic state in films, temperature and effective activation energy of salt decomposition is also connected with complexing. Effective values of surface tension on the boundary with air are measured. Coefficients of cation diffusion in polymer-salt solutions are estimated.
Authors:
Ostroushko, A A; Yushkova, S M; Koridze, N V; Skobkoreva, N V; Zhuravleva, L I; Palitskaya, T A; Antropova, S V; Ostroushko, I P [1] 
  1. Ural'skij Gosudarstvennyj Univ., Sverdlovsk (Russian Federation) AN SSSR, Moscow (Russian Federation). Inst. Obshchej i Neorganicheskoj Khimii
Publication Date:
Jun 01, 1993
Product Type:
Journal Article
Reference Number:
AIX-25-017035; EDB-94-038449
Resource Relation:
Journal Name: Zhurnal Neorganicheskoj Khimii; (Russian Federation); Journal Volume: 38:6
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; YTTRIUM COMPOUNDS; CHEMICAL REACTIONS; ACTIVATION ENERGY; AQUEOUS SOLUTIONS; BARIUM COMPOUNDS; COPPER COMPOUNDS; DECOMPOSITION; DIFFUSION; ELECTRIC CONDUCTIVITY; FORMATES; MIXING HEAT; NITRATES; PH VALUE; PVA; SPECTROPHOTOMETRY; VISCOSITY; ALCOHOLS; ALKALINE EARTH METAL COMPOUNDS; CARBOXYLIC ACID SALTS; DISPERSIONS; ELECTRICAL PROPERTIES; ENERGY; ENTHALPY; HYDROXY COMPOUNDS; MIXTURES; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC POLYMERS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; POLYMERS; POLYVINYLS; SOLUTIONS; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPOUNDS; 400201* - Chemical & Physicochemical Properties
OSTI ID:
5493923
Country of Origin:
Russian Federation
Language:
Russian
Other Identifying Numbers:
Journal ID: ISSN 0044-457X; CODEN: ZNOKAQ
Submitting Site:
INIS
Size:
Pages: 1081-1084
Announcement Date:
Mar 15, 1994

Journal Article:

Citation Formats

Ostroushko, A A, Yushkova, S M, Koridze, N V, Skobkoreva, N V, Zhuravleva, L I, Palitskaya, T A, Antropova, S V, and Ostroushko, I P. Influence of complexing on physicochemical properties of polymer-salt solutions. Vliyanie kompleksoobrazovaniya na fiziko-khimicheskie svojstva polimerno-solevykh rastvorov. Russian Federation: N. p., 1993. Web.
Ostroushko, A A, Yushkova, S M, Koridze, N V, Skobkoreva, N V, Zhuravleva, L I, Palitskaya, T A, Antropova, S V, & Ostroushko, I P. Influence of complexing on physicochemical properties of polymer-salt solutions. Vliyanie kompleksoobrazovaniya na fiziko-khimicheskie svojstva polimerno-solevykh rastvorov. Russian Federation.
Ostroushko, A A, Yushkova, S M, Koridze, N V, Skobkoreva, N V, Zhuravleva, L I, Palitskaya, T A, Antropova, S V, and Ostroushko, I P. 1993. "Influence of complexing on physicochemical properties of polymer-salt solutions. Vliyanie kompleksoobrazovaniya na fiziko-khimicheskie svojstva polimerno-solevykh rastvorov." Russian Federation.
@misc{etde_5493923,
title = {Influence of complexing on physicochemical properties of polymer-salt solutions. Vliyanie kompleksoobrazovaniya na fiziko-khimicheskie svojstva polimerno-solevykh rastvorov}
author = {Ostroushko, A A, Yushkova, S M, Koridze, N V, Skobkoreva, N V, Zhuravleva, L I, Palitskaya, T A, Antropova, S V, and Ostroushko, I P}
abstractNote = {Using the methods of spectrophotometry, viscosimetry, conductometry the influence of salt-polymer complexing processes on physicochemical prperties of aqueous solutions of yttrium, barium, copper nitrates and formates with polyvinyl alcohol was studied. Change of dynamic viscosity, specific electric conductivity of solutions in the process of complexing was shown. Thermal effects of salt-polymer interaction were measured. It is shown that decrease of transition temperature of polymer to plastic state in films, temperature and effective activation energy of salt decomposition is also connected with complexing. Effective values of surface tension on the boundary with air are measured. Coefficients of cation diffusion in polymer-salt solutions are estimated.}
journal = {Zhurnal Neorganicheskoj Khimii; (Russian Federation)}
volume = {38:6}
journal type = {AC}
place = {Russian Federation}
year = {1993}
month = {Jun}
}