Abstract
The thermal unimolecular decomposition of methanol and that of acetone (1B) were investigated experimentally after reflected shockwaves, by following up the OH and CH/sub 3/ absorption or the CH/sub 3/ and acetone absorption respectively. A computer simulation of the decomposition of methanol and the subsequent reactions was done. This gave velocity constants for some reactions, which are different from those that are found in the literature. The experimental investigation of the decomposition of acetone, from comparison of the results with the data in the literature, shows that the observations of CH/sub 3/ absorption are very suitable for obtaining velocity constants for decomposition reactions, where CH/sub 3/ radicals are formed in the first stage.
Citation Formats
Spindler, K.
Thermal unimolecular decomposition of methanol. Zum thermischen unimolekularen Zerfall von Methanol.
Germany: N. p.,
1979.
Web.
Spindler, K.
Thermal unimolecular decomposition of methanol. Zum thermischen unimolekularen Zerfall von Methanol.
Germany.
Spindler, K.
1979.
"Thermal unimolecular decomposition of methanol. Zum thermischen unimolekularen Zerfall von Methanol."
Germany.
@misc{etde_5465752,
title = {Thermal unimolecular decomposition of methanol. Zum thermischen unimolekularen Zerfall von Methanol}
author = {Spindler, K}
abstractNote = {The thermal unimolecular decomposition of methanol and that of acetone (1B) were investigated experimentally after reflected shockwaves, by following up the OH and CH/sub 3/ absorption or the CH/sub 3/ and acetone absorption respectively. A computer simulation of the decomposition of methanol and the subsequent reactions was done. This gave velocity constants for some reactions, which are different from those that are found in the literature. The experimental investigation of the decomposition of acetone, from comparison of the results with the data in the literature, shows that the observations of CH/sub 3/ absorption are very suitable for obtaining velocity constants for decomposition reactions, where CH/sub 3/ radicals are formed in the first stage.}
place = {Germany}
year = {1979}
month = {Jan}
}
title = {Thermal unimolecular decomposition of methanol. Zum thermischen unimolekularen Zerfall von Methanol}
author = {Spindler, K}
abstractNote = {The thermal unimolecular decomposition of methanol and that of acetone (1B) were investigated experimentally after reflected shockwaves, by following up the OH and CH/sub 3/ absorption or the CH/sub 3/ and acetone absorption respectively. A computer simulation of the decomposition of methanol and the subsequent reactions was done. This gave velocity constants for some reactions, which are different from those that are found in the literature. The experimental investigation of the decomposition of acetone, from comparison of the results with the data in the literature, shows that the observations of CH/sub 3/ absorption are very suitable for obtaining velocity constants for decomposition reactions, where CH/sub 3/ radicals are formed in the first stage.}
place = {Germany}
year = {1979}
month = {Jan}
}