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ETDEWEB   /       /    Photochemistry of U(BH/sub 4/)/sub 4/ and U(BD/sub 4/)/sub 4/

Photochemistry of U(BH/sub 4/)/sub 4/ and U(BD/sub 4/)/sub 4/

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Abstract

U(BH/sub 4/)/sub 4/ and U(BD/sub 4/)/sub 4/ are observed to undergo complex degradation reactions promoted by broadband UV radiation. The primary products of these reactions appear to be U(BH/sub 4/)/sub 3/, B/sub 2/H/sub 6/, H/sub 2/, U(BD/sub 4/)/sub 3/, B/sub 2/D/sub 6/ and D/sub 2/. Further, U(BD/sub 4/)/sub 4/ undergoes a related decomposition reaction under the influence of CO/sub 2/ laser irradiation at 924.97 cm/sup -1/.
Authors:
Paine, R T; Schonberg, P R; Light, R W; [1]  Danen, W C; Freund, S M
  1. New Mexico Univ., Albuquerque (USA). Dept. of Chemistry
Publication Date:
Jan 01, 1979
DOI:
https://doi.org/10.1016/0022-1902(79)80179-7
Product Type:
Journal Article
Reference Number:
AIX-11-504676; EDB-80-072197
Resource Relation:
Journal Name: J. Inorg. Nucl. Chem.; (United Kingdom); Journal Volume: 41:11
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; URANIUM COMPOUNDS; PHOTOLYSIS; BOROHYDRIDES; DEUTERIUM COMPOUNDS; INFRARED RADIATION; LASER RADIATION; ULTRAVIOLET RADIATION; ACTINIDE COMPOUNDS; BORON COMPOUNDS; CHEMICAL REACTIONS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; HYDROGEN COMPOUNDS; PHOTOCHEMICAL REACTIONS; RADIATIONS; 400702* - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials
OSTI ID:
5454578
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: JINCA
Submitting Site:
INIS
Size:
Pages: 1577-1578
Announcement Date:
May 01, 1980

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Citation Formats

Paine, R T, Schonberg, P R, Light, R W, Danen, W C, and Freund, S M. Photochemistry of U(BH/sub 4/)/sub 4/ and U(BD/sub 4/)/sub 4/. United Kingdom: N. p., 1979. Web. doi:10.1016/0022-1902(79)80179-7.
Paine, R T, Schonberg, P R, Light, R W, Danen, W C, & Freund, S M. Photochemistry of U(BH/sub 4/)/sub 4/ and U(BD/sub 4/)/sub 4/. United Kingdom. https://doi.org/10.1016/0022-1902(79)80179-7
Paine, R T, Schonberg, P R, Light, R W, Danen, W C, and Freund, S M. 1979. "Photochemistry of U(BH/sub 4/)/sub 4/ and U(BD/sub 4/)/sub 4/." United Kingdom. https://doi.org/10.1016/0022-1902(79)80179-7.
@misc{etde_5454578,
title = {Photochemistry of U(BH/sub 4/)/sub 4/ and U(BD/sub 4/)/sub 4/}
 author = {Paine, R T, Schonberg, P R, Light, R W, Danen, W C, and Freund, S M}
 abstractNote = {U(BH/sub 4/)/sub 4/ and U(BD/sub 4/)/sub 4/ are observed to undergo complex degradation reactions promoted by broadband UV radiation. The primary products of these reactions appear to be U(BH/sub 4/)/sub 3/, B/sub 2/H/sub 6/, H/sub 2/, U(BD/sub 4/)/sub 3/, B/sub 2/D/sub 6/ and D/sub 2/. Further, U(BD/sub 4/)/sub 4/ undergoes a related decomposition reaction under the influence of CO/sub 2/ laser irradiation at 924.97 cm/sup -1/.}
 doi = {10.1016/0022-1902(79)80179-7}
 journal = []
 volume = {41:11}
 journal type = {AC}
 place = {United Kingdom}
 year = {1979}
 month = {Jan}
 }