Abstract
Intercalation can be applied to cathode reaction of rechargeable battery. Three kinds of candidate materials, TiS{sub 2}, NbS{sub 3} and alkali transition metal dioxides such as LiCoO{sub 2} were studied as the battery cathode. TiS{sub 2} is closest to a practical usage. Lithium ion has to diffuse in the TiS{sub 2} crystal lattice during the intercalation. Large surface area is necessary to obtain high current density. Preferred orientation of the crystallite is also required in its film formation to further enhance its current density. CVD reactor was used to obtain TiS{sub 2} fine powder and its thin film. Black fine power was obtained on a thin film deposited on a glass substrate. The powder was obtained in high yield under a pressure of 120 Pa at the electrode center where the plasma density was high. In conclusion, TiS{sub 2} fine power with submicron diameter and also highly preferred oriented TiS{sub 2} thin film were obtained using plasma-CVD. 21 refs., 8 figs.
Kikkawa, Shin'ichi
[1]
- Osaka Univ. (Japan)
Citation Formats
Kikkawa, Shin'ichi.
New materials for advanced lithium battery. Especially on plasma-assisted CVD of TiS sub 2.
Japan: N. p.,
1989.
Web.
Kikkawa, Shin'ichi.
New materials for advanced lithium battery. Especially on plasma-assisted CVD of TiS sub 2.
Japan.
Kikkawa, Shin'ichi.
1989.
"New materials for advanced lithium battery. Especially on plasma-assisted CVD of TiS sub 2."
Japan.
@misc{etde_5381634,
title = {New materials for advanced lithium battery. Especially on plasma-assisted CVD of TiS sub 2}
author = {Kikkawa, Shin'ichi}
abstractNote = {Intercalation can be applied to cathode reaction of rechargeable battery. Three kinds of candidate materials, TiS{sub 2}, NbS{sub 3} and alkali transition metal dioxides such as LiCoO{sub 2} were studied as the battery cathode. TiS{sub 2} is closest to a practical usage. Lithium ion has to diffuse in the TiS{sub 2} crystal lattice during the intercalation. Large surface area is necessary to obtain high current density. Preferred orientation of the crystallite is also required in its film formation to further enhance its current density. CVD reactor was used to obtain TiS{sub 2} fine powder and its thin film. Black fine power was obtained on a thin film deposited on a glass substrate. The powder was obtained in high yield under a pressure of 120 Pa at the electrode center where the plasma density was high. In conclusion, TiS{sub 2} fine power with submicron diameter and also highly preferred oriented TiS{sub 2} thin film were obtained using plasma-CVD. 21 refs., 8 figs.}
journal = []
volume = {46}
journal type = {AC}
place = {Japan}
year = {1989}
month = {Mar}
}
title = {New materials for advanced lithium battery. Especially on plasma-assisted CVD of TiS sub 2}
author = {Kikkawa, Shin'ichi}
abstractNote = {Intercalation can be applied to cathode reaction of rechargeable battery. Three kinds of candidate materials, TiS{sub 2}, NbS{sub 3} and alkali transition metal dioxides such as LiCoO{sub 2} were studied as the battery cathode. TiS{sub 2} is closest to a practical usage. Lithium ion has to diffuse in the TiS{sub 2} crystal lattice during the intercalation. Large surface area is necessary to obtain high current density. Preferred orientation of the crystallite is also required in its film formation to further enhance its current density. CVD reactor was used to obtain TiS{sub 2} fine powder and its thin film. Black fine power was obtained on a thin film deposited on a glass substrate. The powder was obtained in high yield under a pressure of 120 Pa at the electrode center where the plasma density was high. In conclusion, TiS{sub 2} fine power with submicron diameter and also highly preferred oriented TiS{sub 2} thin film were obtained using plasma-CVD. 21 refs., 8 figs.}
journal = []
volume = {46}
journal type = {AC}
place = {Japan}
year = {1989}
month = {Mar}
}