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Structure of tetrakis(salicylaldehydato)thorium(IV)

Abstract

The structure of tetrakis(salicylaldehydato)thorium(IV) has been determined by single crystal X-ray crystallography. The crystals are tetragonal, a = 10.214, b = 23.744 A, space group P4/sub 1/. The molecules are eight coordinate, the coordination polyhedron being a dodecahedron with approximate Dsub(2d) symmetry. The dodecahedral A sites are occupied by the aldehydic oxygens and the phenolic oxygens occupy the B sites.
Authors:
Hill, R J; Rickard, C E.F. [1] 
  1. Auckland Univ. (New Zealand). Dept. of Chemistry
Publication Date:
Jan 01, 1977
Product Type:
Journal Article
Reference Number:
AIX-08-346238; EDB-78-028031
Resource Relation:
Journal Name: J. Inorg. Nucl. Chem.; (United Kingdom); Journal Volume: 39:9
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; THORIUM COMPLEXES; LATTICE PARAMETERS; MOLECULAR STRUCTURE; ALDEHYDES; COORDINATION NUMBER; LIGANDS; SALICYLIC ACID; TETRAGONAL LATTICES; X-RAY DIFFRACTION; ACTINIDE COMPLEXES; CARBOXYLIC ACIDS; COHERENT SCATTERING; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; HYDROXY ACIDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; SCATTERING; 400702* - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials
OSTI ID:
5335174
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: JINCA
Submitting Site:
INIS
Size:
Pages: 1593-1596
Announcement Date:
Dec 01, 1977

Citation Formats

Hill, R J, and Rickard, C E.F. Structure of tetrakis(salicylaldehydato)thorium(IV). United Kingdom: N. p., 1977. Web. doi:10.1016/0022-1902(77)80108-5.
Hill, R J, & Rickard, C E.F. Structure of tetrakis(salicylaldehydato)thorium(IV). United Kingdom. https://doi.org/10.1016/0022-1902(77)80108-5
Hill, R J, and Rickard, C E.F. 1977. "Structure of tetrakis(salicylaldehydato)thorium(IV)." United Kingdom. https://doi.org/10.1016/0022-1902(77)80108-5.
@misc{etde_5335174,
title = {Structure of tetrakis(salicylaldehydato)thorium(IV)}
author = {Hill, R J, and Rickard, C E.F.}
abstractNote = {The structure of tetrakis(salicylaldehydato)thorium(IV) has been determined by single crystal X-ray crystallography. The crystals are tetragonal, a = 10.214, b = 23.744 A, space group P4/sub 1/. The molecules are eight coordinate, the coordination polyhedron being a dodecahedron with approximate Dsub(2d) symmetry. The dodecahedral A sites are occupied by the aldehydic oxygens and the phenolic oxygens occupy the B sites.}
doi = {10.1016/0022-1902(77)80108-5}
journal = []
volume = {39:9}
journal type = {AC}
place = {United Kingdom}
year = {1977}
month = {Jan}
}