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Valency state changes in lanthanide-contained systems under high pressure

Abstract

Changes in valency state induced by pressure in samarium sulphide SmS remind one of alchemy, as the mat black initial substance shines golden after the electron transition. The alchemist's dream is of course not realized, however the compound does exhibit an unusually interesting behaviour in the new state. The valency state of samarium as newly appeared fluctuated very rapidly between two electron configurations. Manipulation of the valency state by pressure or chemical substitution can basically change the physical properties of systems containing lanthanides. The phenomena are described and discussed in the following survey.
Authors:
Publication Date:
Aug 01, 1980
Product Type:
Journal Article
Reference Number:
EDB-84-044818
Resource Relation:
Journal Name: Angew. Chem.; (Germany, Federal Republic of); Journal Volume: 92:8
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; RARE EARTH COMPOUNDS; VALENCE; ELECTRIC CONDUCTIVITY; LATTICE PARAMETERS; MODIFICATIONS; OXIDES; PRESSURE DEPENDENCE; RARE EARTHS; SELENIDES; SULFIDES; TELLURIDES; CHALCOGENIDES; ELECTRICAL PROPERTIES; ELEMENTS; METALS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SELENIUM COMPOUNDS; SULFUR COMPOUNDS; TELLURIUM COMPOUNDS; 400201* - Chemical & Physicochemical Properties
OSTI ID:
5335004
Country of Origin:
Germany
Language:
German
Other Identifying Numbers:
Journal ID: CODEN: ANCEA
Submitting Site:
HEDB
Size:
Pages: 626-631
Announcement Date:
Feb 01, 1984

Citation Formats

Jayaraman, A. Valency state changes in lanthanide-contained systems under high pressure. Germany: N. p., 1980. Web.
Jayaraman, A. Valency state changes in lanthanide-contained systems under high pressure. Germany.
Jayaraman, A. 1980. "Valency state changes in lanthanide-contained systems under high pressure." Germany.
@misc{etde_5335004,
title = {Valency state changes in lanthanide-contained systems under high pressure}
author = {Jayaraman, A}
abstractNote = {Changes in valency state induced by pressure in samarium sulphide SmS remind one of alchemy, as the mat black initial substance shines golden after the electron transition. The alchemist's dream is of course not realized, however the compound does exhibit an unusually interesting behaviour in the new state. The valency state of samarium as newly appeared fluctuated very rapidly between two electron configurations. Manipulation of the valency state by pressure or chemical substitution can basically change the physical properties of systems containing lanthanides. The phenomena are described and discussed in the following survey.}
journal = []
volume = {92:8}
journal type = {AC}
place = {Germany}
year = {1980}
month = {Aug}
}