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Development and testing of on-line analytical instrumentation for alkali and heavy metal release in pressurised conversion processes

Abstract

The purpose of the project is to demonstrate in industrial conditions and further develop the continuous alkali measurement method plasma excited alkali resonance line spectroscopy (PEARLS) developed at Tampere University of Technology (TUT). The demonstration takes place in joint measuring campaigns, where two other continuous alkali measurement methods, ELIF and surface ionisation, are being simultaneously demonstrated. A modification of PEARLS will also be developed for the continuous measurement of heavy metal concentrations. A market study of continuous measuring techniques for alkali and heavy metals is further part of the project. The method will be demonstrated in two pressurised fluidised bed combustion facilities. One of these is the 10 MW PCFB of Foster Wheeler Energia Oy in Karhula. The second one is yet to be decided. The first measuring campaign is scheduled for the spring of 1997 in Karhula. In 1996 the group at TUT participated in the performance of a market study regarding continuous measuring techniques for alkali and heavy metal concentrations. A draft report was submitted to and approved by the EC. Development work on PEARLS in 1996 has centered around the construction of a calibration device for alkali measurements. The device can be used by all three measuring  More>>
Authors:
Hernberg, R; Haeyrinen, V; Oikari, R [1] 
  1. Tampere Univ. of Technology (Finland)
Publication Date:
Oct 01, 1997
Product Type:
Technical Report
Report Number:
AAA-LIEKKI-L97-1-Pt.2
Reference Number:
SCA: 014000; 400102; PA: FI-97:003575; EDB-97:128997; SN: 97001852398
Resource Relation:
Other Information: DN: LIEKKI 2 Research Programme; PBD: 1997; Related Information: Is Part Of LIEKKI 2 - Annual Review 1997. Project reports; Hupa, M.; Matinlinna, J.; Ljung, M. [eds.]; PB: 484 p.
Subject:
01 COAL, LIGNITE, AND PEAT; 40 CHEMISTRY; FLUIDIZED-BED COMBUSTION; ON-LINE MEASUREMENT SYSTEMS; POTASSIUM; GASIFICATION; PLASMA; SODIUM; PRESSURIZATION; LITHIUM; MERCURY; LEAD; CADMIUM; ABSORPTION SPECTROSCOPY; RESONANCE ABSORPTION; COAL
OSTI ID:
531304
Research Organizations:
Aabo Akademi, Turku (Finland). Combustion Chemistry Research Group
Country of Origin:
Finland
Language:
English
Other Identifying Numbers:
Other: ON: DE98701757; CNN: Project TEKES-LIEKKI2-320; ISBN 951-650-955-X; TRN: FI9703575
Availability:
OSTI as DE98701757
Submitting Site:
FI
Size:
pp. 595-606
Announcement Date:
Oct 23, 1997

Citation Formats

Hernberg, R, Haeyrinen, V, and Oikari, R. Development and testing of on-line analytical instrumentation for alkali and heavy metal release in pressurised conversion processes. Finland: N. p., 1997. Web.
Hernberg, R, Haeyrinen, V, & Oikari, R. Development and testing of on-line analytical instrumentation for alkali and heavy metal release in pressurised conversion processes. Finland.
Hernberg, R, Haeyrinen, V, and Oikari, R. 1997. "Development and testing of on-line analytical instrumentation for alkali and heavy metal release in pressurised conversion processes." Finland.
@misc{etde_531304,
title = {Development and testing of on-line analytical instrumentation for alkali and heavy metal release in pressurised conversion processes}
author = {Hernberg, R, Haeyrinen, V, and Oikari, R}
abstractNote = {The purpose of the project is to demonstrate in industrial conditions and further develop the continuous alkali measurement method plasma excited alkali resonance line spectroscopy (PEARLS) developed at Tampere University of Technology (TUT). The demonstration takes place in joint measuring campaigns, where two other continuous alkali measurement methods, ELIF and surface ionisation, are being simultaneously demonstrated. A modification of PEARLS will also be developed for the continuous measurement of heavy metal concentrations. A market study of continuous measuring techniques for alkali and heavy metals is further part of the project. The method will be demonstrated in two pressurised fluidised bed combustion facilities. One of these is the 10 MW PCFB of Foster Wheeler Energia Oy in Karhula. The second one is yet to be decided. The first measuring campaign is scheduled for the spring of 1997 in Karhula. In 1996 the group at TUT participated in the performance of a market study regarding continuous measuring techniques for alkali and heavy metal concentrations. A draft report was submitted to and approved by the EC. Development work on PEARLS in 1996 has centered around the construction of a calibration device for alkali measurements. The device can be used by all three measuring techniques in the project to check readings against a known alkali concentration at controlled and known conditions. In 1996 PEARLS was applied for alkali measurement at several pressurised combustion installations of laboratory and industrial pilot scale}
place = {Finland}
year = {1997}
month = {Oct}
}