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Evaluation of zinc toxicity in soils by means of the CaCl/sub 2/ method

Abstract

Soils in the valleys of the rivers Innerste and Oker, north of the Harz mountains, are seriously contaminated by heavy metals. Above all high zinc contents cause severe plant damages. They are like injuries caused by air pollution in the environment of smelting-houses. Usually the heavy metal content of the soil is estimated by extraction with diluted acids, e.g., 0.43 N HNO/sub 3/. In this way nearly the whole zinc store is recorded. For an evaluation of the plant available zinc content we extracted contaminated soils with 0.025 N CaCl/sub 2/. This procedure records the influence of soil properties on the plant availability of the zinc like pH value and clay content. With 0.43 NHNO/sub 3/ 260-7500 ppM zinc were estimated. The maximum content of the CaCl/sub 2/ solution was 109 ppM. Cereals at stage of shooting contained 68-1210 ppM (DM), sugar beet leaves 72-812 ppM (DM). The CaCl/sub 2/ method brought about a closer relationship between soils and plants compared with the HNO/sub 3/ method. Beyond it these method permits the establishment of a preliminary toxicity limit which is supposed in the range of 1 ppM. The percent quota of Zn-CaCl/sub 2/ on Zn-HNO/sub 3/ as a measure of  More>>
Publication Date:
Jan 01, 1976
Product Type:
Journal Article
Reference Number:
EDB-85-141463
Resource Relation:
Journal Name: Landwirtsch. Forsch.; (Germany, Federal Republic of); Journal Volume: 33:1
Subject:
54 ENVIRONMENTAL SCIENCES; SOILS; ZINC; TOXICITY; CALCIUM CHLORIDES; CEREALS; EXPERIMENTAL DATA; FEDERAL REPUBLIC OF GERMANY; LEAVES; NITRIC ACID; PH VALUE; SMELTERS; SOIL CHEMISTRY; SUGAR BEETS; ALKALINE EARTH METAL COMPOUNDS; BEETS; CALCIUM COMPOUNDS; CALCIUM HALIDES; CHEMISTRY; CHLORIDES; CHLORINE COMPOUNDS; DATA; ELEMENTS; EUROPE; FOOD; GRASS; HALIDES; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; INFORMATION; INORGANIC ACIDS; METALS; NUMERICAL DATA; PLANTS; VEGETABLES; WESTERN EUROPE; 510200* - Environment, Terrestrial- Chemicals Monitoring & Transport- (-1989)
OSTI ID:
5305982
Research Organizations:
LUFA, Hameln, West Germany
Country of Origin:
Germany
Language:
German
Other Identifying Numbers:
Journal ID: CODEN: LAWFA
Submitting Site:
HEDB
Size:
Pages: 274-281
Announcement Date:
Sep 01, 1985

Citation Formats

Merkel, D, and Koester, W. Evaluation of zinc toxicity in soils by means of the CaCl/sub 2/ method. Germany: N. p., 1976. Web.
Merkel, D, & Koester, W. Evaluation of zinc toxicity in soils by means of the CaCl/sub 2/ method. Germany.
Merkel, D, and Koester, W. 1976. "Evaluation of zinc toxicity in soils by means of the CaCl/sub 2/ method." Germany.
@misc{etde_5305982,
title = {Evaluation of zinc toxicity in soils by means of the CaCl/sub 2/ method}
author = {Merkel, D, and Koester, W}
abstractNote = {Soils in the valleys of the rivers Innerste and Oker, north of the Harz mountains, are seriously contaminated by heavy metals. Above all high zinc contents cause severe plant damages. They are like injuries caused by air pollution in the environment of smelting-houses. Usually the heavy metal content of the soil is estimated by extraction with diluted acids, e.g., 0.43 N HNO/sub 3/. In this way nearly the whole zinc store is recorded. For an evaluation of the plant available zinc content we extracted contaminated soils with 0.025 N CaCl/sub 2/. This procedure records the influence of soil properties on the plant availability of the zinc like pH value and clay content. With 0.43 NHNO/sub 3/ 260-7500 ppM zinc were estimated. The maximum content of the CaCl/sub 2/ solution was 109 ppM. Cereals at stage of shooting contained 68-1210 ppM (DM), sugar beet leaves 72-812 ppM (DM). The CaCl/sub 2/ method brought about a closer relationship between soils and plants compared with the HNO/sub 3/ method. Beyond it these method permits the establishment of a preliminary toxicity limit which is supposed in the range of 1 ppM. The percent quota of Zn-CaCl/sub 2/ on Zn-HNO/sub 3/ as a measure of the zinc availability was closely related to the pH value of the soil. The relationship was closer the more soils with lower pH values were present, but there was an essential relationship even at pH levels above 7.0. In the environment of a smelting-house the zinc content of plants was closer related to Zn-HNO/sub 3/ compared with Zn-CaCl/sub 2/. In this case the zinc content of the plants was partly caused by the zinc pollution. But at increasing pH value of the soil even here the availability of the soil zinc decreased too. 33 references.}
journal = []
volume = {33:1}
journal type = {AC}
place = {Germany}
year = {1976}
month = {Jan}
}