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Radiolysis of titanium potassium oxalate in aqueous solution. [. gamma. rays]

Journal Article:

Abstract

The dissolution state of titanium potassium oxalate in aqueous solution is different according to the pH. The yellowish brown titanium complex produced by the reaction of titanium potassium oxalate and hydrogen peroxide seems to be different in its structure according to the pH. Considering these points, gamma-ray irradiation was carried out on the sample by dissolving titanium potassium oxalate in purified water under the conditions of oxygen saturation and nitrogen saturation, and the relation between irradiation dose and the production of titanium complex was determined. On the basis of the experimental result, the mechanism of forming hydrogen peroxide was presumed. The radiation source used was 2,000 Ci of /sup 60/Co. For photometric analysis, a 139 type photoelectric spectrophotometer of Hitachi Ltd. was used. From the experimental results, in neutral water, titanium potassium oxalate exists in the state that two oxalic acid ions are coordinated to titanyl ion, while in case of the pH lowered by the addition of sulfuric acid, it can exist in the state that one oxalic acid ion is coordinated to titanyl ion. The yield of hydrogen peroxide produced by irradiating titanium potassium oxalate aqueous solution with gamma-ray is the sum of the molecular product from water  More>>
Authors:
Bundo, Y; Ono, I; [1]  Ogawa, T
  1. Industrial Research Inst. of Kanagawa Prefecture, Yokohama (Japan)
Publication Date:
Jan 01, 1975
Product Type:
Journal Article
Reference Number:
AIX-09-349345; EDB-78-027997
Resource Relation:
Journal Name: Kanagawa-ken Kogyo Shikenjo Kenkyu Hokoku; (Japan); Journal Volume: 44
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; OXALATES; RADIOLYSIS; POTASSIUM COMPOUNDS; TITANIUM COMPOUNDS; AQUEOUS SOLUTIONS; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; G VALUE; GAMMA RADIATION; IRRADIATION; LIGANDS; PH VALUE; ALKALI METAL COMPOUNDS; CARBOXYLIC ACID SALTS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; CHEMISTRY; DECOMPOSITION; DISPERSIONS; ELECTROMAGNETIC RADIATION; IONIZING RADIATIONS; KINETICS; MIXTURES; RADIATION CHEMISTRY; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS; SOLUTIONS; TRANSITION ELEMENT COMPOUNDS; YIELDS; 400600* - Radiation Chemistry
OSTI ID:
5283039
Country of Origin:
Japan
Language:
Japanese
Other Identifying Numbers:
Journal ID: CODEN: KKSKA
Submitting Site:
INIS
Size:
Pages: 1-4
Announcement Date:
Jan 01, 1978

Journal Article:

Citation Formats

Bundo, Y, Ono, I, and Ogawa, T. Radiolysis of titanium potassium oxalate in aqueous solution. [. gamma. rays]. Japan: N. p., 1975. Web.
Bundo, Y, Ono, I, & Ogawa, T. Radiolysis of titanium potassium oxalate in aqueous solution. [. gamma. rays]. Japan.
Bundo, Y, Ono, I, and Ogawa, T. 1975. "Radiolysis of titanium potassium oxalate in aqueous solution. [. gamma. rays]." Japan.
@misc{etde_5283039,
title = {Radiolysis of titanium potassium oxalate in aqueous solution. [. gamma. rays]}
author = {Bundo, Y, Ono, I, and Ogawa, T}
abstractNote = {The dissolution state of titanium potassium oxalate in aqueous solution is different according to the pH. The yellowish brown titanium complex produced by the reaction of titanium potassium oxalate and hydrogen peroxide seems to be different in its structure according to the pH. Considering these points, gamma-ray irradiation was carried out on the sample by dissolving titanium potassium oxalate in purified water under the conditions of oxygen saturation and nitrogen saturation, and the relation between irradiation dose and the production of titanium complex was determined. On the basis of the experimental result, the mechanism of forming hydrogen peroxide was presumed. The radiation source used was 2,000 Ci of /sup 60/Co. For photometric analysis, a 139 type photoelectric spectrophotometer of Hitachi Ltd. was used. From the experimental results, in neutral water, titanium potassium oxalate exists in the state that two oxalic acid ions are coordinated to titanyl ion, while in case of the pH lowered by the addition of sulfuric acid, it can exist in the state that one oxalic acid ion is coordinated to titanyl ion. The yield of hydrogen peroxide produced by irradiating titanium potassium oxalate aqueous solution with gamma-ray is the sum of the molecular product from water and the radiolysis product from titanium potassium oxalate.}
journal = {Kanagawa-ken Kogyo Shikenjo Kenkyu Hokoku; (Japan)}
volume = {44}
journal type = {AC}
place = {Japan}
year = {1975}
month = {Jan}
}