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Investigation into interaction of CO/sub 2/ molecules with zeolites by infrared spectroscopy

Abstract

Interaction of CO/sub 2/ molecules with zeolites, particularly with SrNaJ was studied by infrared-spectroscopy. To obtain infrared-spectra the zeolites were pressed into tablets and were calcinated at 500 deg. In the spectra the bands of chemisorbed CO/sub 2/ absorption were found in the range 1300 - 1600 cm/sup -1/. The CO/sub 2/ molecule was found to be strongly deformed due to chemisorption. In terms of electronic structure of the zeolite crystalline skeleton several types of CO/sub 2/ molecules interaction with different active zeolites were found. The position of the high-frequency band of CO/sub 2/ absorption in zeolites spectra was found to be a linear function of electrostatic field of the cations.
Authors:
Ignat'eva, L A; Levshin, L V; Chukin, G D; Efimenko, L V; Kozlova, T I [1] 
  1. Moskovskij Gosudarstvennyj Univ. (USSR). Kafedra Optiki
Publication Date:
Jul 01, 1975
Product Type:
Journal Article
Reference Number:
AIX-09-349225; EDB-78-045579
Resource Relation:
Journal Name: Vestn. Mosk. Univ., Ser. III. Fiz. Astron.; (USSR); Journal Volume: 16:4
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CARBON DIOXIDE; CHEMISORPTION; ZEOLITES; SORPTIVE PROPERTIES; CATIONS; CHEMICAL REACTION KINETICS; ELECTRONIC STRUCTURE; INFRARED SPECTRA; SODIUM COMPOUNDS; STRONTIUM COMPOUNDS; YTTRIUM COMPOUNDS; ALKALI METAL COMPOUNDS; ALKALINE EARTH METAL COMPOUNDS; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHARGED PARTICLES; CHEMICAL REACTIONS; INORGANIC ION EXCHANGERS; ION EXCHANGE MATERIALS; IONS; KINETICS; MINERALS; OXIDES; OXYGEN COMPOUNDS; REACTION KINETICS; SEPARATION PROCESSES; SORPTION; SPECTRA; TRANSITION ELEMENT COMPOUNDS; 400201* - Chemical & Physicochemical Properties
OSTI ID:
5252697
Country of Origin:
USSR
Language:
Russian
Other Identifying Numbers:
Journal ID: CODEN: VMUFA
Submitting Site:
INIS
Size:
Pages: 436-442
Announcement Date:
Jan 01, 1978

Citation Formats

Ignat'eva, L A, Levshin, L V, Chukin, G D, Efimenko, L V, and Kozlova, T I. Investigation into interaction of CO/sub 2/ molecules with zeolites by infrared spectroscopy. USSR: N. p., 1975. Web.
Ignat'eva, L A, Levshin, L V, Chukin, G D, Efimenko, L V, & Kozlova, T I. Investigation into interaction of CO/sub 2/ molecules with zeolites by infrared spectroscopy. USSR.
Ignat'eva, L A, Levshin, L V, Chukin, G D, Efimenko, L V, and Kozlova, T I. 1975. "Investigation into interaction of CO/sub 2/ molecules with zeolites by infrared spectroscopy." USSR.
@misc{etde_5252697,
title = {Investigation into interaction of CO/sub 2/ molecules with zeolites by infrared spectroscopy}
author = {Ignat'eva, L A, Levshin, L V, Chukin, G D, Efimenko, L V, and Kozlova, T I}
abstractNote = {Interaction of CO/sub 2/ molecules with zeolites, particularly with SrNaJ was studied by infrared-spectroscopy. To obtain infrared-spectra the zeolites were pressed into tablets and were calcinated at 500 deg. In the spectra the bands of chemisorbed CO/sub 2/ absorption were found in the range 1300 - 1600 cm/sup -1/. The CO/sub 2/ molecule was found to be strongly deformed due to chemisorption. In terms of electronic structure of the zeolite crystalline skeleton several types of CO/sub 2/ molecules interaction with different active zeolites were found. The position of the high-frequency band of CO/sub 2/ absorption in zeolites spectra was found to be a linear function of electrostatic field of the cations.}
journal = []
volume = {16:4}
journal type = {AC}
place = {USSR}
year = {1975}
month = {Jul}
}