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Grafting

Conference:

Abstract

The unique value of ionizing radiation for the initiation of grafting to backbone polymers is discussed. The principles of the technique are briefly reviewed. The conditions under which free radicals and ions participate in these reactions are examined. Examples of representative grafting processes are considered to illustrate where the technique can be of potential commercial value to a wide range of industries. The general principles of these grafting reactions are shown to be applicable to radiation induced rapid cure technology such as is provided by electron beam processing facilities. Grafting reactions initiated by UV are also treated and shown to be of importance because of the many similarities in properties of the ionizing radiation and UV systems, also the rapid industrial exploitation of EB and sensitized UV processing technology. Possible future trends in radiation grafting are outlined.
Authors:
Garnett, J L [1] 
  1. New South Wales Univ., Kensington (Australia). School of Chemistry
Publication Date:
Jan 01, 1979
Product Type:
Conference
Reference Number:
AIX-11-525677; EDB-80-097110
Resource Relation:
Journal Name: Radiat. Phys. Chem.; (United Kingdom); Journal Volume: 14:1-2; Conference: Advances in radiation processing: 2. international meeting on radiation processing, Miami, FL, USA, 22 - 26 Oct 1978
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; GRAFT POLYMERS; PRODUCTION; ORGANIC POLYMERS; CHEMICAL RADIATION EFFECTS; BIBLIOGRAPHIES; CHEMICAL REACTION KINETICS; ELECTRON BEAMS; INDUSTRY; IRRADIATION; IRRADIATION PLANTS; POLYMERIZATION; REVIEWS; ULTRAVIOLET RADIATION; BEAMS; CHEMICAL REACTIONS; CHEMISTRY; DOCUMENT TYPES; ELECTROMAGNETIC RADIATION; KINETICS; LEPTON BEAMS; NUCLEAR FACILITIES; ORGANIC COMPOUNDS; PARTICLE BEAMS; POLYMERS; RADIATION CHEMISTRY; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS; 400600* - Radiation Chemistry
OSTI ID:
5252241
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: RPCHD
Submitting Site:
INIS
Size:
Pages: 79-99
Announcement Date:

Conference:

Citation Formats

Garnett, J L. Grafting. United Kingdom: N. p., 1979. Web.
Garnett, J L. Grafting. United Kingdom.
Garnett, J L. 1979. "Grafting." United Kingdom.
@misc{etde_5252241,
title = {Grafting}
author = {Garnett, J L}
abstractNote = {The unique value of ionizing radiation for the initiation of grafting to backbone polymers is discussed. The principles of the technique are briefly reviewed. The conditions under which free radicals and ions participate in these reactions are examined. Examples of representative grafting processes are considered to illustrate where the technique can be of potential commercial value to a wide range of industries. The general principles of these grafting reactions are shown to be applicable to radiation induced rapid cure technology such as is provided by electron beam processing facilities. Grafting reactions initiated by UV are also treated and shown to be of importance because of the many similarities in properties of the ionizing radiation and UV systems, also the rapid industrial exploitation of EB and sensitized UV processing technology. Possible future trends in radiation grafting are outlined.}
journal = {Radiat. Phys. Chem.; (United Kingdom)}
volume = {14:1-2}
place = {United Kingdom}
year = {1979}
month = {Jan}
}