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Complexes of lanthanum(III), cerium(III), samarium(III) and dysprosium(III) with substituted piperidines

Journal Article:

Abstract

Complexes of the general formulae M/sub 2/Cl/sub 6/(L)/sub 3/.C/sub 2/H/sub 5/OH and M/sub 2/(NO/sub 3/)/sub 6/(L)/sub 2/.CH/sub 3/OH have been synthesised by the reactions of chlorides and nitrates of La(III), Ce(III), Sm(III) and Dy(III) with 2-methylpiperidine, 3-methylpiperidine and 4-methylpiperidine. These complexes have been characterised on the basis of their elemental analysis, and IR and electronic reflectance spectra. IR spectral data indicate the presence of coordinated ethanol and methanol molecules and bidentate nitrate groups. Coordination numbers of the metal ions vary from 5 to 8. 19 refs.
Publication Date:
Nov 01, 1983
Product Type:
Journal Article
Reference Number:
AIX-17-067497; EDB-86-175990
Resource Relation:
Journal Name: Indian J. Chem., Sect. A; (India); Journal Volume: 22:11
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CERIUM COMPLEXES; STRUCTURAL CHEMICAL ANALYSIS; DYSPROSIUM COMPLEXES; LANTHANUM COMPLEXES; SAMARIUM COMPLEXES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; EXPERIMENTAL DATA; INFRARED SPECTRA; PIPERIDINES; AMINES; AZINES; COMPLEXES; DATA; HETEROCYCLIC COMPOUNDS; INFORMATION; NUMERICAL DATA; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PYRIDINES; RARE EARTH COMPLEXES; SPECTRA; SYNTHESIS; 400201* - Chemical & Physicochemical Properties; 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
OSTI ID:
5228528
Research Organizations:
Punjabi Univ., Patiala, India. Dept. of Chemistry
Country of Origin:
India
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: IJCAD
Submitting Site:
INIS
Size:
Pages: 987-990
Announcement Date:
Oct 01, 1986

Journal Article:

Citation Formats

Manhas, B S, Trikha, A K, Singh, H, and Chander, M. Complexes of lanthanum(III), cerium(III), samarium(III) and dysprosium(III) with substituted piperidines. India: N. p., 1983. Web.
Manhas, B S, Trikha, A K, Singh, H, & Chander, M. Complexes of lanthanum(III), cerium(III), samarium(III) and dysprosium(III) with substituted piperidines. India.
Manhas, B S, Trikha, A K, Singh, H, and Chander, M. 1983. "Complexes of lanthanum(III), cerium(III), samarium(III) and dysprosium(III) with substituted piperidines." India.
@misc{etde_5228528,
title = {Complexes of lanthanum(III), cerium(III), samarium(III) and dysprosium(III) with substituted piperidines}
author = {Manhas, B S, Trikha, A K, Singh, H, and Chander, M}
abstractNote = {Complexes of the general formulae M/sub 2/Cl/sub 6/(L)/sub 3/.C/sub 2/H/sub 5/OH and M/sub 2/(NO/sub 3/)/sub 6/(L)/sub 2/.CH/sub 3/OH have been synthesised by the reactions of chlorides and nitrates of La(III), Ce(III), Sm(III) and Dy(III) with 2-methylpiperidine, 3-methylpiperidine and 4-methylpiperidine. These complexes have been characterised on the basis of their elemental analysis, and IR and electronic reflectance spectra. IR spectral data indicate the presence of coordinated ethanol and methanol molecules and bidentate nitrate groups. Coordination numbers of the metal ions vary from 5 to 8. 19 refs.}
journal = {Indian J. Chem., Sect. A; (India)}
volume = {22:11}
journal type = {AC}
place = {India}
year = {1983}
month = {Nov}
}