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Hexagonal perovskites with cationic vacancies. 7. Vibrational spectroscopic investigations on the rhombohedral 12 L-stacking polytypes Ba/sub 4/Bsup(II)(Re/sub 2/vacantO/sub 12/) and Ba/sub 4/Bsub(2/3)sup(III)vacantsub(1/3)(Re/sub 2/vacantO/sub 12/)

Abstract

For the rhombohedral 12 L stacking polytypes Ba/sub 4/Bsup(II)(Re/sub 2/vacantO/sub 12/) and Ba/sub 4/Bsub(2/3)sup(III)vacantsub(1/3)(Re/sub 2/vacantO/sub 12/), space group R3m, sequence (3)(1), the lattice consists of groups of three face sharing octahedra with the composition Re/sub 2/vacantO/sub 12/. They are isolated from each other by the Ba and B ions. The vibrational spectra are interpreted according to the factor group analysis. For the Re/sub 2/vacantO/sub 12/ unit (symmetry Dsub(3d) the results of a complete vibrational analysis and the calculation of the force constants are reported.
Authors:
Fadini, A; Kemmler-Sack, S; Schittenhelm, H J; Rother, H J; Treiber, U [1] 
  1. Tuebingen Univ. (Germany, F.R.). Lehrstuhl fuer Anorganische Chemie 2
Publication Date:
Jul 01, 1979
Product Type:
Journal Article
Reference Number:
AIX-11-516639; EDB-80-096966
Resource Relation:
Journal Name: Z. Anorg. Allg. Chem.; (German Democratic Republic); Journal Volume: 454
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; BARIUM COMPOUNDS; RAMAN SPECTRA; TRIGONAL LATTICES; CADMIUM COMPOUNDS; CALCIUM COMPOUNDS; COBALT COMPOUNDS; GADOLINIUM COMPOUNDS; MAGNESIUM COMPOUNDS; RHENATES; YTTRIUM COMPOUNDS; ZINC COMPOUNDS; EXPERIMENTAL DATA; INFRARED SPECTRA; ISOLATED VALUES; LATTICE VIBRATIONS; SPACE GROUPS; SYMMETRY; VACANCIES; ALKALINE EARTH METAL COMPOUNDS; CRYSTAL DEFECTS; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DATA; DATA FORMS; INFORMATION; NUMERICAL DATA; OXYGEN COMPOUNDS; POINT DEFECTS; RARE EARTH COMPOUNDS; RHENIUM COMPOUNDS; SPECTRA; TRANSITION ELEMENT COMPOUNDS; 400201* - Chemical & Physicochemical Properties
OSTI ID:
5218974
Country of Origin:
Germany
Language:
German
Other Identifying Numbers:
Journal ID: CODEN: ZAACA
Submitting Site:
INIS
Size:
Pages: 49-62
Announcement Date:
May 01, 1980

Citation Formats

Fadini, A, Kemmler-Sack, S, Schittenhelm, H J, Rother, H J, and Treiber, U. Hexagonal perovskites with cationic vacancies. 7. Vibrational spectroscopic investigations on the rhombohedral 12 L-stacking polytypes Ba/sub 4/Bsup(II)(Re/sub 2/vacantO/sub 12/) and Ba/sub 4/Bsub(2/3)sup(III)vacantsub(1/3)(Re/sub 2/vacantO/sub 12/). Germany: N. p., 1979. Web. doi:10.1002/zaac.19794540109.
Fadini, A, Kemmler-Sack, S, Schittenhelm, H J, Rother, H J, & Treiber, U. Hexagonal perovskites with cationic vacancies. 7. Vibrational spectroscopic investigations on the rhombohedral 12 L-stacking polytypes Ba/sub 4/Bsup(II)(Re/sub 2/vacantO/sub 12/) and Ba/sub 4/Bsub(2/3)sup(III)vacantsub(1/3)(Re/sub 2/vacantO/sub 12/). Germany. https://doi.org/10.1002/zaac.19794540109
Fadini, A, Kemmler-Sack, S, Schittenhelm, H J, Rother, H J, and Treiber, U. 1979. "Hexagonal perovskites with cationic vacancies. 7. Vibrational spectroscopic investigations on the rhombohedral 12 L-stacking polytypes Ba/sub 4/Bsup(II)(Re/sub 2/vacantO/sub 12/) and Ba/sub 4/Bsub(2/3)sup(III)vacantsub(1/3)(Re/sub 2/vacantO/sub 12/)." Germany. https://doi.org/10.1002/zaac.19794540109.
@misc{etde_5218974,
title = {Hexagonal perovskites with cationic vacancies. 7. Vibrational spectroscopic investigations on the rhombohedral 12 L-stacking polytypes Ba/sub 4/Bsup(II)(Re/sub 2/vacantO/sub 12/) and Ba/sub 4/Bsub(2/3)sup(III)vacantsub(1/3)(Re/sub 2/vacantO/sub 12/)}
author = {Fadini, A, Kemmler-Sack, S, Schittenhelm, H J, Rother, H J, and Treiber, U}
abstractNote = {For the rhombohedral 12 L stacking polytypes Ba/sub 4/Bsup(II)(Re/sub 2/vacantO/sub 12/) and Ba/sub 4/Bsub(2/3)sup(III)vacantsub(1/3)(Re/sub 2/vacantO/sub 12/), space group R3m, sequence (3)(1), the lattice consists of groups of three face sharing octahedra with the composition Re/sub 2/vacantO/sub 12/. They are isolated from each other by the Ba and B ions. The vibrational spectra are interpreted according to the factor group analysis. For the Re/sub 2/vacantO/sub 12/ unit (symmetry Dsub(3d) the results of a complete vibrational analysis and the calculation of the force constants are reported.}
doi = {10.1002/zaac.19794540109}
journal = []
volume = {454}
journal type = {AC}
place = {Germany}
year = {1979}
month = {Jul}
}