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Heterogeneous hydrogenation of unsaturated compounds with catalyst P-2-Ni with turnover numbers up to 90,000

Journal Article:

Abstract

Unsaturated compounds are very rapidly hydrogenated with nickel-boride catalyst P-2-Ni without solvent under mild conditions (70-85/sup 0/C and 10 bar). Turnover numbers UZ up to 90,000 and space-time-yields of 7.440 mmol product per l and 1 mgA Nickel in one hour with a mean catalyst activity a = 124 were observed. This hydrogenation catalyst has a power, which is in the same magnitude of very active noble metal catalysts.
Authors:
Strohmeier, W; Pfoehler, M; Steigerwald, H [1] 
  1. Wuerzburg Univ. (Germany, F.R.). Inst. fuer Physikalische Chemie
Publication Date:
Dec 01, 1977
Product Type:
Journal Article
Reference Number:
ERA-03-038736; EDB-78-077229
Resource Relation:
Journal Name: Z. Naturforsch., b; (Germany, Federal Republic of); Journal Volume: 32:12
Subject:
01 COAL, LIGNITE, AND PEAT; HYDROGENATION; CATALYSIS; NICKEL BORIDES; CATALYTIC EFFECTS; ALKENES; CATALYSTS; CHEMICAL REACTION KINETICS; COMPARATIVE EVALUATIONS; EFFICIENCY; PRESSURE DEPENDENCE; TEMPERATURE DEPENDENCE; BORIDES; BORON COMPOUNDS; CHEMICAL REACTIONS; HYDROCARBONS; KINETICS; NICKEL COMPOUNDS; ORGANIC COMPOUNDS; REACTION KINETICS; TRANSITION ELEMENT COMPOUNDS; 010403* - Coal & Coal Products- Hydrogenation- (-1987)
OSTI ID:
5084687
Country of Origin:
Germany
Language:
German
Other Identifying Numbers:
Journal ID: CODEN: ZENBA
Submitting Site:
DE
Size:
Pages: 1461-1466
Announcement Date:
Jun 01, 1978

Journal Article:

Citation Formats

Strohmeier, W, Pfoehler, M, and Steigerwald, H. Heterogeneous hydrogenation of unsaturated compounds with catalyst P-2-Ni with turnover numbers up to 90,000. Germany: N. p., 1977. Web.
Strohmeier, W, Pfoehler, M, & Steigerwald, H. Heterogeneous hydrogenation of unsaturated compounds with catalyst P-2-Ni with turnover numbers up to 90,000. Germany.
Strohmeier, W, Pfoehler, M, and Steigerwald, H. 1977. "Heterogeneous hydrogenation of unsaturated compounds with catalyst P-2-Ni with turnover numbers up to 90,000." Germany.
@misc{etde_5084687,
title = {Heterogeneous hydrogenation of unsaturated compounds with catalyst P-2-Ni with turnover numbers up to 90,000}
author = {Strohmeier, W, Pfoehler, M, and Steigerwald, H}
abstractNote = {Unsaturated compounds are very rapidly hydrogenated with nickel-boride catalyst P-2-Ni without solvent under mild conditions (70-85/sup 0/C and 10 bar). Turnover numbers UZ up to 90,000 and space-time-yields of 7.440 mmol product per l and 1 mgA Nickel in one hour with a mean catalyst activity a = 124 were observed. This hydrogenation catalyst has a power, which is in the same magnitude of very active noble metal catalysts.}
journal = {Z. Naturforsch., b; (Germany, Federal Republic of)}
volume = {32:12}
journal type = {AC}
place = {Germany}
year = {1977}
month = {Dec}
}