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Visualising the Micro World of Chemical/Geochemical Interactions Using Atomic Force Microscopy (AFM)

Abstract

Scanning force microscopy, in particular AFM (Atomic Force Microscopy), provides a particular useful and interesting tool for the examination of surface structure at the near-atomic level. AFM is particularly well suited to the study of interactions at the surface in aqueous solutions using real time in-situ measurements. In this paper there is presented AFM images showing in situ crystal growth from supersaturated BaSO{sub 4} solutions onto the surface of barite. Growth structures in the form of spiral crystal growth features, presumably originating from screw dislocations, are illustrated. AFM images of novel scale crystal growth inhibition experiments are presented. Examination of the manner in which generically different species adsorb onto growth structures may help to explain mechanistic differences in the way which different inhibitor species perform against barium sulphate scale formation. Adsorption of polyacrylamide species onto mica surfaces have been viewed. The general utility of AFM to a number of other common surface interactions in oil field chemistry will be discussed. 17 refs., 3 figs.
Publication Date:
Dec 31, 1996
Product Type:
Conference
Report Number:
NEI-NO-781; CONF-9603242-20
Reference Number:
SCA: 023000; PA: NW-97:005212; EDB-97:090217; NTS-97:011969; NTS-97:013403; SN: 97001808096
Resource Relation:
Conference: 7. international symposium on oil field chemicals, Geilo (Norway), 17-20 Mar 1996; Other Information: PBD: 1996
Subject:
02 PETROLEUM; OIL FIELDS; BARIUM SULFATES; CRYSTAL GROWTH; BARITE; MEASURING METHODS; MICROSCOPY; ADSORPTION; BENCH-SCALE EXPERIMENTS; SCALING; INHIBITION
OSTI ID:
491913
Research Organizations:
Norske Sivilingenioerers Forening, Oslo (Norway)
Country of Origin:
Norway
Language:
English
Other Identifying Numbers:
Other: ON: DE97753132; TRN: NO9705212
Availability:
OSTI as DE97753132
Submitting Site:
NW
Size:
23 p.
Announcement Date:
Jul 23, 1997

Citation Formats

Graham, G M, and Sorbie, K S. Visualising the Micro World of Chemical/Geochemical Interactions Using Atomic Force Microscopy (AFM). Norway: N. p., 1996. Web.
Graham, G M, & Sorbie, K S. Visualising the Micro World of Chemical/Geochemical Interactions Using Atomic Force Microscopy (AFM). Norway.
Graham, G M, and Sorbie, K S. 1996. "Visualising the Micro World of Chemical/Geochemical Interactions Using Atomic Force Microscopy (AFM)." Norway.
@misc{etde_491913,
title = {Visualising the Micro World of Chemical/Geochemical Interactions Using Atomic Force Microscopy (AFM)}
author = {Graham, G M, and Sorbie, K S}
abstractNote = {Scanning force microscopy, in particular AFM (Atomic Force Microscopy), provides a particular useful and interesting tool for the examination of surface structure at the near-atomic level. AFM is particularly well suited to the study of interactions at the surface in aqueous solutions using real time in-situ measurements. In this paper there is presented AFM images showing in situ crystal growth from supersaturated BaSO{sub 4} solutions onto the surface of barite. Growth structures in the form of spiral crystal growth features, presumably originating from screw dislocations, are illustrated. AFM images of novel scale crystal growth inhibition experiments are presented. Examination of the manner in which generically different species adsorb onto growth structures may help to explain mechanistic differences in the way which different inhibitor species perform against barium sulphate scale formation. Adsorption of polyacrylamide species onto mica surfaces have been viewed. The general utility of AFM to a number of other common surface interactions in oil field chemistry will be discussed. 17 refs., 3 figs.}
place = {Norway}
year = {1996}
month = {Dec}
}