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INTRAMOLECULAR ISOTOPE EFFECTS IN HYDROCARBON MASS SPECTRA

Abstract

Approximate calculations based on the quasi-equilibrium rate theory of the origin of mass spectra are shown to lead to an approximately correct magnitude for the intramolecular ( pi /sup -/) isotope effect on C--H bond dissociation probabilities of various deuterohydrocarbons. (auth)
Publication Date:
Jul 15, 1963
Product Type:
Conference
Report Number:
CONF-296-2; AED-Conf-63-144-4
Reference Number:
NSA-18-001721
Resource Relation:
Conference: Symposium on Unimolecular Reactions in the Mass Spectrometer and Related Topics in Chemical Kinetics, Salt Lake City, UT (United States), 7-10 Jul 1963
Subject:
CHEMISTRY; AMINES; BINDING ENERGY; BOROHYDRIDES; BORON; BORON BROMIDES; BORON CHLORIDES; BORON COMPOUNDS; BORON FLUORIDES; BORON HYDRIDES; BORON NITRIDES; BORON OXIDES; CARBON; CONFIGURATION; CRYSTALS; DECOMPOSITION; DEUTERIUM COMPOUNDS; DIAGRAMS; ENERGY; ENTHALPY; ENTROPY; EQUATIONS; FLUORINE; FREE ENERGY; HIGH TEMPERATURE; HYDRAZINE; HYDROCARBONS; HYDROFLUORIC ACID; HYDROGEN; ISOMERS; ISOTOPE EFFECTS; LATTICES; LITHIUM COMPOUNDS; LITHIUM OXIDES; MASS SPECTROMETERS; MATHEMATICS; METHYL RADICALS; MINERAL ACIDS; MOLECULES; NUMERICALS; SODIUM COMPOUNDS; TABLES; TEMPERATURE; THERMODYNAMICS; VARIATIONS
OSTI ID:
4877740
Research Organizations:
Shell Development Co., Emeryville, CA (United States)
Country of Origin:
United States
Language:
English
Submitting Site:
DTIE
Size:
Pages: 13
Announcement Date:
May 02, 2013

Citation Formats

Stevenson, D. P., and Schachtschneider, J. H. INTRAMOLECULAR ISOTOPE EFFECTS IN HYDROCARBON MASS SPECTRA. United States: N. p., 1963. Web.
Stevenson, D. P., & Schachtschneider, J. H. INTRAMOLECULAR ISOTOPE EFFECTS IN HYDROCARBON MASS SPECTRA. United States.
Stevenson, D. P., and Schachtschneider, J. H. 1963. "INTRAMOLECULAR ISOTOPE EFFECTS IN HYDROCARBON MASS SPECTRA." United States.
@misc{etde_4877740,
title = {INTRAMOLECULAR ISOTOPE EFFECTS IN HYDROCARBON MASS SPECTRA}
author = {Stevenson, D. P., and Schachtschneider, J. H.}
abstractNote = {Approximate calculations based on the quasi-equilibrium rate theory of the origin of mass spectra are shown to lead to an approximately correct magnitude for the intramolecular ( pi /sup -/) isotope effect on C--H bond dissociation probabilities of various deuterohydrocarbons. (auth)}
place = {United States}
year = {1963}
month = {Jul}
}