Abstract
Methane activation by non-radical method and especially possibilities to heterogenize the homogeneous non-radical system of Periana et al. was studied. Varied loadings of Pd and Hg were ion exchanged to acidic ZSM-5 zeolites with two different Si/A1 ratios. Activation was tested in tubular flow reactor and the outcoming gas was analyzed with quadrupole mass spectrometer. Catalysts, fresh and used, were characterized by XRF and XRD spectroscopies. The methane activation was observed on tested catalysts. However, the activation was concluded to occur mainly through radical reaction and only to some extent by the expected non-radical mechanism. (author) (9 refs.)
Kataja, K;
Huuska, M;
Karinto, K;
Maijanen, A;
Reinikainen, M;
Kiviaho, J;
Hase, A
[1]
- VTT Chemical Technology, Espoo (Finland)
Citation Formats
Kataja, K, Huuska, M, Karinto, K, Maijanen, A, Reinikainen, M, Kiviaho, J, and Hase, A.
Methane activation on palladium and mercury loaded solid supports.
Finland: N. p.,
1996.
Web.
Kataja, K, Huuska, M, Karinto, K, Maijanen, A, Reinikainen, M, Kiviaho, J, & Hase, A.
Methane activation on palladium and mercury loaded solid supports.
Finland.
Kataja, K, Huuska, M, Karinto, K, Maijanen, A, Reinikainen, M, Kiviaho, J, and Hase, A.
1996.
"Methane activation on palladium and mercury loaded solid supports."
Finland.
@misc{etde_464542,
title = {Methane activation on palladium and mercury loaded solid supports}
author = {Kataja, K, Huuska, M, Karinto, K, Maijanen, A, Reinikainen, M, Kiviaho, J, and Hase, A}
abstractNote = {Methane activation by non-radical method and especially possibilities to heterogenize the homogeneous non-radical system of Periana et al. was studied. Varied loadings of Pd and Hg were ion exchanged to acidic ZSM-5 zeolites with two different Si/A1 ratios. Activation was tested in tubular flow reactor and the outcoming gas was analyzed with quadrupole mass spectrometer. Catalysts, fresh and used, were characterized by XRF and XRD spectroscopies. The methane activation was observed on tested catalysts. However, the activation was concluded to occur mainly through radical reaction and only to some extent by the expected non-radical mechanism. (author) (9 refs.)}
place = {Finland}
year = {1996}
month = {Dec}
}
title = {Methane activation on palladium and mercury loaded solid supports}
author = {Kataja, K, Huuska, M, Karinto, K, Maijanen, A, Reinikainen, M, Kiviaho, J, and Hase, A}
abstractNote = {Methane activation by non-radical method and especially possibilities to heterogenize the homogeneous non-radical system of Periana et al. was studied. Varied loadings of Pd and Hg were ion exchanged to acidic ZSM-5 zeolites with two different Si/A1 ratios. Activation was tested in tubular flow reactor and the outcoming gas was analyzed with quadrupole mass spectrometer. Catalysts, fresh and used, were characterized by XRF and XRD spectroscopies. The methane activation was observed on tested catalysts. However, the activation was concluded to occur mainly through radical reaction and only to some extent by the expected non-radical mechanism. (author) (9 refs.)}
place = {Finland}
year = {1996}
month = {Dec}
}