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Effectiveness factors for a commercial steam reforming (Ni) catalyst and for a calcined dolomite used downstream biomass gasifiers

Abstract

A commercial steam reforming catalyst from BASF, the G1-25 S one, and a calcined dolomite, Norte-1, from Cantabria-Spain, have been used, once crushed and sieved to different particle fractions between 1.0 and 4.0 mm. The materials have been tested downstream small pilot biomass gasifiers, bubbling fluidized bed type, gasifying with air and with steam. The Thiele modulus and the effectiveness factor have been calculated at temperatures of 750-850 deg C. It is experimentally shown that diffusion control plays an important part when particle size is larger than ca. 0.5 mm. This has to be taken into account when comparing the quality of the solids for tar elimination. (author) (5 refs.)
Authors:
Corella, J; Narvaez, I; Orio, A [1] 
  1. Madrid Univ. (Spain). Dept. of Chem. Eng.
Publication Date:
Dec 31, 1996
Product Type:
Conference
Report Number:
VTT-SYMP-163; CONF-9601128-
Reference Number:
SCA: 090900; PA: FI-97:003268; EDB-97:060323; SN: 97001773135
Resource Relation:
Conference: 2. symposium of the VTT research programme on chemical reaction mechanisms, Espoo (Finland), 29-30 Jan 1996; Other Information: PBD: 1996; Related Information: Is Part Of New catalysts for clean environment; Maijanen, A.; Hase, A. [eds.] [VTT Chemical Technology, Espoo (Finland)]; PB: 264 p.
Subject:
09 BIOMASS FUELS; BIOMASS; GASIFICATION; HOT GAS CLEANUP; CATALYSTS; FLUIDIZED BEDS; TAR; PILOT PLANTS; CHEMICAL REACTION KINETICS; PARTICLE SIZE
OSTI ID:
464539
Research Organizations:
Technical Research Centre of Finland, Espoo (Finland)
Country of Origin:
Finland
Language:
English
Other Identifying Numbers:
Other: ON: DE97740080; ISBN 951-38-4554-0; TRN: FI9703268
Availability:
OSTI as DE97740080
Submitting Site:
FI
Size:
pp. 185-190
Announcement Date:
May 14, 1997

Citation Formats

Corella, J, Narvaez, I, and Orio, A. Effectiveness factors for a commercial steam reforming (Ni) catalyst and for a calcined dolomite used downstream biomass gasifiers. Finland: N. p., 1996. Web.
Corella, J, Narvaez, I, & Orio, A. Effectiveness factors for a commercial steam reforming (Ni) catalyst and for a calcined dolomite used downstream biomass gasifiers. Finland.
Corella, J, Narvaez, I, and Orio, A. 1996. "Effectiveness factors for a commercial steam reforming (Ni) catalyst and for a calcined dolomite used downstream biomass gasifiers." Finland.
@misc{etde_464539,
title = {Effectiveness factors for a commercial steam reforming (Ni) catalyst and for a calcined dolomite used downstream biomass gasifiers}
author = {Corella, J, Narvaez, I, and Orio, A}
abstractNote = {A commercial steam reforming catalyst from BASF, the G1-25 S one, and a calcined dolomite, Norte-1, from Cantabria-Spain, have been used, once crushed and sieved to different particle fractions between 1.0 and 4.0 mm. The materials have been tested downstream small pilot biomass gasifiers, bubbling fluidized bed type, gasifying with air and with steam. The Thiele modulus and the effectiveness factor have been calculated at temperatures of 750-850 deg C. It is experimentally shown that diffusion control plays an important part when particle size is larger than ca. 0.5 mm. This has to be taken into account when comparing the quality of the solids for tar elimination. (author) (5 refs.)}
place = {Finland}
year = {1996}
month = {Dec}
}