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New hydride compounds of 1,4-diazabicyclo[2.2.2]octane and its dication with borine and tetrahydridoborate anion and products of their transformations; Novye gidridnye soedineniya 1,4-diazabitsiklo[2.2.2]oktana i ego dikationa s borinom i tetergidridoborat-anionom i produkty ikh prevrashcheniya

Journal Article:

Abstract

New compounds [dabcoH{sub 2}](BH{sub 4}){sub 2}, dabco(BH{sub 3}){sub 2}2H{sub 2}, [dabco(BH{sub 3}){sub 2}H{sub 2}]{sub n} have been synthesized by means of interaction between dihydrochloride of 1,4-diazobicyclo[2.2.2] octane (dabco) and NaBH{sub 4} in the medium of nonaqueous solvents (glyme, diglyme, tetrahydrofuran, dimethylsulfoxide) and identified by the methods of element analysis, conductometry, {sup 1}H, {sup 11}B, {sup 14}N NMR, IR spectroscopy and thermal analysis. A mechanism is suggested and the conditions are defined for mutual transformations of the compounds studied. Their ability to bind reversibly molecular hydrogen has been revealed for the first time. 19 refs.; 3 figs.; 1 tab.
Publication Date:
Dec 31, 1996
Product Type:
Journal Article
Reference Number:
SCA: 400201; PA: AIX-28:027394; EDB-97:050398; SN: 97001757739
Resource Relation:
Journal Name: Zhurnal Obshchej Khimii; Journal Volume: 66; Journal Issue: 7; Other Information: PBD: 1996
Subject:
40 CHEMISTRY; BOROHYDRIDES; CHEMICAL PREPARATION; CHEMICAL REACTIONS; CHEMICAL COMPOSITION; DENSITY; ELECTRIC CONDUCTIVITY; INFRARED SPECTRA; NMR SPECTRA; ORGANIC NITROGEN COMPOUNDS; ORGANIC SOLVENTS
OSTI ID:
448330
Country of Origin:
Russian Federation
Language:
Russian
Other Identifying Numbers:
Journal ID: ZOKHA4; ISSN 0044-460X; TRN: RU9700220027394
Submitting Site:
INIS
Size:
pp. 1202-1208
Announcement Date:
Apr 01, 1997

Journal Article:

Citation Formats

Shevchenko, Yu N, Yashina, N I, Markova, O Z, and Trachevskij, V V. New hydride compounds of 1,4-diazabicyclo[2.2.2]octane and its dication with borine and tetrahydridoborate anion and products of their transformations; Novye gidridnye soedineniya 1,4-diazabitsiklo[2.2.2]oktana i ego dikationa s borinom i tetergidridoborat-anionom i produkty ikh prevrashcheniya. Russian Federation: N. p., 1996. Web.
Shevchenko, Yu N, Yashina, N I, Markova, O Z, & Trachevskij, V V. New hydride compounds of 1,4-diazabicyclo[2.2.2]octane and its dication with borine and tetrahydridoborate anion and products of their transformations; Novye gidridnye soedineniya 1,4-diazabitsiklo[2.2.2]oktana i ego dikationa s borinom i tetergidridoborat-anionom i produkty ikh prevrashcheniya. Russian Federation.
Shevchenko, Yu N, Yashina, N I, Markova, O Z, and Trachevskij, V V. 1996. "New hydride compounds of 1,4-diazabicyclo[2.2.2]octane and its dication with borine and tetrahydridoborate anion and products of their transformations; Novye gidridnye soedineniya 1,4-diazabitsiklo[2.2.2]oktana i ego dikationa s borinom i tetergidridoborat-anionom i produkty ikh prevrashcheniya." Russian Federation.
@misc{etde_448330,
title = {New hydride compounds of 1,4-diazabicyclo[2.2.2]octane and its dication with borine and tetrahydridoborate anion and products of their transformations; Novye gidridnye soedineniya 1,4-diazabitsiklo[2.2.2]oktana i ego dikationa s borinom i tetergidridoborat-anionom i produkty ikh prevrashcheniya}
author = {Shevchenko, Yu N, Yashina, N I, Markova, O Z, and Trachevskij, V V}
abstractNote = {New compounds [dabcoH{sub 2}](BH{sub 4}){sub 2}, dabco(BH{sub 3}){sub 2}2H{sub 2}, [dabco(BH{sub 3}){sub 2}H{sub 2}]{sub n} have been synthesized by means of interaction between dihydrochloride of 1,4-diazobicyclo[2.2.2] octane (dabco) and NaBH{sub 4} in the medium of nonaqueous solvents (glyme, diglyme, tetrahydrofuran, dimethylsulfoxide) and identified by the methods of element analysis, conductometry, {sup 1}H, {sup 11}B, {sup 14}N NMR, IR spectroscopy and thermal analysis. A mechanism is suggested and the conditions are defined for mutual transformations of the compounds studied. Their ability to bind reversibly molecular hydrogen has been revealed for the first time. 19 refs.; 3 figs.; 1 tab.}
journal = {Zhurnal Obshchej Khimii}
issue = {7}
volume = {66}
journal type = {AC}
place = {Russian Federation}
year = {1996}
month = {Dec}
}