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Photocatalysts: ambient temperature destruction of VOCs

Abstract

Photocatalysis was a failure as a solar energy driven organic synthesis technique, but as this study indicates, it has undergone a renaissance as a promising treatment method for volatile organic compounds (VOCs) in air streams. Photocatalytic oxidation (PCO) relies upon the ability of certain semiconductors to be stimulated by UV radiation. UV light excites valence band electrons in the semiconductor catalyst to jump to a conductance band leaving holes in the valence band. The electrons and holes can react with compounds such as organic contaminants present in an air stream. Hallmarks of the technology include rapid destruction kinetics for many VOCs at ambient temperature and efficient use energy in the form of UV-A photons. Studies clearly indicate that PCO is competitive on capital cost and offers significant operating cost savings on selected applications. 6 refs., 3 tabs., 2 figs.
Authors:
Miller, R [1] 
  1. IT Corp., Oak Ridge, TN (United States)
Publication Date:
Dec 31, 1994
Product Type:
Miscellaneous
Report Number:
CONF-940952-
Reference Number:
SCA: 540120; 140400; PA: CANM-96:002584; EDB-96:158930; SN: 96001684993
Resource Relation:
Conference: 1. North American conference and exhibition on emerging clean air technologies and business opportunities: meeting global air challenges through partnerships, Toronto (Canada), 26-30 Sep 1994; Other Information: DN: Proceedings in three volumes.; PBD: 1994; Related Information: Is Part Of Conference proceedings from Clean air `94; PB: 1463 p.
Subject:
54 ENVIRONMENTAL SCIENCES; 14 SOLAR ENERGY; SOLAR ENERGY; AIR POLLUTION CONTROL; CATALYSIS; VOLATILE MATTER; ORGANIC COMPOUNDS; ECONOMICS; ULTRAVIOLET RADIATION; COST
Sponsoring Organizations:
Environment Canada, Hull, PQ (Canada); Environmental Protection Agency, Ada, OK (United States); Department of Foreign Affairs and International Trade, Ottawa, ON (Canada); Air and Waste Management Association, ON (Canada). Ontario Section; Department of Commerce, Washington, DC (United States); Quebec Ministere de l`Environnement, Ste-Foy, PQ (Canada); Industry Canada, Ottawa, ON (Canada). Resource and Technologies Directorate; Department of Energy, Washington, DC (United States); Natural Resources Canada, Ottawa, ON (Canada); Ontario Ministry of Environment and Energy, Hamilton, ON (Canada)
OSTI ID:
388919
Country of Origin:
Canada
Language:
English
Other Identifying Numbers:
TRN: CA9602584
Availability:
Available from Prospectus Publishing, 180 Elgin Street, suite 900, Ottawa, K2P 2K3
Submitting Site:
CANM
Size:
pp. 951-959
Announcement Date:
Jan 20, 2004

Citation Formats

Miller, R. Photocatalysts: ambient temperature destruction of VOCs. Canada: N. p., 1994. Web.
Miller, R. Photocatalysts: ambient temperature destruction of VOCs. Canada.
Miller, R. 1994. "Photocatalysts: ambient temperature destruction of VOCs." Canada.
@misc{etde_388919,
title = {Photocatalysts: ambient temperature destruction of VOCs}
author = {Miller, R}
abstractNote = {Photocatalysis was a failure as a solar energy driven organic synthesis technique, but as this study indicates, it has undergone a renaissance as a promising treatment method for volatile organic compounds (VOCs) in air streams. Photocatalytic oxidation (PCO) relies upon the ability of certain semiconductors to be stimulated by UV radiation. UV light excites valence band electrons in the semiconductor catalyst to jump to a conductance band leaving holes in the valence band. The electrons and holes can react with compounds such as organic contaminants present in an air stream. Hallmarks of the technology include rapid destruction kinetics for many VOCs at ambient temperature and efficient use energy in the form of UV-A photons. Studies clearly indicate that PCO is competitive on capital cost and offers significant operating cost savings on selected applications. 6 refs., 3 tabs., 2 figs.}
place = {Canada}
year = {1994}
month = {Dec}
}