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Reaction of pyridine-N-oxides with halogens; Vzaimodejstvie piridin-N-oksidov s galogenami

Abstract

By the methods of conductometry, NMR and IR spectroscopy it has been ascertained that interaction of pyridine-N-oxides with bromine, iodine and interhalides (ICl and IBr) gives rise to the formation of crystal complexes of 1:1 composition. The complexes mentioned are of presumably ionic structure: [RC{sub 5}H{sub 4}N-O...X...O-NC{sub 5}H{sub 4}R]{sup +}[Y-X-Y]{sup -},where X,Y = Cl,Br,I.
Authors:
Kanibolotskij, A L; Mikhzajlov, V A; Savelova, V A [1] 
  1. AN Ukrainskoj SSR, Donetsk (Ukraine). Inst. Fiziko-Organicheskoj Khimii i Uglekhimii
Publication Date:
Dec 31, 1994
Product Type:
Journal Article
Reference Number:
SCA: 400201; PA: AIX-27:067456; EDB-96:144341; SN: 96001670403
Resource Relation:
Journal Name: Zhurnal Organicheskoj Khimii; Journal Volume: 30; Journal Issue: 7; Other Information: PBD: 1994
Subject:
40 CHEMISTRY; IODINE; CHEMICAL REACTIONS; IODINE BROMIDES; IODINE CHLORIDES; COORDINATION VALENCES; INFRARED SPECTRA; IODINE COMPLEXES; MOLECULAR STRUCTURE; NMR SPECTRA; ORGANIC OXYGEN COMPOUNDS; PYRIDINES
OSTI ID:
372963
Country of Origin:
Russian Federation
Language:
Russian
Other Identifying Numbers:
Journal ID: ZORKAE; ISSN 0514-7492; TRN: RU9603594067456
Submitting Site:
INIS
Size:
pp. 1053-1058
Announcement Date:
Oct 11, 1996

Citation Formats

Kanibolotskij, A L, Mikhzajlov, V A, and Savelova, V A. Reaction of pyridine-N-oxides with halogens; Vzaimodejstvie piridin-N-oksidov s galogenami. Russian Federation: N. p., 1994. Web.
Kanibolotskij, A L, Mikhzajlov, V A, & Savelova, V A. Reaction of pyridine-N-oxides with halogens; Vzaimodejstvie piridin-N-oksidov s galogenami. Russian Federation.
Kanibolotskij, A L, Mikhzajlov, V A, and Savelova, V A. 1994. "Reaction of pyridine-N-oxides with halogens; Vzaimodejstvie piridin-N-oksidov s galogenami." Russian Federation.
@misc{etde_372963,
title = {Reaction of pyridine-N-oxides with halogens; Vzaimodejstvie piridin-N-oksidov s galogenami}
author = {Kanibolotskij, A L, Mikhzajlov, V A, and Savelova, V A}
abstractNote = {By the methods of conductometry, NMR and IR spectroscopy it has been ascertained that interaction of pyridine-N-oxides with bromine, iodine and interhalides (ICl and IBr) gives rise to the formation of crystal complexes of 1:1 composition. The complexes mentioned are of presumably ionic structure: [RC{sub 5}H{sub 4}N-O...X...O-NC{sub 5}H{sub 4}R]{sup +}[Y-X-Y]{sup -},where X,Y = Cl,Br,I.}
journal = []
issue = {7}
volume = {30}
journal type = {AC}
place = {Russian Federation}
year = {1994}
month = {Dec}
}