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On the improvement of mechanical properties of monolithic silica aerogels (for transparent insulating material); Silica aerogel (tomei dannetsu zairyo) kyodo no kaizen ni tsuite

Abstract

Study was made on improvement of the strength of silica aerogel as transparent insulating material. Silica aerogel is a low-density porous material with high heat insulation and transparency. To develop a insulating material with high transparency, monolithic silica aerogel was studied. For direct use of it for windows, its strength improvement was attempted. The aerogel was prepared by supercritical drying (alcohol or CO2) of silica wet gel obtained by hydrolysis and condensation of silicon alkoxide solution. To prepare the aerogel bonded on plate glass for strength improvement, the aerogel was bonded to alkoxide by exposing active silanol radical through F-etching of plate glass surface. However, to obtain the practical large-area bonded aerogel, shrinkage control of the aerogel in supercritical drying was necessary. Addition of Laponite into a silica network for strength improvement by polymer increased the bending strength by 50%. Although some reduction of its transparency was observed because of clouding, its heat insulation was stable. Further strength improvement is necessary for its practical use. 5 figs., 1 tab.
Authors:
Tajiri, K; Igarashi, K; Tanemura, S [1] 
  1. National Industrial Research Institute of Nagoya, Nagoya (Japan)
Publication Date:
Nov 25, 1997
Product Type:
Conference
Report Number:
ETDE/JP-98753622; CONF-9711143-
Reference Number:
SCA: 360603; 360606; 360601; 320107; PA: JP-98:0G1104; SN: 98001983495
Resource Relation:
Conference: 1997 JSES/JWEA joint conference, Taiyo/furyoku energy koen, Aichi (Japan), 28-29 Nov 1997; Other Information: PBD: 25 Nov 1997; Related Information: Is Part Of Proceedings of JSES/JWEA Joint Conference (1997); PB: 454 p.; Taiyo/Furyoku energy koen ronbunshu (1997)
Subject:
36 MATERIALS SCIENCE; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; SILICA GEL; PARTICULATES; COLLOIDS; POROUS MATERIALS; OPACITY; THERMAL INSULATION; MECHANICAL PROPERTIES; AUGMENTATION; WINDOWS; ALKOXIDES; HYDROLYSIS; DEHYDROCYCLIZATION; SUPERCRITICAL STATE; DRYING; GLASS; ETCHING; SURFACE TREATMENTS; SHRINKAGE; FILLERS; CLAYS
OSTI ID:
366048
Research Organizations:
Japan Solar Energy Society, Tokyo (Japan)
Country of Origin:
Japan
Language:
Japanese
Other Identifying Numbers:
Other: ON: DE98753622; TRN: JN98G1104
Availability:
Available from Japan Solar Energy Society, 44-14, Yoyogi 2-chome, Shibuya-ku, Tokyo, Japan; OSTI as DE98753622
Submitting Site:
NEDO
Size:
pp. 353-356
Announcement Date:
Sep 02, 1999

Citation Formats

Tajiri, K, Igarashi, K, and Tanemura, S. On the improvement of mechanical properties of monolithic silica aerogels (for transparent insulating material); Silica aerogel (tomei dannetsu zairyo) kyodo no kaizen ni tsuite. Japan: N. p., 1997. Web.
Tajiri, K, Igarashi, K, & Tanemura, S. On the improvement of mechanical properties of monolithic silica aerogels (for transparent insulating material); Silica aerogel (tomei dannetsu zairyo) kyodo no kaizen ni tsuite. Japan.
Tajiri, K, Igarashi, K, and Tanemura, S. 1997. "On the improvement of mechanical properties of monolithic silica aerogels (for transparent insulating material); Silica aerogel (tomei dannetsu zairyo) kyodo no kaizen ni tsuite." Japan.
@misc{etde_366048,
title = {On the improvement of mechanical properties of monolithic silica aerogels (for transparent insulating material); Silica aerogel (tomei dannetsu zairyo) kyodo no kaizen ni tsuite}
author = {Tajiri, K, Igarashi, K, and Tanemura, S}
abstractNote = {Study was made on improvement of the strength of silica aerogel as transparent insulating material. Silica aerogel is a low-density porous material with high heat insulation and transparency. To develop a insulating material with high transparency, monolithic silica aerogel was studied. For direct use of it for windows, its strength improvement was attempted. The aerogel was prepared by supercritical drying (alcohol or CO2) of silica wet gel obtained by hydrolysis and condensation of silicon alkoxide solution. To prepare the aerogel bonded on plate glass for strength improvement, the aerogel was bonded to alkoxide by exposing active silanol radical through F-etching of plate glass surface. However, to obtain the practical large-area bonded aerogel, shrinkage control of the aerogel in supercritical drying was necessary. Addition of Laponite into a silica network for strength improvement by polymer increased the bending strength by 50%. Although some reduction of its transparency was observed because of clouding, its heat insulation was stable. Further strength improvement is necessary for its practical use. 5 figs., 1 tab.}
place = {Japan}
year = {1997}
month = {Nov}
}