Abstract
Nitrogen, hydrogen and deuterium atoms are matrix-isolated in solid N{sub 2} by deposition from gas phase and studied by electron spin resonance (ESR). These atoms are found to be trapped at the substitutional position of the cryo crystal lattice. The ESR line-widths of the N atoms in the recorded spectra appear to be one-fourth as those cites by most authors. It is shown that a calculation is possible which gives a theoretical linewidth matching the experimental one. Two distinct types of matrix surrounding are possible for the substitutional nitrogen atoms, one of which being consistent with the non distorted N{sub 2} crystal lattice. Hydrogen and deuterium ESR linewidths are found to broaden due to the zero point vibration of the atoms. Spin-lattice relaxation times of N,H, and D atoms in solid N{sub 2} matrix are presented.
Dmitriev, Yu A;
Zhitnikov, R A
[1]
- AN SSSR, Leningrad (Russian Federation). Fiziko-Tekhnicheskij Inst
Citation Formats
Dmitriev, Yu A, and Zhitnikov, R A.
ESR studies of N,H, and D atoms trapped in solid molecular N{sub 2} matrix; Issledovanie metodom EhPR atomov N,H i D, zakhvachennykh v matritse tverdogo molekulyarnogo azota.
Ukraine: N. p.,
1998.
Web.
Dmitriev, Yu A, & Zhitnikov, R A.
ESR studies of N,H, and D atoms trapped in solid molecular N{sub 2} matrix; Issledovanie metodom EhPR atomov N,H i D, zakhvachennykh v matritse tverdogo molekulyarnogo azota.
Ukraine.
Dmitriev, Yu A, and Zhitnikov, R A.
1998.
"ESR studies of N,H, and D atoms trapped in solid molecular N{sub 2} matrix; Issledovanie metodom EhPR atomov N,H i D, zakhvachennykh v matritse tverdogo molekulyarnogo azota."
Ukraine.
@misc{etde_318318,
title = {ESR studies of N,H, and D atoms trapped in solid molecular N{sub 2} matrix; Issledovanie metodom EhPR atomov N,H i D, zakhvachennykh v matritse tverdogo molekulyarnogo azota}
author = {Dmitriev, Yu A, and Zhitnikov, R A}
abstractNote = {Nitrogen, hydrogen and deuterium atoms are matrix-isolated in solid N{sub 2} by deposition from gas phase and studied by electron spin resonance (ESR). These atoms are found to be trapped at the substitutional position of the cryo crystal lattice. The ESR line-widths of the N atoms in the recorded spectra appear to be one-fourth as those cites by most authors. It is shown that a calculation is possible which gives a theoretical linewidth matching the experimental one. Two distinct types of matrix surrounding are possible for the substitutional nitrogen atoms, one of which being consistent with the non distorted N{sub 2} crystal lattice. Hydrogen and deuterium ESR linewidths are found to broaden due to the zero point vibration of the atoms. Spin-lattice relaxation times of N,H, and D atoms in solid N{sub 2} matrix are presented.}
journal = []
issue = {1}
volume = {24}
journal type = {AC}
place = {Ukraine}
year = {1998}
month = {Jan}
}
title = {ESR studies of N,H, and D atoms trapped in solid molecular N{sub 2} matrix; Issledovanie metodom EhPR atomov N,H i D, zakhvachennykh v matritse tverdogo molekulyarnogo azota}
author = {Dmitriev, Yu A, and Zhitnikov, R A}
abstractNote = {Nitrogen, hydrogen and deuterium atoms are matrix-isolated in solid N{sub 2} by deposition from gas phase and studied by electron spin resonance (ESR). These atoms are found to be trapped at the substitutional position of the cryo crystal lattice. The ESR line-widths of the N atoms in the recorded spectra appear to be one-fourth as those cites by most authors. It is shown that a calculation is possible which gives a theoretical linewidth matching the experimental one. Two distinct types of matrix surrounding are possible for the substitutional nitrogen atoms, one of which being consistent with the non distorted N{sub 2} crystal lattice. Hydrogen and deuterium ESR linewidths are found to broaden due to the zero point vibration of the atoms. Spin-lattice relaxation times of N,H, and D atoms in solid N{sub 2} matrix are presented.}
journal = []
issue = {1}
volume = {24}
journal type = {AC}
place = {Ukraine}
year = {1998}
month = {Jan}
}