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Association of ions in LiPF{sub 6} solutions in propylencarbonate and {gamma}-butyrolactone; Assotsiatsiya ionov v rastvorakh LiPF{sub 6} v propilenkarbonate i {gamma}-butirolaktone

Journal Article:

Abstract

Lithium hexafluorophosphate solutions in propylencarbonate and {gamma}-butyrolactone are investigated in a wide ranges of concentrations and temperatures using conductometry, viscosimetry, densimetry methods and measurements of lithium-7 nucleus spin-lattice relaxation rates. Absence of correlations between solution conductivity and ionization ability of solvents, which is conditioned by the prevailing viscosity effect, is shown. Notable effect of ion-dipole interaction on the formation of Li{sup +} ion electric field gradient is ascertained within the framework of ion association model. 15 refs.; 2 figs.; 1 tab.
Publication Date:
Oct 01, 1995
Product Type:
Journal Article
Reference Number:
SCA: 400201; PA: AIX-27:050120; EDB-96:107103; SN: 96001617170
Resource Relation:
Journal Name: Zhurnal Neorganicheskoj Khimii; Journal Volume: 40; Journal Issue: 10; Other Information: PBD: Oct 1995
Subject:
40 CHEMISTRY; LITHIUM COMPOUNDS; ELECTRIC CONDUCTIVITY; SPIN-LATTICE RELAXATION; CHEMICAL COMPOSITION; CONCENTRATION RATIO; FLUORINE COMPOUNDS; ORGANIC SOLVENTS; PHOSPHORUS COMPOUNDS; SOLUTIONS; TEMPERATURE RANGE 0273-0400 K
OSTI ID:
252123
Country of Origin:
Russian Federation
Language:
Russian
Other Identifying Numbers:
Journal ID: ZNOKAQ; ISSN 0044-457X; TRN: RU9602137050120
Submitting Site:
INIS
Size:
pp. 1742-1744
Announcement Date:

Journal Article:

Citation Formats

Plakhotnik, V N, Sukhaya, E M, and Mishustin, A I. Association of ions in LiPF{sub 6} solutions in propylencarbonate and {gamma}-butyrolactone; Assotsiatsiya ionov v rastvorakh LiPF{sub 6} v propilenkarbonate i {gamma}-butirolaktone. Russian Federation: N. p., 1995. Web.
Plakhotnik, V N, Sukhaya, E M, & Mishustin, A I. Association of ions in LiPF{sub 6} solutions in propylencarbonate and {gamma}-butyrolactone; Assotsiatsiya ionov v rastvorakh LiPF{sub 6} v propilenkarbonate i {gamma}-butirolaktone. Russian Federation.
Plakhotnik, V N, Sukhaya, E M, and Mishustin, A I. 1995. "Association of ions in LiPF{sub 6} solutions in propylencarbonate and {gamma}-butyrolactone; Assotsiatsiya ionov v rastvorakh LiPF{sub 6} v propilenkarbonate i {gamma}-butirolaktone." Russian Federation.
@misc{etde_252123,
title = {Association of ions in LiPF{sub 6} solutions in propylencarbonate and {gamma}-butyrolactone; Assotsiatsiya ionov v rastvorakh LiPF{sub 6} v propilenkarbonate i {gamma}-butirolaktone}
author = {Plakhotnik, V N, Sukhaya, E M, and Mishustin, A I}
abstractNote = {Lithium hexafluorophosphate solutions in propylencarbonate and {gamma}-butyrolactone are investigated in a wide ranges of concentrations and temperatures using conductometry, viscosimetry, densimetry methods and measurements of lithium-7 nucleus spin-lattice relaxation rates. Absence of correlations between solution conductivity and ionization ability of solvents, which is conditioned by the prevailing viscosity effect, is shown. Notable effect of ion-dipole interaction on the formation of Li{sup +} ion electric field gradient is ascertained within the framework of ion association model. 15 refs.; 2 figs.; 1 tab.}
journal = {Zhurnal Neorganicheskoj Khimii}
issue = {10}
volume = {40}
journal type = {AC}
place = {Russian Federation}
year = {1995}
month = {Oct}
}