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Electrolytic decomposition of N-nitrosodimethylamine in water

Abstract

The feasibility of electrically reducing N-nitrosodimethylamine (NDMA) in aqueous solutions was studied in a series of bench-scale experiments. The presence of nitrosamines in soil and groundwater is largely associated with missile fuels, but also with pesticides and other chemicals. Inexpensive carbon, stainless steel and nickel electrodes were used to perform the experiments. The electrodes, voltage and solution pH were the variables studied. Results showed that a higher rate of decomposition of NDMA occurred in acidic conditions using a relatively high potential applied to the electrodes. Further studies were suggested to optimize treatment conditions and evaluate the technical and economical feasibility of the process. 9 refs., 2 tabs., 2 figs.
Authors:
Volchek, K; Ladanowski, C; Somers, A; Whittaker, H; [1]  Anantaraman, A [2] 
  1. Environment Canada, Edmonton, AB (Canada). Emergencies Science Div.
  2. Ottawa Univ., ON (Canada). Electrochemical Science and Technology Centre
Publication Date:
Dec 31, 1995
Product Type:
Miscellaneous
Report Number:
CONF-9506359-
Reference Number:
SCA: 540220; PA: CANM-96:001344; EDB-96:101057; SN: 96001607018
Resource Relation:
Conference: 12. technical seminar on chemical spills, Edmonton (Canada), 12-13 Jun 1995; Other Information: PBD: 1995; Related Information: Is Part Of Proceedings of the twelfth technical seminar on chemical spills; PB: 316 p.
Subject:
54 ENVIRONMENTAL SCIENCES; NITROSAMINES; DECONTAMINATION; SOILS; PESTICIDES; REDUCTION; ELECTRIC POTENTIAL; PH VALUE; FEASIBILITY STUDIES
Sponsoring Organizations:
Environment Canada, Edmonton, AB (Canada). Environmental Protection Service; Environment Canada, Ottawa, ON (Canada). Technology Development and Technical Services Branch
OSTI ID:
244384
Research Organizations:
Environment Canada, Ottawa, ON (Canada)
Country of Origin:
Canada
Language:
English
Other Identifying Numbers:
TRN: CA9601344
Availability:
Available from Emergencies Science Division, Environment Canada, Environmental Technology Centre, Ottawa, Ontario, K1A 0H3
Submitting Site:
CANM
Size:
pp. 39-47
Announcement Date:
Jan 18, 2004

Citation Formats

Volchek, K, Ladanowski, C, Somers, A, Whittaker, H, and Anantaraman, A. Electrolytic decomposition of N-nitrosodimethylamine in water. Canada: N. p., 1995. Web.
Volchek, K, Ladanowski, C, Somers, A, Whittaker, H, & Anantaraman, A. Electrolytic decomposition of N-nitrosodimethylamine in water. Canada.
Volchek, K, Ladanowski, C, Somers, A, Whittaker, H, and Anantaraman, A. 1995. "Electrolytic decomposition of N-nitrosodimethylamine in water." Canada.
@misc{etde_244384,
title = {Electrolytic decomposition of N-nitrosodimethylamine in water}
author = {Volchek, K, Ladanowski, C, Somers, A, Whittaker, H, and Anantaraman, A}
abstractNote = {The feasibility of electrically reducing N-nitrosodimethylamine (NDMA) in aqueous solutions was studied in a series of bench-scale experiments. The presence of nitrosamines in soil and groundwater is largely associated with missile fuels, but also with pesticides and other chemicals. Inexpensive carbon, stainless steel and nickel electrodes were used to perform the experiments. The electrodes, voltage and solution pH were the variables studied. Results showed that a higher rate of decomposition of NDMA occurred in acidic conditions using a relatively high potential applied to the electrodes. Further studies were suggested to optimize treatment conditions and evaluate the technical and economical feasibility of the process. 9 refs., 2 tabs., 2 figs.}
place = {Canada}
year = {1995}
month = {Dec}
}