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Atomic Layer Deposition of TiO{sub 2} Thin Films from Ti(O{sup i}Pr){sub 2}(dmae){sub 2} and H{sub 2}O

Abstract

TiO{sub 2} thin films were grown on Si (100) substrates by atomic layer deposition using [Ti(OPr{sup i}){sub 2}(dmae){sub 2}] and water as precursors. The thickness, chemical composition, crystalline structure, and morphology of the deposited films were investigated by transmission electron microscopy, UV spectrometry, X-ray photoelectron spectroscopy, X-ray diffraction, and atomic force microscopy. The results show that TiO{sub 2} ALD using [Ti(OPr{sup i}){sub 2}(dmae){sub 2}] as a precursor is self-controlled at temperatures of 100-300 .deg. C. At the growth temperatures below 300 .deg. C, the surface morphology of the TiO{sub 2} films is smooth and uniform. The TiO{sub 2} film was grown with a preferred orientation toward the [101] direction at 400 .deg. C.
Authors:
Lee, Jae P.; Park, Mi H.; Sung, Myung M.; [1]  Chung, Taek Mo; Kim, Yun Soo [2] 
  1. Kookmin University, Seoul (Korea, Republic of)
  2. Korea Research Institute of Chemical Technology, Daejeon (Korea, Republic of)
Publication Date:
Apr 15, 2004
Product Type:
Journal Article
Resource Relation:
Journal Name: Bulletin of the Korean Chemical Society; Journal Volume: 25; Journal Issue: 4; Other Information: 21 refs, 8 figs
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY; CHEMICAL COMPOSITION; DEPOSITION; MORPHOLOGY; SUBSTRATES; SURFACES; THICKNESS; THIN FILMS; TITANIUM OXIDES
OSTI ID:
22543500
Country of Origin:
Korea, Republic of
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0253-2964; TRN: KR1603399114505
Submitting Site:
KRN
Size:
page(s) 475-479
Announcement Date:
Dec 09, 2016

Citation Formats

Lee, Jae P., Park, Mi H., Sung, Myung M., Chung, Taek Mo, and Kim, Yun Soo. Atomic Layer Deposition of TiO{sub 2} Thin Films from Ti(O{sup i}Pr){sub 2}(dmae){sub 2} and H{sub 2}O. Korea, Republic of: N. p., 2004. Web.
Lee, Jae P., Park, Mi H., Sung, Myung M., Chung, Taek Mo, & Kim, Yun Soo. Atomic Layer Deposition of TiO{sub 2} Thin Films from Ti(O{sup i}Pr){sub 2}(dmae){sub 2} and H{sub 2}O. Korea, Republic of.
Lee, Jae P., Park, Mi H., Sung, Myung M., Chung, Taek Mo, and Kim, Yun Soo. 2004. "Atomic Layer Deposition of TiO{sub 2} Thin Films from Ti(O{sup i}Pr){sub 2}(dmae){sub 2} and H{sub 2}O." Korea, Republic of.
@misc{etde_22543500,
title = {Atomic Layer Deposition of TiO{sub 2} Thin Films from Ti(O{sup i}Pr){sub 2}(dmae){sub 2} and H{sub 2}O}
author = {Lee, Jae P., Park, Mi H., Sung, Myung M., Chung, Taek Mo, and Kim, Yun Soo}
abstractNote = {TiO{sub 2} thin films were grown on Si (100) substrates by atomic layer deposition using [Ti(OPr{sup i}){sub 2}(dmae){sub 2}] and water as precursors. The thickness, chemical composition, crystalline structure, and morphology of the deposited films were investigated by transmission electron microscopy, UV spectrometry, X-ray photoelectron spectroscopy, X-ray diffraction, and atomic force microscopy. The results show that TiO{sub 2} ALD using [Ti(OPr{sup i}){sub 2}(dmae){sub 2}] as a precursor is self-controlled at temperatures of 100-300 .deg. C. At the growth temperatures below 300 .deg. C, the surface morphology of the TiO{sub 2} films is smooth and uniform. The TiO{sub 2} film was grown with a preferred orientation toward the [101] direction at 400 .deg. C.}
journal = []
issue = {4}
volume = {25}
journal type = {AC}
place = {Korea, Republic of}
year = {2004}
month = {Apr}
}