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ETDEWEB   /       /    Preparation and study of chlorine mono-fluoride and of chlorine oxi-fluorides; Preparation et etude du monofluorure et des oxyfluorures de chlore

Preparation and study of chlorine mono-fluoride and of chlorine oxi-fluorides; Preparation et etude du monofluorure et des oxyfluorures de chlore

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Abstract

The objective of this engineering school report was to be a contribution to the study of a family of fluorine compounds: chlorine mono-fluoride (ClF), chlorine fluoride oxide (ClOF), chloryl fluoride (ClO{sub 2}F), perchloryl fluoride (ClO{sub 3}F) and perchloryl oxi-fluoride (ClO{sub 4}F). Such a study required very pure products to be obtained in order to be able to characterize them by different methods (infrared, micro-sublimation, and chromatography). The thermolysis of ClO{sub 2}F and ClO{sub 4}F has been particularly studied, and magnetic resonance has been used to establish a relationship between fluorine chemical displacement and the electro-negativity of the F-X bond where X represents the atom group to which fluorine is bonded.
Authors:
Publication Date:
Jul 01, 1969
Product Type:
Thesis/Dissertation
Report Number:
FRCEA-TH-7497
Resource Relation:
Other Information: 44 refs.; Available from the INIS Liaison Officer for France, see the 'INIS contacts' section of the INIS web site for current contact and E-mail addresses: http://www.iaea.org/inis/Contacts/; Diplome d'Ingenieur C.N.A.M., Specialite: Chimie Industrielle
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ATOMIC DISPLACEMENTS; CALIBRATION; CHEMICAL ANALYSIS; CHEMICAL BONDS; CHEMICAL STATE; CHLORINE FLUORIDES; CHROMATOGRAPHY; FLUORINE; IMPURITIES; INFRARED SPECTROMETERS; ISOTOPE SEPARATION; MAGNETIC RESONANCE; OXYFLUORIDES; PURIFICATION; SUBLIMATION
OSTI ID:
22511688
Research Organizations:
Conservatoire National des Arts et Metiers - C.N.A.M. (France); Commissariat a l'energie atomique et aux energies alternatives - CEA, Departement de Physico-Chimie (France)
Country of Origin:
France
Language:
French
Other Identifying Numbers:
TRN: FR1601817082365
Availability:
Available from INIS in electronic form
Submitting Site:
INIS
Size:
114 page(s)
Announcement Date:
Sep 08, 2016

Thesis/Dissertation:

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Citation Formats

Macheteau, Yves. Preparation and study of chlorine mono-fluoride and of chlorine oxi-fluorides; Preparation et etude du monofluorure et des oxyfluorures de chlore. France: N. p., 1969. Web.
Macheteau, Yves. Preparation and study of chlorine mono-fluoride and of chlorine oxi-fluorides; Preparation et etude du monofluorure et des oxyfluorures de chlore. France.
Macheteau, Yves. 1969. "Preparation and study of chlorine mono-fluoride and of chlorine oxi-fluorides; Preparation et etude du monofluorure et des oxyfluorures de chlore." France.
@misc{etde_22511688,
title = {Preparation and study of chlorine mono-fluoride and of chlorine oxi-fluorides; Preparation et etude du monofluorure et des oxyfluorures de chlore}
 author = {Macheteau, Yves}
 abstractNote = {The objective of this engineering school report was to be a contribution to the study of a family of fluorine compounds: chlorine mono-fluoride (ClF), chlorine fluoride oxide (ClOF), chloryl fluoride (ClO{sub 2}F), perchloryl fluoride (ClO{sub 3}F) and perchloryl oxi-fluoride (ClO{sub 4}F). Such a study required very pure products to be obtained in order to be able to characterize them by different methods (infrared, micro-sublimation, and chromatography). The thermolysis of ClO{sub 2}F and ClO{sub 4}F has been particularly studied, and magnetic resonance has been used to establish a relationship between fluorine chemical displacement and the electro-negativity of the F-X bond where X represents the atom group to which fluorine is bonded.}
 place = {France}
 year = {1969}
 month = {Jul}
 }