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A novel electro analytical nanosensor based on graphene oxide/silver nanoparticles for simultaneous determination of quercetin and morin

Abstract

Graphical abstract: - Abstract: In this report, silver nanoparticles (AgNPs) with the mean diameters of 10-30 nm were self-assembled onto the surfaces of 2-aminoethanethiol (2-AET) functionalized graphene oxide (AETGO) sheets. The graphene oxide (GO) and AgNPs-AETGO nanocomposites were characterized by a transmission electron microscope (TEM), x-ray photoelectron spectroscopy (XPS), reflection–absorption infrared spectroscopy (RAIRS) and the x-ray diffraction (XRD). The simultaneous determination of quercetin (QR) and morin (MR) has been performed on glassy carbon electrode (GCE) modified with AgNPs-AETGO (AgNPs-AETGO/GCE). QR presented an oxidation step at Ea of 200 mV and reduction step at Ec of 150 mV and RT presented an oxidation step at Ea of 600 mV at AgNPs-AETGO/GCE by cyclic voltammetry (CV). The linearity ranges and the detection limits of QR and MR were 1.0 × 10-8 - 5.0 × 10-6 M and 3.3 × 10-9 M, respectively. The AgNPs-AETGO/GCE was also applied to real samples for the simultaneous determination of QR and MR. Thus the developed method can be adopted as an alternative to the published chromatographic, spectrophotometric and electroanalytical methods for simultaneous determination of QR and MR.
Authors:
Yola, Mehmet Lütfi; [1]  Gupta, Vinod Kumar, E-mail: vinodfcy@iitr.ac.in; [2]  Eren, Tanju; Şen, Arif Emre; Atar, Necip [3] 
  1. Sinop University, Faculty of Engineering, Department of Metallurgical and Materials Engineering, Sinop (Turkey)
  2. Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667 (India)
  3. Dumlupınar University, Faculty of Arts and Sciences, Department of Chemistry, Kutahya (Turkey)
Publication Date:
Feb 01, 2014
Product Type:
Journal Article
Resource Relation:
Journal Name: Electrochimica Acta; Journal Volume: 120; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 77 NANOSCIENCE AND NANOTECHNOLOGY; 46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY; ABSORPTION; ABSORPTION SPECTROSCOPY; CYSTEAMINE; ELECTRODES; GRAPHENE; INFRARED SPECTRA; MORIN; NANOCOMPOSITES; NANOPARTICLES; OXIDATION; OXIDES; QUERCETIN; SENSITIVITY; SILVER; SPECTROPHOTOMETRY; TRANSMISSION ELECTRON MICROSCOPY; VOLTAMETRY; X-RAY DIFFRACTION; X-RAY PHOTOELECTRON SPECTROSCOPY
OSTI ID:
22324430
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0013-4686; CODEN: ELCAAV; Other: PII: S0013-4686(13)02526-7; TRN: GB15R1090030645
Availability:
Available from http://dx.doi.org/10.1016/j.electacta.2013.12.086
Submitting Site:
INIS
Size:
page(s) 204-211
Announcement Date:
Apr 09, 2015

Citation Formats

Yola, Mehmet Lütfi, Gupta, Vinod Kumar, E-mail: vinodfcy@iitr.ac.in, Eren, Tanju, Şen, Arif Emre, and Atar, Necip. A novel electro analytical nanosensor based on graphene oxide/silver nanoparticles for simultaneous determination of quercetin and morin. United Kingdom: N. p., 2014. Web. doi:10.1016/J.ELECTACTA.2013.12.086.
Yola, Mehmet Lütfi, Gupta, Vinod Kumar, E-mail: vinodfcy@iitr.ac.in, Eren, Tanju, Şen, Arif Emre, & Atar, Necip. A novel electro analytical nanosensor based on graphene oxide/silver nanoparticles for simultaneous determination of quercetin and morin. United Kingdom. https://doi.org/10.1016/J.ELECTACTA.2013.12.086
Yola, Mehmet Lütfi, Gupta, Vinod Kumar, E-mail: vinodfcy@iitr.ac.in, Eren, Tanju, Şen, Arif Emre, and Atar, Necip. 2014. "A novel electro analytical nanosensor based on graphene oxide/silver nanoparticles for simultaneous determination of quercetin and morin." United Kingdom. https://doi.org/10.1016/J.ELECTACTA.2013.12.086.
@misc{etde_22324430,
title = {A novel electro analytical nanosensor based on graphene oxide/silver nanoparticles for simultaneous determination of quercetin and morin}
author = {Yola, Mehmet Lütfi, Gupta, Vinod Kumar, E-mail: vinodfcy@iitr.ac.in, Eren, Tanju, Şen, Arif Emre, and Atar, Necip}
abstractNote = {Graphical abstract: - Abstract: In this report, silver nanoparticles (AgNPs) with the mean diameters of 10-30 nm were self-assembled onto the surfaces of 2-aminoethanethiol (2-AET) functionalized graphene oxide (AETGO) sheets. The graphene oxide (GO) and AgNPs-AETGO nanocomposites were characterized by a transmission electron microscope (TEM), x-ray photoelectron spectroscopy (XPS), reflection–absorption infrared spectroscopy (RAIRS) and the x-ray diffraction (XRD). The simultaneous determination of quercetin (QR) and morin (MR) has been performed on glassy carbon electrode (GCE) modified with AgNPs-AETGO (AgNPs-AETGO/GCE). QR presented an oxidation step at Ea of 200 mV and reduction step at Ec of 150 mV and RT presented an oxidation step at Ea of 600 mV at AgNPs-AETGO/GCE by cyclic voltammetry (CV). The linearity ranges and the detection limits of QR and MR were 1.0 × 10-8 - 5.0 × 10-6 M and 3.3 × 10-9 M, respectively. The AgNPs-AETGO/GCE was also applied to real samples for the simultaneous determination of QR and MR. Thus the developed method can be adopted as an alternative to the published chromatographic, spectrophotometric and electroanalytical methods for simultaneous determination of QR and MR.}
doi = {10.1016/J.ELECTACTA.2013.12.086}
journal = []
volume = {120}
journal type = {AC}
place = {United Kingdom}
year = {2014}
month = {Feb}
}