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Sulfur in hierarchically pore-structured carbon pillars as cathode material for lithium–sulfur batteries

Abstract

Highlights: ► Hierarchically pore-structured carbon pillars (HPC) is prepared by directly pyrolyzing Al-based porous coordination polymers (Al-PCP). ► Evidences for the location of sulfur in the HPC and the interaction between S and C are provided. ► This HPC/S composite shows good electrochemical performances as cathode of lithium–sulfur batteries. -- Abstract: Hierarchically pore-structured carbon (HPC) pillars with a high surface area and large pore volume are obtained by pyrolyzing Al-based porous coordination polymers (Al-PCP) and used as a matrix of the sulfur for lithium–sulfur (Li–S) batteries. The structure and electrochemical performance of the sulfur-impregnated HPC are characterized. The improved performance of the composite is ascribed to the unique porous structure of the HPC matrix and its strong interaction with sulfur.
Authors:
Wang, Xuefeng; Fang, Xiangpeng; Guo, Xianwei; [1]  Wang, Zhaoxiang; [1]  Chen, Liquan [1] 
  1. Key Laboratory for Renewable Energy, Chinese Academy of Sciences Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condense Matter Physics, Institute of Physics, Chinese Academy of Sciences, P.O. Box 603, Beijing 100190 (China)
Publication Date:
May 01, 2013
Product Type:
Journal Article
Resource Relation:
Journal Name: Electrochimica Acta; Journal Volume: 97; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CARBON; CATHODES; ENERGY STORAGE; POLYMERS; POROUS MATERIALS; STRONG INTERACTIONS; SULFUR; SURFACE AREA
OSTI ID:
22240397
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0013-4686; CODEN: ELCAAV; Other: PII: S0013-4686(13)00371-X; TRN: GB14R4170061526
Availability:
Available from http://dx.doi.org/10.1016/j.electacta.2013.02.126
Submitting Site:
INIS
Size:
page(s) 238-243
Announcement Date:
Jun 27, 2014

Citation Formats

Wang, Xuefeng, Fang, Xiangpeng, Guo, Xianwei, Wang, Zhaoxiang, and Chen, Liquan. Sulfur in hierarchically pore-structured carbon pillars as cathode material for lithium–sulfur batteries. United Kingdom: N. p., 2013. Web. doi:10.1016/J.ELECTACTA.2013.02.126.
Wang, Xuefeng, Fang, Xiangpeng, Guo, Xianwei, Wang, Zhaoxiang, & Chen, Liquan. Sulfur in hierarchically pore-structured carbon pillars as cathode material for lithium–sulfur batteries. United Kingdom. https://doi.org/10.1016/J.ELECTACTA.2013.02.126
Wang, Xuefeng, Fang, Xiangpeng, Guo, Xianwei, Wang, Zhaoxiang, and Chen, Liquan. 2013. "Sulfur in hierarchically pore-structured carbon pillars as cathode material for lithium–sulfur batteries." United Kingdom. https://doi.org/10.1016/J.ELECTACTA.2013.02.126.
@misc{etde_22240397,
title = {Sulfur in hierarchically pore-structured carbon pillars as cathode material for lithium–sulfur batteries}
author = {Wang, Xuefeng, Fang, Xiangpeng, Guo, Xianwei, Wang, Zhaoxiang, and Chen, Liquan}
abstractNote = {Highlights: ► Hierarchically pore-structured carbon pillars (HPC) is prepared by directly pyrolyzing Al-based porous coordination polymers (Al-PCP). ► Evidences for the location of sulfur in the HPC and the interaction between S and C are provided. ► This HPC/S composite shows good electrochemical performances as cathode of lithium–sulfur batteries. -- Abstract: Hierarchically pore-structured carbon (HPC) pillars with a high surface area and large pore volume are obtained by pyrolyzing Al-based porous coordination polymers (Al-PCP) and used as a matrix of the sulfur for lithium–sulfur (Li–S) batteries. The structure and electrochemical performance of the sulfur-impregnated HPC are characterized. The improved performance of the composite is ascribed to the unique porous structure of the HPC matrix and its strong interaction with sulfur.}
doi = {10.1016/J.ELECTACTA.2013.02.126}
journal = []
volume = {97}
journal type = {AC}
place = {United Kingdom}
year = {2013}
month = {May}
}