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Preparation and characterization of activated carbon from pistachio nut shells via microwave-induced chemical activation

Abstract

In this work, pistachio nut shell, a biomass residue abundantly available from the pistachio nut processing industries, was utilized as a feedstock for the preparation of activated carbon (PSAC) via microwave assisted KOH activation. The activation step was performed at the microwave input power of 600 W and irradiation time of 7 min. The porosity, functional and surface chemistry were featured by means of low temperature nitrogen adsorption, scanning electron microscopy and Fourier transform infrared spectroscopy. Result showed that the BET surface area, Langmuir surface area, and total pore volume of PSAC were 700.53 m{sup 2} g{sup -1}, 1038.78 m{sup 2} g{sup -1} and 0.375 m{sup 3} g{sup -1}, respectively. The adsorptive property of PSAC was tested using methylene blue dye as the targeted adsorbate. Equilibrium data was best fitted by the Langmuir isotherm model, showing a monolayer adsorption capacity of 296.57 mg g{sup -1}. The study revealed the potentiality of microwave-induced activation as a viable activation method. -- Highlights: {yields} Pistachio nut shell activated carbon (PSAC) was prepared via microwave assisted KOH activation. {yields} The activation step was performed at the microwave input power of 600 W and irradiation time of 7 min. {yields} BET surface area of PSAC  More>>
Authors:
Foo, K. Y.; [1]  Hameed, B.H., E-mail: chbassim@eng.usm.my [1] 
  1. School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia)
Publication Date:
Jul 15, 2011
Product Type:
Journal Article
Resource Relation:
Journal Name: Biomass and Bioenergy; Journal Volume: 35; Journal Issue: 7; Other Information: Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 09 BIOMASS FUELS; ACTIVATED CARBON; ADSORPTION; BIOFUELS; BIOMASS; CHEMICAL ACTIVATION; FOURIER TRANSFORM SPECTROMETERS; IRRADIATION; ISOTHERMS; METHYLENE BLUE; MICROWAVE RADIATION; POTASSIUM HYDROXIDES; SHELLS; SORPTIVE PROPERTIES; SURFACE AREA
OSTI ID:
22201287
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0961-9534; CODEN: BMSBEO; Other: PII: S0961-9534(11)00225-X; TRN: GB12R0676022198
Availability:
Available from http://dx.doi.org/10.1016/j.biombioe.2011.04.023
Submitting Site:
INIS
Size:
page(s) 3257-3261
Announcement Date:
Mar 06, 2014

Citation Formats

Foo, K. Y., and Hameed, B.H., E-mail: chbassim@eng.usm.my. Preparation and characterization of activated carbon from pistachio nut shells via microwave-induced chemical activation. United Kingdom: N. p., 2011. Web. doi:10.1016/J.BIOMBIOE.2011.04.023.
Foo, K. Y., & Hameed, B.H., E-mail: chbassim@eng.usm.my. Preparation and characterization of activated carbon from pistachio nut shells via microwave-induced chemical activation. United Kingdom. https://doi.org/10.1016/J.BIOMBIOE.2011.04.023
Foo, K. Y., and Hameed, B.H., E-mail: chbassim@eng.usm.my. 2011. "Preparation and characterization of activated carbon from pistachio nut shells via microwave-induced chemical activation." United Kingdom. https://doi.org/10.1016/J.BIOMBIOE.2011.04.023.
@misc{etde_22201287,
title = {Preparation and characterization of activated carbon from pistachio nut shells via microwave-induced chemical activation}
author = {Foo, K. Y., and Hameed, B.H., E-mail: chbassim@eng.usm.my}
abstractNote = {In this work, pistachio nut shell, a biomass residue abundantly available from the pistachio nut processing industries, was utilized as a feedstock for the preparation of activated carbon (PSAC) via microwave assisted KOH activation. The activation step was performed at the microwave input power of 600 W and irradiation time of 7 min. The porosity, functional and surface chemistry were featured by means of low temperature nitrogen adsorption, scanning electron microscopy and Fourier transform infrared spectroscopy. Result showed that the BET surface area, Langmuir surface area, and total pore volume of PSAC were 700.53 m{sup 2} g{sup -1}, 1038.78 m{sup 2} g{sup -1} and 0.375 m{sup 3} g{sup -1}, respectively. The adsorptive property of PSAC was tested using methylene blue dye as the targeted adsorbate. Equilibrium data was best fitted by the Langmuir isotherm model, showing a monolayer adsorption capacity of 296.57 mg g{sup -1}. The study revealed the potentiality of microwave-induced activation as a viable activation method. -- Highlights: {yields} Pistachio nut shell activated carbon (PSAC) was prepared via microwave assisted KOH activation. {yields} The activation step was performed at the microwave input power of 600 W and irradiation time of 7 min. {yields} BET surface area of PSAC was 700.53 m{sup 2}/g. {yields} Monolayer adsorption capacity of PSAC for MB was 296.57 mg/g.}
doi = {10.1016/J.BIOMBIOE.2011.04.023}
journal = []
issue = {7}
volume = {35}
journal type = {AC}
place = {United Kingdom}
year = {2011}
month = {Jul}
}