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Assessment of environmentally available metals in sediment samples from water for public supply of the city of Palmas, Tocantis, Brazil; Avaliacao dos metais ambientalmente disponiveis em amostras de sedimento de pontos de captacao de agua para abastecimento publico de Palmas, TO, Brasil

Abstract

The sediments are an important compartment used as a tool for assessment of aquatic ecosystems quality, for indicating the presence of contaminants released continuously into the environment as a result of human activities. Among chemical substances discharged to surface water, there are metals that in undesirable amounts, can be toxic to biota. Due to the importance of sediment and of shortage of data of water quality of the Araguaia-Tocantins river system, the present study conducted an assessment of environmentally available metals in sediment samples from water for public supply of the city of Palmas, in Tocantins, Brazil. The concentrations of As, Cd, Pb and Se were analyzed by Graphite Furnace Atomic Absorption Spectrometry (GFAAS), Ag, Al, B, Ba, Be, Ca, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, P, Sb, Sc, Si, Ti, V and Zn were analyzed by Inductively Coupled Plasma Optical Emission Spectrometry (ICPOES) and Hg by Cold Vapor Atomic Absorption Spectrometry (CVAAS). Two partial solubilization processes were performed for a comparative study, one with HCl 0,1 M and agitation at room temperature, considered a milder method for metal extraction from anthropogenic origin, and another with HNO{sub 3} 8 M and microwave heating, considered as  More>>
Publication Date:
Jul 01, 2012
Product Type:
Thesis/Dissertation
Report Number:
INIS-BR-12718
Resource Relation:
Other Information: Diss. (M.Sc.)
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 54 ENVIRONMENTAL SCIENCES; ABSORPTION SPECTROSCOPY; BRAZIL; ENVIRONMENTAL QUALITY; ICP MASS SPECTROSCOPY; METALS; MULTI-ELEMENT ANALYSIS; SAMPLE PREPARATION; SEDIMENTS; WATER SUPPLY
OSTI ID:
22138021
Research Organizations:
Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)
Country of Origin:
Brazil
Language:
Portuguese
Other Identifying Numbers:
TRN: BR1300158092761
Availability:
Available from INIS in electronic form
Submitting Site:
BRN
Size:
137 page(s)
Announcement Date:
Oct 10, 2013

Citation Formats

Oliveira, Bruna Rafaela. Assessment of environmentally available metals in sediment samples from water for public supply of the city of Palmas, Tocantis, Brazil; Avaliacao dos metais ambientalmente disponiveis em amostras de sedimento de pontos de captacao de agua para abastecimento publico de Palmas, TO, Brasil. Brazil: N. p., 2012. Web.
Oliveira, Bruna Rafaela. Assessment of environmentally available metals in sediment samples from water for public supply of the city of Palmas, Tocantis, Brazil; Avaliacao dos metais ambientalmente disponiveis em amostras de sedimento de pontos de captacao de agua para abastecimento publico de Palmas, TO, Brasil. Brazil.
Oliveira, Bruna Rafaela. 2012. "Assessment of environmentally available metals in sediment samples from water for public supply of the city of Palmas, Tocantis, Brazil; Avaliacao dos metais ambientalmente disponiveis em amostras de sedimento de pontos de captacao de agua para abastecimento publico de Palmas, TO, Brasil." Brazil.
@misc{etde_22138021,
title = {Assessment of environmentally available metals in sediment samples from water for public supply of the city of Palmas, Tocantis, Brazil; Avaliacao dos metais ambientalmente disponiveis em amostras de sedimento de pontos de captacao de agua para abastecimento publico de Palmas, TO, Brasil}
author = {Oliveira, Bruna Rafaela}
abstractNote = {The sediments are an important compartment used as a tool for assessment of aquatic ecosystems quality, for indicating the presence of contaminants released continuously into the environment as a result of human activities. Among chemical substances discharged to surface water, there are metals that in undesirable amounts, can be toxic to biota. Due to the importance of sediment and of shortage of data of water quality of the Araguaia-Tocantins river system, the present study conducted an assessment of environmentally available metals in sediment samples from water for public supply of the city of Palmas, in Tocantins, Brazil. The concentrations of As, Cd, Pb and Se were analyzed by Graphite Furnace Atomic Absorption Spectrometry (GFAAS), Ag, Al, B, Ba, Be, Ca, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, P, Sb, Sc, Si, Ti, V and Zn were analyzed by Inductively Coupled Plasma Optical Emission Spectrometry (ICPOES) and Hg by Cold Vapor Atomic Absorption Spectrometry (CVAAS). Two partial solubilization processes were performed for a comparative study, one with HCl 0,1 M and agitation at room temperature, considered a milder method for metal extraction from anthropogenic origin, and another with HNO{sub 3} 8 M and microwave heating, considered as an alternative to more complex methods of total digestion, since it provides a good evaluation of the total concentration of the elements. The sediment quality evaluation was realized by comparing the concentration values of the elements As, Cd, Cr, Cu, Hg, Ni, Pb and Zn with the quality guidelines (TEL and PEL) adopted by Canadian Council of Minister of the Environment (CCME), to thereby contribute to the environmental quality of the water of the Araguaia-Tocantins river system. (author)}
place = {Brazil}
year = {2012}
month = {Jul}
}