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Synthesis and field evaluation of synthetic blends of the sex pheromone of Crocidosema aporema (Lepidoptera: Tortricidae) in soybean

Abstract

Crocidosema (= Epinotia) aporema (Walsingham) (Lepidoptera: Tortricidae) is a bud borer that feeds on soybean and forage legumes. Its economic importance is restricted to South America, where it can alternate throughout the year between forage and grain legumes. The sex pheromone of C. aporema females is composed of a 15:1 mixture of (7Z,9Z)-dodeca-7,9-dien-1-ol and (7Z,9Z)- dodeca-7,9-dienyl acetate. Aiming at the development of a monitoring tool, it was synthesized both components of the pheromone and evaluated male captures in pheromone traps baited with different blends of synthetic pheromone, in an experimental soybean field in Uruguay. The conjugated dienes were obtained from 2-pentyn-1-ol and 1,7-heptanediol, by oxidation of the former, Wittig coupling and Zn-catalyzed reduction of the triple bond. The 1:1 mixture was the most efficient in capturing males. The pheromone traps were attractive for up to 40 days, even with small septum loads (0.1 mg) and low population levels. (author)
Authors:
Gonzalez, Andres; Altesor, Paula; Liberati, Paola; Rossini, Carmen; [1]  Alves, Leticia; Ramos, Juan; Carrera, Ignacio; Gonzalez, David; Seoane, Gustavo; Gamenara, Daniela; [2]  Silva, Horacio; Castiglioni, Enrique [3] 
  1. Laboratorio de Ecologia Quimica, Facultad de Quimica, Universidad de la Republica, Montevideo (Uruguay)
  2. Departamento de Quimica Organica, Facultad de Quimica, Universidad de la Republica, Montevideo (Uruguay)
  3. Departamento de Proteccion Vegetal, Facultad de Agronomia, EEMAC, Universidad de la Republica, Paysandu (Uruguay)
Publication Date:
Nov 15, 2012
Product Type:
Journal Article
Resource Relation:
Journal Name: Journal of the Brazilian Chemical Society; Journal Volume: 23; Journal Issue: 11
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ALDEHYDES; CARBON 13; CATALYSTS; DIENES; GAS CHROMATOGRAPHY; GLYCOLS; HEPTANE; HEXANE; HYDROGEN 1; ISOMERIZATION; LIQUID COLUMN CHROMATOGRAPHY; MASS SPECTRA; METHANOL; NMR SPECTRA; PHEROMONE; SILICA GEL; SODIUM SULFATES; TOLUENE; ZINC
OSTI ID:
22125510
Country of Origin:
Brazil
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0103-5053; CODEN: JOCSET; TRN: BR13V0109080256
Availability:
Available from http://www.scielo.br/pdf/jbchs/v23n11/aop090_12.pdf
Submitting Site:
BRN
Size:
page(s) 1997-2002
Announcement Date:
Sep 12, 2013

Citation Formats

Gonzalez, Andres, Altesor, Paula, Liberati, Paola, Rossini, Carmen, Alves, Leticia, Ramos, Juan, Carrera, Ignacio, Gonzalez, David, Seoane, Gustavo, Gamenara, Daniela, Silva, Horacio, and Castiglioni, Enrique. Synthesis and field evaluation of synthetic blends of the sex pheromone of Crocidosema aporema (Lepidoptera: Tortricidae) in soybean. Brazil: N. p., 2012. Web. doi:10.1590/S0103-50532012005000072.
Gonzalez, Andres, Altesor, Paula, Liberati, Paola, Rossini, Carmen, Alves, Leticia, Ramos, Juan, Carrera, Ignacio, Gonzalez, David, Seoane, Gustavo, Gamenara, Daniela, Silva, Horacio, & Castiglioni, Enrique. Synthesis and field evaluation of synthetic blends of the sex pheromone of Crocidosema aporema (Lepidoptera: Tortricidae) in soybean. Brazil. https://doi.org/10.1590/S0103-50532012005000072
Gonzalez, Andres, Altesor, Paula, Liberati, Paola, Rossini, Carmen, Alves, Leticia, Ramos, Juan, Carrera, Ignacio, Gonzalez, David, Seoane, Gustavo, Gamenara, Daniela, Silva, Horacio, and Castiglioni, Enrique. 2012. "Synthesis and field evaluation of synthetic blends of the sex pheromone of Crocidosema aporema (Lepidoptera: Tortricidae) in soybean." Brazil. https://doi.org/10.1590/S0103-50532012005000072.
@misc{etde_22125510,
title = {Synthesis and field evaluation of synthetic blends of the sex pheromone of Crocidosema aporema (Lepidoptera: Tortricidae) in soybean}
author = {Gonzalez, Andres, Altesor, Paula, Liberati, Paola, Rossini, Carmen, Alves, Leticia, Ramos, Juan, Carrera, Ignacio, Gonzalez, David, Seoane, Gustavo, Gamenara, Daniela, Silva, Horacio, and Castiglioni, Enrique}
abstractNote = {Crocidosema (= Epinotia) aporema (Walsingham) (Lepidoptera: Tortricidae) is a bud borer that feeds on soybean and forage legumes. Its economic importance is restricted to South America, where it can alternate throughout the year between forage and grain legumes. The sex pheromone of C. aporema females is composed of a 15:1 mixture of (7Z,9Z)-dodeca-7,9-dien-1-ol and (7Z,9Z)- dodeca-7,9-dienyl acetate. Aiming at the development of a monitoring tool, it was synthesized both components of the pheromone and evaluated male captures in pheromone traps baited with different blends of synthetic pheromone, in an experimental soybean field in Uruguay. The conjugated dienes were obtained from 2-pentyn-1-ol and 1,7-heptanediol, by oxidation of the former, Wittig coupling and Zn-catalyzed reduction of the triple bond. The 1:1 mixture was the most efficient in capturing males. The pheromone traps were attractive for up to 40 days, even with small septum loads (0.1 mg) and low population levels. (author)}
doi = {10.1590/S0103-50532012005000072}
journal = []
issue = {11}
volume = {23}
journal type = {AC}
place = {Brazil}
year = {2012}
month = {Nov}
}