Abstract
New work is to be presented on the effect of gamma radiation on the catalytic activity of alumina silica gel and decationateii molecular sieves of the Linde Y-type. A graded set of alumina silica coprecipitated gel catalysts have been made with the atomic ratio of alumina silica having ten different equally spaced values. Another set of catalysts was made by partially replacing the sodium of a Linde molecular Y-sieve Na{sub 56}(AlO{sub 2}){sub 56}(SiO{sub 2}){sub 126} by ammonium ion and then decomposing it to drive both the ammonia and the water away to produce a de-cationated position in the sieve: A graded set of such catalysts has been prepared containing varying amounts of these de-cationated sites from zero to 100% of the original sodium content. These two sets of catalysts have been characterized for catalytic activity before and after gamma radiation by studying the kinetics of cumene decomposition into benzene and propylene, the double bond isomerization of butene-1 to butene-2 and the hydrogen/deuterium exchange reaction. The number of active sites was determined by progressive poisoning using quinoline and the activity per site was thus characterized. The materials were also studied by measuring the electron spin resonance of adsorbed electron transfer agents
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Citation Formats
Turkevich, J., Ikawa, T., Nozaki, F., and Stamires, D.
Catalytic Activity and Nuclear Radiation; L'activite catalytique et les rayonnements nucleaires; Kataliticheskaya aktivnost' i yadernoe izluchenie; La actividad catalitica y las radiaciones nucleares.
IAEA: N. p.,
1963.
Web.
Turkevich, J., Ikawa, T., Nozaki, F., & Stamires, D.
Catalytic Activity and Nuclear Radiation; L'activite catalytique et les rayonnements nucleaires; Kataliticheskaya aktivnost' i yadernoe izluchenie; La actividad catalitica y las radiaciones nucleares.
IAEA.
Turkevich, J., Ikawa, T., Nozaki, F., and Stamires, D.
1963.
"Catalytic Activity and Nuclear Radiation; L'activite catalytique et les rayonnements nucleaires; Kataliticheskaya aktivnost' i yadernoe izluchenie; La actividad catalitica y las radiaciones nucleares."
IAEA.
@misc{etde_22108171,
title = {Catalytic Activity and Nuclear Radiation; L'activite catalytique et les rayonnements nucleaires; Kataliticheskaya aktivnost' i yadernoe izluchenie; La actividad catalitica y las radiaciones nucleares}
author = {Turkevich, J., Ikawa, T., Nozaki, F., and Stamires, D.}
abstractNote = {New work is to be presented on the effect of gamma radiation on the catalytic activity of alumina silica gel and decationateii molecular sieves of the Linde Y-type. A graded set of alumina silica coprecipitated gel catalysts have been made with the atomic ratio of alumina silica having ten different equally spaced values. Another set of catalysts was made by partially replacing the sodium of a Linde molecular Y-sieve Na{sub 56}(AlO{sub 2}){sub 56}(SiO{sub 2}){sub 126} by ammonium ion and then decomposing it to drive both the ammonia and the water away to produce a de-cationated position in the sieve: A graded set of such catalysts has been prepared containing varying amounts of these de-cationated sites from zero to 100% of the original sodium content. These two sets of catalysts have been characterized for catalytic activity before and after gamma radiation by studying the kinetics of cumene decomposition into benzene and propylene, the double bond isomerization of butene-1 to butene-2 and the hydrogen/deuterium exchange reaction. The number of active sites was determined by progressive poisoning using quinoline and the activity per site was thus characterized. The materials were also studied by measuring the electron spin resonance of adsorbed electron transfer agents such as triphenylamine, perylen'e and symmetrical diphenyl ethylene. The ability to transfer electrons was found to be parallel to catalytic activity. Proton resonance of adsorbed water was'used to characterize the nature of the catalytic site. (author) [French] Les auteurs se proposent de presenter des recherches nouvelles consacrees aux effets des rayons gamma sur l'activite catalytique du gel de silice et d'alumine et des tamis moleculaires decationises du type Linde Y. Pour cela ils ont prepare une serie de catalyseurs en coprecipitant de la silice et de l'alumine dans des proportions successivement egales a dix nombres regulierement espaces. Ils ont prepare une deuxieme serie de catalyseurs en remplacant en partie l e sodium d'un tamis moleculaire du type Linde Y (Na{sub 56}(AlO{sub 2}){sub 56}(SiO{sub 2}){sub 126}) par l'ion ammonium pour l e decomposer ensuite de maniere a retirer a la fois l'ammoniaque et l'eau, ce qui cree des sites depourvus d e cations dans le tamis. Ils ont prepare une serie de ces catalyseurs possedant des nombres regulierement croissants de sites decationises (de 0 a 100%par rapport a la teneur primitive en sodium). Ils ont etudie l'activite catalytique de ces deux series de catalyseurs avant et apres exposition aux rayons gamma, en observant ia cinetique de la decomposition du cumene en benzene et propylene, l'isomerisation du butene - 1 en butene-2 par deplacement de la double liaison et la reaction d'echange hydrogene-deuteriu'm. Le nombre des sites actifs a ete determine par empoisonnement progressif a la quinoleine; on a donc pu chiffrer l'activite par site. Les auteurs ont aussi etudie ces substances en mesurant la resonance de spin des electrons pour des agents de transfert des electrons adsorbes, notamment la triphenylamine, le perylene et le diphenylethylene symetrique. Ils ont constate que la capacite de transfert des electrons est parallele a l'activite catalytique. lis ont pris la resonance protonique de l'eau absorbee pour caracteriser la nature du site catalytique. (author) [Spanish] Los autores exponen los resultados de nuevos trabajos acerca de los efectos de los rayos gamma sobre la actividad catalitica de un gel de silice y alumina y sobre tamices moleculares descationizados del tipo Linde Y. A tal efecto, prepararon una serie graduada de catalizadores de gel de silice y alumina coprecipitados, con diez distintos valores equidistantes para la razon atomica alumina/silice. Otra serie de catalizadores se obtuvo sustituyendo parcialmente el sodio de un tamiz molecular Linde Y, Na{sup 56}(AlO{sub 2}){sub 56}(SiO{sub 2}){sub 126}, por el ion amonio y descomponiendolo despues para expulsar tanto el amonio como el agua, con lo que se crean sitios desprovistos de cationes en el tamiz. Se ha preparado una serie graduada de estos catalizadores que poseen numeros regularmente crecientes de tales sitios desde cero hasta un ciento por ciento con respecto al contenido original de sodio. Los autores determinaron la actividad catalitica de esas dos series de catalizadores antes y despues de someterlos a irradiacion gamma, estudiando la cinetica de la descomposicion del eumeno en benceno y propileno, la isomerizacion del butano-1 en butano-2 por desplazamiento del doble enlace y la reaccion de intercambio hydrogenodeuterio. Se determino el numero de sitios activos recurriendo al envenenamiento progresivo por medio de quinolei'na, lo que permite establecer la actividad por cada sitio. Tambien se estudiaron los materiales midiendo la resonancia del espin electronico de agentes de transferencia de electrones adsorbidos tales como la trifenilamina, el perileno y el difeniletileno simetrico. Se comprobo que la capacidad de transferencia de electrones era paralela a la actividad catalitica. Para determinar la naturaleza de los sitios cataliticos, se utilizo la resonancia protonica del agua adsorbida. (author) [Russian] Predstavlena' novaya rabota po issledovaniyu dejstviya gamma-izlucheniya na kataliticheskuyu aktivnost' alyumosilikagelya i dekationirovannykh molekulyarnykh sit .gida Linde Y. Metodom sooavzhdeniya prigotovlen rnd obraztsov katalizatorov alyumosilikagelya, prichem atomnoe otnoshenie alyuminiya k kremniyu v kazhdom iz okisnykh katalizatorov bylo raznym, i takim obrazom poluchilos' desyat' razlichnykh obraztsov razlichnykh sostavov. Drugaya seriya obraztsov katalizatorov poluchena pri nepolnom zameshchenii natriya v molekulyarnom site tipa Linde Y (Na{sub 56}(AlO{sub 2}){sub 56}(SiO{sub 2} ){sub 126} na ion ammoniya) i pri posleduyushchem razlozhenii ego dlya udaleniya kak ammiaka, tak i vody. Pri ehtom v site obrazovyvalis' vakansii kationov. Prigotovlena tselaya seriya takikh katalizatorov, soderzhavshikh razlichnoe kolichestvo dekationirovannykh tsentrov ot nulya do sta protsen- tov, schitaya na iskhodnoe soderzhanie natriya. Kataliticheskuyu aktivnost' ehtikh dvukh tipov katalizatorov opredelyali do i posle gamma-oblucheniya, issleduya kinetiku razlozheniya kumola v benzole i propilene, provodya izomerizatsiyu dvojnykh svyazej butena-1 v buten-2 i provodya reaktsii obmena mekhdu vodorodom i dejteriem. Chislo aktivnykh tsentrov opredelyali po vozrastavshemu otravleniyu, primenyaya khinolin, i takim obrazom kharakterizovali aktivnost', prikhodyashchuyusya na tsentr. Veshchestva izucheny takzhe putem izmereniya ehlektronno-spinovogo rezonansa adsorbirovannykh ehlektronno-perenosyashchikh agentov, kak, naprimer, trifenilamin, perilen i simmetrichnyj difenilehtilen. Bylo najdeno, chto sposobnost' k perenosu ehlektronov sootvetstvuet kataliticheskoj aktivnosti. Dlya vyyasneniya prirody aktivnykh tsentrov ispol'zovali protonnyj rezonans adsorbirovannoj vody. (author)}
place = {IAEA}
year = {1963}
month = {Nov}
}
title = {Catalytic Activity and Nuclear Radiation; L'activite catalytique et les rayonnements nucleaires; Kataliticheskaya aktivnost' i yadernoe izluchenie; La actividad catalitica y las radiaciones nucleares}
author = {Turkevich, J., Ikawa, T., Nozaki, F., and Stamires, D.}
abstractNote = {New work is to be presented on the effect of gamma radiation on the catalytic activity of alumina silica gel and decationateii molecular sieves of the Linde Y-type. A graded set of alumina silica coprecipitated gel catalysts have been made with the atomic ratio of alumina silica having ten different equally spaced values. Another set of catalysts was made by partially replacing the sodium of a Linde molecular Y-sieve Na{sub 56}(AlO{sub 2}){sub 56}(SiO{sub 2}){sub 126} by ammonium ion and then decomposing it to drive both the ammonia and the water away to produce a de-cationated position in the sieve: A graded set of such catalysts has been prepared containing varying amounts of these de-cationated sites from zero to 100% of the original sodium content. These two sets of catalysts have been characterized for catalytic activity before and after gamma radiation by studying the kinetics of cumene decomposition into benzene and propylene, the double bond isomerization of butene-1 to butene-2 and the hydrogen/deuterium exchange reaction. The number of active sites was determined by progressive poisoning using quinoline and the activity per site was thus characterized. The materials were also studied by measuring the electron spin resonance of adsorbed electron transfer agents such as triphenylamine, perylen'e and symmetrical diphenyl ethylene. The ability to transfer electrons was found to be parallel to catalytic activity. Proton resonance of adsorbed water was'used to characterize the nature of the catalytic site. (author) [French] Les auteurs se proposent de presenter des recherches nouvelles consacrees aux effets des rayons gamma sur l'activite catalytique du gel de silice et d'alumine et des tamis moleculaires decationises du type Linde Y. Pour cela ils ont prepare une serie de catalyseurs en coprecipitant de la silice et de l'alumine dans des proportions successivement egales a dix nombres regulierement espaces. Ils ont prepare une deuxieme serie de catalyseurs en remplacant en partie l e sodium d'un tamis moleculaire du type Linde Y (Na{sub 56}(AlO{sub 2}){sub 56}(SiO{sub 2}){sub 126}) par l'ion ammonium pour l e decomposer ensuite de maniere a retirer a la fois l'ammoniaque et l'eau, ce qui cree des sites depourvus d e cations dans le tamis. Ils ont prepare une serie de ces catalyseurs possedant des nombres regulierement croissants de sites decationises (de 0 a 100%par rapport a la teneur primitive en sodium). Ils ont etudie l'activite catalytique de ces deux series de catalyseurs avant et apres exposition aux rayons gamma, en observant ia cinetique de la decomposition du cumene en benzene et propylene, l'isomerisation du butene - 1 en butene-2 par deplacement de la double liaison et la reaction d'echange hydrogene-deuteriu'm. Le nombre des sites actifs a ete determine par empoisonnement progressif a la quinoleine; on a donc pu chiffrer l'activite par site. Les auteurs ont aussi etudie ces substances en mesurant la resonance de spin des electrons pour des agents de transfert des electrons adsorbes, notamment la triphenylamine, le perylene et le diphenylethylene symetrique. Ils ont constate que la capacite de transfert des electrons est parallele a l'activite catalytique. lis ont pris la resonance protonique de l'eau absorbee pour caracteriser la nature du site catalytique. (author) [Spanish] Los autores exponen los resultados de nuevos trabajos acerca de los efectos de los rayos gamma sobre la actividad catalitica de un gel de silice y alumina y sobre tamices moleculares descationizados del tipo Linde Y. A tal efecto, prepararon una serie graduada de catalizadores de gel de silice y alumina coprecipitados, con diez distintos valores equidistantes para la razon atomica alumina/silice. Otra serie de catalizadores se obtuvo sustituyendo parcialmente el sodio de un tamiz molecular Linde Y, Na{sup 56}(AlO{sub 2}){sub 56}(SiO{sub 2}){sub 126}, por el ion amonio y descomponiendolo despues para expulsar tanto el amonio como el agua, con lo que se crean sitios desprovistos de cationes en el tamiz. Se ha preparado una serie graduada de estos catalizadores que poseen numeros regularmente crecientes de tales sitios desde cero hasta un ciento por ciento con respecto al contenido original de sodio. Los autores determinaron la actividad catalitica de esas dos series de catalizadores antes y despues de someterlos a irradiacion gamma, estudiando la cinetica de la descomposicion del eumeno en benceno y propileno, la isomerizacion del butano-1 en butano-2 por desplazamiento del doble enlace y la reaccion de intercambio hydrogenodeuterio. Se determino el numero de sitios activos recurriendo al envenenamiento progresivo por medio de quinolei'na, lo que permite establecer la actividad por cada sitio. Tambien se estudiaron los materiales midiendo la resonancia del espin electronico de agentes de transferencia de electrones adsorbidos tales como la trifenilamina, el perileno y el difeniletileno simetrico. Se comprobo que la capacidad de transferencia de electrones era paralela a la actividad catalitica. Para determinar la naturaleza de los sitios cataliticos, se utilizo la resonancia protonica del agua adsorbida. (author) [Russian] Predstavlena' novaya rabota po issledovaniyu dejstviya gamma-izlucheniya na kataliticheskuyu aktivnost' alyumosilikagelya i dekationirovannykh molekulyarnykh sit .gida Linde Y. Metodom sooavzhdeniya prigotovlen rnd obraztsov katalizatorov alyumosilikagelya, prichem atomnoe otnoshenie alyuminiya k kremniyu v kazhdom iz okisnykh katalizatorov bylo raznym, i takim obrazom poluchilos' desyat' razlichnykh obraztsov razlichnykh sostavov. Drugaya seriya obraztsov katalizatorov poluchena pri nepolnom zameshchenii natriya v molekulyarnom site tipa Linde Y (Na{sub 56}(AlO{sub 2}){sub 56}(SiO{sub 2} ){sub 126} na ion ammoniya) i pri posleduyushchem razlozhenii ego dlya udaleniya kak ammiaka, tak i vody. Pri ehtom v site obrazovyvalis' vakansii kationov. Prigotovlena tselaya seriya takikh katalizatorov, soderzhavshikh razlichnoe kolichestvo dekationirovannykh tsentrov ot nulya do sta protsen- tov, schitaya na iskhodnoe soderzhanie natriya. Kataliticheskuyu aktivnost' ehtikh dvukh tipov katalizatorov opredelyali do i posle gamma-oblucheniya, issleduya kinetiku razlozheniya kumola v benzole i propilene, provodya izomerizatsiyu dvojnykh svyazej butena-1 v buten-2 i provodya reaktsii obmena mekhdu vodorodom i dejteriem. Chislo aktivnykh tsentrov opredelyali po vozrastavshemu otravleniyu, primenyaya khinolin, i takim obrazom kharakterizovali aktivnost', prikhodyashchuyusya na tsentr. Veshchestva izucheny takzhe putem izmereniya ehlektronno-spinovogo rezonansa adsorbirovannykh ehlektronno-perenosyashchikh agentov, kak, naprimer, trifenilamin, perilen i simmetrichnyj difenilehtilen. Bylo najdeno, chto sposobnost' k perenosu ehlektronov sootvetstvuet kataliticheskoj aktivnosti. Dlya vyyasneniya prirody aktivnykh tsentrov ispol'zovali protonnyj rezonans adsorbirovannoj vody. (author)}
place = {IAEA}
year = {1963}
month = {Nov}
}