Abstract
Studies of the radiation-peroxidation of polymethylmethacrylate (PMMA) are discussed in relation to the subsequent grafting of vinyl pyrrolidone to the peroxidized polymer. The peroxidation has been investigated as a function of dose, PMMA molecular weight, and irradiation temperature. It is shown that low molecular weight PMMA is more effectively peroxidized and grafted at doses of a few megarads than a relatively high molecular weight polymer. It is also observed that increasing the temperature to about the glass sansition also increases peroxidation and grafting. The results are explained in terms to the effects of temperature and molecular weight on the mobility of polymer and fragment radicals. (author) [French] Le memoire decrit les resultats d'etudes sur la radioperoxydation du polymethacrylate de methyle (PMAM) et le greffage ulterieur de vinyle pyrrolidone sur le polymere peroxyde. On a etudie la peroxydation en fonction de la dose du poids moleculaire du PMAM et de la temperature d'irradiation. Les auteurs montrent qu'un polymethacrylate de methyle a poids moleculaire faible est plus facilement peroxyde et greffe a des doses de quelques megarad que ne l'est un polymere a poids moleculaire relativement eleve. Il a egalement ete observe qu'en augmentant la temperature jusqu'au point de passage a l'etat
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Kircher, J. F.;
Markle, R. A.;
Lieberman, R.;
Sleimers, F. A.;
Leininger, R. I.
[1]
- Batelle Memorial Institute, Columbus, OH (United States)
Citation Formats
Kircher, J. F., Markle, R. A., Lieberman, R., Sleimers, F. A., and Leininger, R. I.
Grafting to Polymethylmethacrylate by the Radiation-Peroxidation Method; Greffage sur le polymethacrylate de methyle par la methode de la radioperoxydation radiochimique; Privivanie k polimetilmetakripatu po metodu radiatsionnogo peroksidirovaniya; Injertos en el polimetilmetacrilato por el metodo de peroxidacion radioinducida.
IAEA: N. p.,
1963.
Web.
Kircher, J. F., Markle, R. A., Lieberman, R., Sleimers, F. A., & Leininger, R. I.
Grafting to Polymethylmethacrylate by the Radiation-Peroxidation Method; Greffage sur le polymethacrylate de methyle par la methode de la radioperoxydation radiochimique; Privivanie k polimetilmetakripatu po metodu radiatsionnogo peroksidirovaniya; Injertos en el polimetilmetacrilato por el metodo de peroxidacion radioinducida.
IAEA.
Kircher, J. F., Markle, R. A., Lieberman, R., Sleimers, F. A., and Leininger, R. I.
1963.
"Grafting to Polymethylmethacrylate by the Radiation-Peroxidation Method; Greffage sur le polymethacrylate de methyle par la methode de la radioperoxydation radiochimique; Privivanie k polimetilmetakripatu po metodu radiatsionnogo peroksidirovaniya; Injertos en el polimetilmetacrilato por el metodo de peroxidacion radioinducida."
IAEA.
@misc{etde_22099289,
title = {Grafting to Polymethylmethacrylate by the Radiation-Peroxidation Method; Greffage sur le polymethacrylate de methyle par la methode de la radioperoxydation radiochimique; Privivanie k polimetilmetakripatu po metodu radiatsionnogo peroksidirovaniya; Injertos en el polimetilmetacrilato por el metodo de peroxidacion radioinducida}
author = {Kircher, J. F., Markle, R. A., Lieberman, R., Sleimers, F. A., and Leininger, R. I.}
abstractNote = {Studies of the radiation-peroxidation of polymethylmethacrylate (PMMA) are discussed in relation to the subsequent grafting of vinyl pyrrolidone to the peroxidized polymer. The peroxidation has been investigated as a function of dose, PMMA molecular weight, and irradiation temperature. It is shown that low molecular weight PMMA is more effectively peroxidized and grafted at doses of a few megarads than a relatively high molecular weight polymer. It is also observed that increasing the temperature to about the glass sansition also increases peroxidation and grafting. The results are explained in terms to the effects of temperature and molecular weight on the mobility of polymer and fragment radicals. (author) [French] Le memoire decrit les resultats d'etudes sur la radioperoxydation du polymethacrylate de methyle (PMAM) et le greffage ulterieur de vinyle pyrrolidone sur le polymere peroxyde. On a etudie la peroxydation en fonction de la dose du poids moleculaire du PMAM et de la temperature d'irradiation. Les auteurs montrent qu'un polymethacrylate de methyle a poids moleculaire faible est plus facilement peroxyde et greffe a des doses de quelques megarad que ne l'est un polymere a poids moleculaire relativement eleve. Il a egalement ete observe qu'en augmentant la temperature jusqu'au point de passage a l'etat vineux, la peroxydation et les quantites de copolymere greffe augmentent egalement. L'explication des resultats est donnee en fonction des effets de la temperature et du poids moleculaire sur la mobilite du polymere et des radicaux. (author) [Spanish] Los autores examinan los resultados de estudios de la peroxidacion radioinducida del polimetilmetacrilato (PMMA), en relacion con el injerto subsiguiente de vinilpirrolidona en el polimero peroxidado. Han investigado la peroxidacion en funcion de la dosis, del peso molecular del PMMA y de la temperatura de irradiacion. Demuestran que al aplicar dosis de algunos megairad el PMMA de bajo peso molecular se peroxida e injerta con mayor facilidad que un polimero de peso molecular relativamente elevado. Se observa tambien que al elevar la temperatura hasta alcanzar al punto de transicion de la fase vidriosa aumenta el grado de peroxidacion y de injerto. Los autores proponen una explicacion de los resultados, basada en los efectos de la temperatura y del peso molecular sobre la movilidad del polimero y de los radicales. (author) [Russian] Issledovano radiatsionnoe okislenie polimetilmetakrilata (RMMA) v perekisnoe soedinenie v svyazi s posleduyushchim privivaniem pirrolidonvinila k perekisnomu polimeru. Peroksidirovanie issledovano v zavisimosti ot velichiny dozy, molekulyarnogo vesa RMMA i temperatury izlucheniya. Pokazano, chto RMMA s malym molekulyarnym vesom bolee ehffektivno okislyaetsya do perekisi i privivaetsya pri obluchenii dozami v neskol'ko megarad, chem polimer so sravnitel'no bol'shim molekulyarnym vesom. Otmecheno takzhe, chto povyshenie temperatury primerno do temperatury perekhoda stekla v zhidkoe sostoyanie intensifitsiruet protsessy okisleniya do perekisej i privivaniya. Rezul'taty ob{sup y}asneny, iskhodya iz vliyaniya temperatury i molekulyarnogo vesa na podvizhnost' polimera i oskolochnye radikaly. (author)}
place = {IAEA}
year = {1963}
month = {Nov}
}
title = {Grafting to Polymethylmethacrylate by the Radiation-Peroxidation Method; Greffage sur le polymethacrylate de methyle par la methode de la radioperoxydation radiochimique; Privivanie k polimetilmetakripatu po metodu radiatsionnogo peroksidirovaniya; Injertos en el polimetilmetacrilato por el metodo de peroxidacion radioinducida}
author = {Kircher, J. F., Markle, R. A., Lieberman, R., Sleimers, F. A., and Leininger, R. I.}
abstractNote = {Studies of the radiation-peroxidation of polymethylmethacrylate (PMMA) are discussed in relation to the subsequent grafting of vinyl pyrrolidone to the peroxidized polymer. The peroxidation has been investigated as a function of dose, PMMA molecular weight, and irradiation temperature. It is shown that low molecular weight PMMA is more effectively peroxidized and grafted at doses of a few megarads than a relatively high molecular weight polymer. It is also observed that increasing the temperature to about the glass sansition also increases peroxidation and grafting. The results are explained in terms to the effects of temperature and molecular weight on the mobility of polymer and fragment radicals. (author) [French] Le memoire decrit les resultats d'etudes sur la radioperoxydation du polymethacrylate de methyle (PMAM) et le greffage ulterieur de vinyle pyrrolidone sur le polymere peroxyde. On a etudie la peroxydation en fonction de la dose du poids moleculaire du PMAM et de la temperature d'irradiation. Les auteurs montrent qu'un polymethacrylate de methyle a poids moleculaire faible est plus facilement peroxyde et greffe a des doses de quelques megarad que ne l'est un polymere a poids moleculaire relativement eleve. Il a egalement ete observe qu'en augmentant la temperature jusqu'au point de passage a l'etat vineux, la peroxydation et les quantites de copolymere greffe augmentent egalement. L'explication des resultats est donnee en fonction des effets de la temperature et du poids moleculaire sur la mobilite du polymere et des radicaux. (author) [Spanish] Los autores examinan los resultados de estudios de la peroxidacion radioinducida del polimetilmetacrilato (PMMA), en relacion con el injerto subsiguiente de vinilpirrolidona en el polimero peroxidado. Han investigado la peroxidacion en funcion de la dosis, del peso molecular del PMMA y de la temperatura de irradiacion. Demuestran que al aplicar dosis de algunos megairad el PMMA de bajo peso molecular se peroxida e injerta con mayor facilidad que un polimero de peso molecular relativamente elevado. Se observa tambien que al elevar la temperatura hasta alcanzar al punto de transicion de la fase vidriosa aumenta el grado de peroxidacion y de injerto. Los autores proponen una explicacion de los resultados, basada en los efectos de la temperatura y del peso molecular sobre la movilidad del polimero y de los radicales. (author) [Russian] Issledovano radiatsionnoe okislenie polimetilmetakrilata (RMMA) v perekisnoe soedinenie v svyazi s posleduyushchim privivaniem pirrolidonvinila k perekisnomu polimeru. Peroksidirovanie issledovano v zavisimosti ot velichiny dozy, molekulyarnogo vesa RMMA i temperatury izlucheniya. Pokazano, chto RMMA s malym molekulyarnym vesom bolee ehffektivno okislyaetsya do perekisi i privivaetsya pri obluchenii dozami v neskol'ko megarad, chem polimer so sravnitel'no bol'shim molekulyarnym vesom. Otmecheno takzhe, chto povyshenie temperatury primerno do temperatury perekhoda stekla v zhidkoe sostoyanie intensifitsiruet protsessy okisleniya do perekisej i privivaniya. Rezul'taty ob{sup y}asneny, iskhodya iz vliyaniya temperatury i molekulyarnogo vesa na podvizhnost' polimera i oskolochnye radikaly. (author)}
place = {IAEA}
year = {1963}
month = {Nov}
}