Abstract
The cross-linking of polyvinyl chloride with ionizing radiation poses special problems. Due to rather unfavourable cross-linking and dislinking parameters for this polymer, the radiation doses necessary for high cross-link densities are uneconomicall y large and discolouration and dehydrohalogenatio n are simultaneously produced. These difficulties have been overcome by the incorporation into the P. V. C., prior to irradiation, of diallyl and triallyl esters. Heavily cross-linked products are thereby obtained with relatively low doses of ionizing radiation. Examination of the physical properties of the products suggests that these are not simply graft copolymers, which term normally implies the presence of long branch chains, but are polymer attenuated allyl networks. In these materials, the desirable properties of the parent polymer and of the allyl network are combined. The tensile strength, modulus and elongation of the attenuated network copolymers are presented and discussed as a function of temperature and of the concentration and functionality of the allyl ester. Reference is also made to the swelling and chemical resistance of the products. (author) [French] La reticulation du chlorure de polyvinyle sous l'action des rayonnements ionisants pose des problemes particuliers. Les parametres de reticulation et de degradation etant plutot defavorables pour ce polymere, les doses
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Pinner, S H
[1]
- Tube Investments Research Laboratories, Hinxton Hall, Cambridge (United Kingdom)
Citation Formats
Pinner, S H.
Physical Properties of P.V.C. Attenuated Network Copolymers Produced by Ionizing Radiation; Proprietes physiques des copolymeres obtenus sous l'action de rayonnements ionisants et dont le reseau est attenue par l'effet du chlorure de polyvinyle; Fizicheskie svojstva polivinilkhloridnykh obednennykh tsepej sopolimerov, poluchennykh v rezul'tate vozdejstviya ioniziruyushchej radiatsii; Propiedades fisicas de los copolimeros de redes atenuadas por cloruro de polivinilo obtenidos por irradiacion.
IAEA: N. p.,
1960.
Web.
Pinner, S H.
Physical Properties of P.V.C. Attenuated Network Copolymers Produced by Ionizing Radiation; Proprietes physiques des copolymeres obtenus sous l'action de rayonnements ionisants et dont le reseau est attenue par l'effet du chlorure de polyvinyle; Fizicheskie svojstva polivinilkhloridnykh obednennykh tsepej sopolimerov, poluchennykh v rezul'tate vozdejstviya ioniziruyushchej radiatsii; Propiedades fisicas de los copolimeros de redes atenuadas por cloruro de polivinilo obtenidos por irradiacion.
IAEA.
Pinner, S H.
1960.
"Physical Properties of P.V.C. Attenuated Network Copolymers Produced by Ionizing Radiation; Proprietes physiques des copolymeres obtenus sous l'action de rayonnements ionisants et dont le reseau est attenue par l'effet du chlorure de polyvinyle; Fizicheskie svojstva polivinilkhloridnykh obednennykh tsepej sopolimerov, poluchennykh v rezul'tate vozdejstviya ioniziruyushchej radiatsii; Propiedades fisicas de los copolimeros de redes atenuadas por cloruro de polivinilo obtenidos por irradiacion."
IAEA.
@misc{etde_22025814,
title = {Physical Properties of P.V.C. Attenuated Network Copolymers Produced by Ionizing Radiation; Proprietes physiques des copolymeres obtenus sous l'action de rayonnements ionisants et dont le reseau est attenue par l'effet du chlorure de polyvinyle; Fizicheskie svojstva polivinilkhloridnykh obednennykh tsepej sopolimerov, poluchennykh v rezul'tate vozdejstviya ioniziruyushchej radiatsii; Propiedades fisicas de los copolimeros de redes atenuadas por cloruro de polivinilo obtenidos por irradiacion}
author = {Pinner, S H}
abstractNote = {The cross-linking of polyvinyl chloride with ionizing radiation poses special problems. Due to rather unfavourable cross-linking and dislinking parameters for this polymer, the radiation doses necessary for high cross-link densities are uneconomicall y large and discolouration and dehydrohalogenatio n are simultaneously produced. These difficulties have been overcome by the incorporation into the P. V. C., prior to irradiation, of diallyl and triallyl esters. Heavily cross-linked products are thereby obtained with relatively low doses of ionizing radiation. Examination of the physical properties of the products suggests that these are not simply graft copolymers, which term normally implies the presence of long branch chains, but are polymer attenuated allyl networks. In these materials, the desirable properties of the parent polymer and of the allyl network are combined. The tensile strength, modulus and elongation of the attenuated network copolymers are presented and discussed as a function of temperature and of the concentration and functionality of the allyl ester. Reference is also made to the swelling and chemical resistance of the products. (author) [French] La reticulation du chlorure de polyvinyle sous l'action des rayonnements ionisants pose des problemes particuliers. Les parametres de reticulation et de degradation etant plutot defavorables pour ce polymere, les doses d'irradiation necessaires a l'obtention de fortes densites de pontage sont trop elevees pour donner des resultats economiquement interessants; elles provoquent simultanement la decoloration et la deshalogenhydratation. Il a ete possible de surmonter ces difficultes par introduction d'esters diallyliques et triallyliques dans le chlorure de polyvinyle, avant irradiation. Ce procede permet d'obtenir au moyen de doses d'irradiation relativement faibles des produits fortement reticules. L'etude des proprietes physiques de ces produits montre qu'il s'agit non pas de simples copolymeres greffes - terme qui implique normalement la presence de longues chaines ramifiees - mais de reseaux allyliques attenues sous l'action d'un polymere. Ces produits reunissent les proprietes recherchees du polymere ascendant et celles du reseau allylique. La resistance a la traction, les modules d'elasticite et l'allongement des copolymeres a reseau attenue sont exposes et examines en fonction de la temperature ambiante ainsi que de la concentration et du nombre de groupes fonctionnels de l'ester allylique. L'auteur explique ainsi la resistance des produits au gonflement et a l'action chimique. (author) [Spanish] La reticulacion del cloruro de polivinilo por la accion de las radiaciones ionizantes plantea problemas especiales. A causa de los parametros de reticulacion y de ruptura de los enlaces transversales de este polimero que son mas bien desfavorables, las dosis de radiacion necesarias para obtener un elevado grado de reticulacion son, desde un punto de vista economico, excesivamente costosas y se producen simultaneamente efectos de decoloracion y de deshidrohalogenacion. Se han superado estos obstaculos anadiendo asteres de dialilo y trialilo al cloruro de polivinilo, antes de la irradiacion. De esta forma, se obtienen productos de elevado grado de reticulacion con dosis de radiaciones ionizantes relativamente pequenas. Al examinar las propiedades fisicas de estos productos, se observa que-no son simplemento copolimeros de injerto, termino que normalmente supone la presencia de largas cadenas ramificadas, sino que son redes alilicas atenuadas por polimeros. En este producto se combinan las valiosas propiedades del polimero original y de la red alilica. La resistencia a la traccion, el modulo de elasticidad y la elongacion de esos copolimeros se estudian en funcion de la temperatura y de la concentracion y caracteristicas funcionales del ester alilico. Tambien se estudia la turgencia y la resistencia quimica de los productos obtenidos. (author) [Russian] Obrazovanie perekrestnykh svyazej v polivinilkhloride s pomoshch'yu ioniziruyushchej radiatsii stavit osobye problemy. V svyazi s neblagopriyatnym obrazovaniem poperechnykh svyazej i parametrami razrusheniya svyazej dlya dannogo polimera dozy radiatsii, neobkhodimye dlya obrazovaniya prochnykh tsoperechnykh plotnostej soedinenij, yavlyayutsya slishkom bol'shimi i parallel'no s ehtim proiskhodit protsess obestsvechivaniya i degidrogalogenirovaniya. EHti trudnosti udalos' preodolet' putem vvedeniya diallilovykh i triallilovykh ehfirov v polivinilkhlorid eshche do oblucheniya. Takim obrazom udalos' poluchit' produkty s prochnymi poperechnymi svyazyami pri otnositel'no malykh dozakh ioniziruyushchej radiatsii. Proverka fizicheskikh svojstv dannykh produktov pokazyvaet, chto oni yavlyayutsya ne prostymi graft-sopolimerami, chto obychno svyazano s prisutstviem dlinnykh razvetvlennykh tsepej, a obednennymi allilovymi polimernymi svyazyami. V ehtikh materialakh sochetayutsya svojstva iskhodnogo polimera i allilovoj svyazi. V doklade govoritsya o prochnosti na razryv, module i rastyazhenii oslablennoj svyazi sopolimerov, kotorye rassmatrivayutsya v zavisimosti ot temperatury, kontsentratsii i roli allilovogo ehfira. Takzhe privodyatsya zamechaniya po stojkosti poluchennykh produktov k razbukhaniyu i k khimicheskomu vozdejstviyu. (author)}
place = {IAEA}
year = {1960}
month = {Jul}
}
title = {Physical Properties of P.V.C. Attenuated Network Copolymers Produced by Ionizing Radiation; Proprietes physiques des copolymeres obtenus sous l'action de rayonnements ionisants et dont le reseau est attenue par l'effet du chlorure de polyvinyle; Fizicheskie svojstva polivinilkhloridnykh obednennykh tsepej sopolimerov, poluchennykh v rezul'tate vozdejstviya ioniziruyushchej radiatsii; Propiedades fisicas de los copolimeros de redes atenuadas por cloruro de polivinilo obtenidos por irradiacion}
author = {Pinner, S H}
abstractNote = {The cross-linking of polyvinyl chloride with ionizing radiation poses special problems. Due to rather unfavourable cross-linking and dislinking parameters for this polymer, the radiation doses necessary for high cross-link densities are uneconomicall y large and discolouration and dehydrohalogenatio n are simultaneously produced. These difficulties have been overcome by the incorporation into the P. V. C., prior to irradiation, of diallyl and triallyl esters. Heavily cross-linked products are thereby obtained with relatively low doses of ionizing radiation. Examination of the physical properties of the products suggests that these are not simply graft copolymers, which term normally implies the presence of long branch chains, but are polymer attenuated allyl networks. In these materials, the desirable properties of the parent polymer and of the allyl network are combined. The tensile strength, modulus and elongation of the attenuated network copolymers are presented and discussed as a function of temperature and of the concentration and functionality of the allyl ester. Reference is also made to the swelling and chemical resistance of the products. (author) [French] La reticulation du chlorure de polyvinyle sous l'action des rayonnements ionisants pose des problemes particuliers. Les parametres de reticulation et de degradation etant plutot defavorables pour ce polymere, les doses d'irradiation necessaires a l'obtention de fortes densites de pontage sont trop elevees pour donner des resultats economiquement interessants; elles provoquent simultanement la decoloration et la deshalogenhydratation. Il a ete possible de surmonter ces difficultes par introduction d'esters diallyliques et triallyliques dans le chlorure de polyvinyle, avant irradiation. Ce procede permet d'obtenir au moyen de doses d'irradiation relativement faibles des produits fortement reticules. L'etude des proprietes physiques de ces produits montre qu'il s'agit non pas de simples copolymeres greffes - terme qui implique normalement la presence de longues chaines ramifiees - mais de reseaux allyliques attenues sous l'action d'un polymere. Ces produits reunissent les proprietes recherchees du polymere ascendant et celles du reseau allylique. La resistance a la traction, les modules d'elasticite et l'allongement des copolymeres a reseau attenue sont exposes et examines en fonction de la temperature ambiante ainsi que de la concentration et du nombre de groupes fonctionnels de l'ester allylique. L'auteur explique ainsi la resistance des produits au gonflement et a l'action chimique. (author) [Spanish] La reticulacion del cloruro de polivinilo por la accion de las radiaciones ionizantes plantea problemas especiales. A causa de los parametros de reticulacion y de ruptura de los enlaces transversales de este polimero que son mas bien desfavorables, las dosis de radiacion necesarias para obtener un elevado grado de reticulacion son, desde un punto de vista economico, excesivamente costosas y se producen simultaneamente efectos de decoloracion y de deshidrohalogenacion. Se han superado estos obstaculos anadiendo asteres de dialilo y trialilo al cloruro de polivinilo, antes de la irradiacion. De esta forma, se obtienen productos de elevado grado de reticulacion con dosis de radiaciones ionizantes relativamente pequenas. Al examinar las propiedades fisicas de estos productos, se observa que-no son simplemento copolimeros de injerto, termino que normalmente supone la presencia de largas cadenas ramificadas, sino que son redes alilicas atenuadas por polimeros. En este producto se combinan las valiosas propiedades del polimero original y de la red alilica. La resistencia a la traccion, el modulo de elasticidad y la elongacion de esos copolimeros se estudian en funcion de la temperatura y de la concentracion y caracteristicas funcionales del ester alilico. Tambien se estudia la turgencia y la resistencia quimica de los productos obtenidos. (author) [Russian] Obrazovanie perekrestnykh svyazej v polivinilkhloride s pomoshch'yu ioniziruyushchej radiatsii stavit osobye problemy. V svyazi s neblagopriyatnym obrazovaniem poperechnykh svyazej i parametrami razrusheniya svyazej dlya dannogo polimera dozy radiatsii, neobkhodimye dlya obrazovaniya prochnykh tsoperechnykh plotnostej soedinenij, yavlyayutsya slishkom bol'shimi i parallel'no s ehtim proiskhodit protsess obestsvechivaniya i degidrogalogenirovaniya. EHti trudnosti udalos' preodolet' putem vvedeniya diallilovykh i triallilovykh ehfirov v polivinilkhlorid eshche do oblucheniya. Takim obrazom udalos' poluchit' produkty s prochnymi poperechnymi svyazyami pri otnositel'no malykh dozakh ioniziruyushchej radiatsii. Proverka fizicheskikh svojstv dannykh produktov pokazyvaet, chto oni yavlyayutsya ne prostymi graft-sopolimerami, chto obychno svyazano s prisutstviem dlinnykh razvetvlennykh tsepej, a obednennymi allilovymi polimernymi svyazyami. V ehtikh materialakh sochetayutsya svojstva iskhodnogo polimera i allilovoj svyazi. V doklade govoritsya o prochnosti na razryv, module i rastyazhenii oslablennoj svyazi sopolimerov, kotorye rassmatrivayutsya v zavisimosti ot temperatury, kontsentratsii i roli allilovogo ehfira. Takzhe privodyatsya zamechaniya po stojkosti poluchennykh produktov k razbukhaniyu i k khimicheskomu vozdejstviyu. (author)}
place = {IAEA}
year = {1960}
month = {Jul}
}