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Investigations of the chemical states of carrier-free phosphorus-32 as extracted into water from pile-irradiated sulphur; Recherches sur les etats chimiques du phosphore-32 sans entraineur obtenu par extraction aqueuse a partir de soufre irradie dans un reacteur; Issledovanie khimicheskogo sostoyaniya svobodnogo ot nositelya fosfora-32 pri izvlechenii ego v vodu iz obluchennoj v yadernom reaktore sery; Estudio de los estados quimicos del fosforo-32 libre de portador que se obtiene por extraccion acuosa del azufre irradiado en un reactor

Conference:

Abstract

One of the methods of producing carrier free phosphorus-32 today is by extraction into water from pile-irradiated sulphur. The present work gives information concerning the chemical states of P{sup 32} in aqueous solutions at different steps of the routine production-process. The variation in the chemical state of P{sup 32} compounds in the final product has also been examined as a function of storage time. P{sup 32} bound as orthophosphate was found to be the main component. During the chemical processing, the amount of orthophosphate increased from about 70% at the beginning of the extraction to about 98 % in the final carrier-free P{sup 32} product. The residual amount consisted of a mixture of pyro-, tri-, tetra-, and other long-chain polyphosphates (number of P {>=} 5). No metaphosphates (ring-formed) were found in the solutions during production and storage. The results indicate that the polyphosphorus compounds were formed in the target material during irradiation. Special attention was paid to the adsorption of carrier-free P{sup 32} compounds to glassware under the existing experimental conditions. (author) [French] L'une des methodes employee a l'heure actuelle pour obtenir du phosphore-32 sans entraineur consiste a l'extraire dans l'eau a partir de soufre irradie dans un reacteur. Les  More>>
Authors:
Dahl, J B; Birkelund, O R [1] 
  1. Institutt for Atomenergi, Kjeller, Lillestrom (Norway)
Publication Date:
Jan 15, 1962
Product Type:
Conference
Resource Relation:
Conference: Conference on the Use of Radioisotopes in the Physical Sciences and Industry, Copenhagen (Denmark), 6-17 Sep 1960; Other Information: 12 figs, 5 tabs, 14 refs; Related Information: In: Radioisotopes in the Physical Sciences and Industry. Proceedings of the Conference on the Use of Radioisotopes in the Physical Sciences and Industry. V. II| 566 p.
Subject:
07 ISOTOPES AND RADIATION SOURCES; ADSORPTION; AQUEOUS SOLUTIONS; CHEMICAL STATE; EXTRACTION; IRRADIATION; PHOSPHATES; PHOSPHORUS 32; SULFUR; WATER
OSTI ID:
22025698
Research Organizations:
International Atomic Energy Agency, Vienna (Austria); United Nations Educational, Scientific and Cultural Organization, Paris (France)
Country of Origin:
IAEA
Language:
English
Other Identifying Numbers:
Other: ISSN 0074-1884; TRN: XA12N1714112991
Submitting Site:
INIS
Size:
page(s) 470-493
Announcement Date:
Jan 16, 2013

Conference:

Citation Formats

Dahl, J B, and Birkelund, O R. Investigations of the chemical states of carrier-free phosphorus-32 as extracted into water from pile-irradiated sulphur; Recherches sur les etats chimiques du phosphore-32 sans entraineur obtenu par extraction aqueuse a partir de soufre irradie dans un reacteur; Issledovanie khimicheskogo sostoyaniya svobodnogo ot nositelya fosfora-32 pri izvlechenii ego v vodu iz obluchennoj v yadernom reaktore sery; Estudio de los estados quimicos del fosforo-32 libre de portador que se obtiene por extraccion acuosa del azufre irradiado en un reactor. IAEA: N. p., 1962. Web.
Dahl, J B, & Birkelund, O R. Investigations of the chemical states of carrier-free phosphorus-32 as extracted into water from pile-irradiated sulphur; Recherches sur les etats chimiques du phosphore-32 sans entraineur obtenu par extraction aqueuse a partir de soufre irradie dans un reacteur; Issledovanie khimicheskogo sostoyaniya svobodnogo ot nositelya fosfora-32 pri izvlechenii ego v vodu iz obluchennoj v yadernom reaktore sery; Estudio de los estados quimicos del fosforo-32 libre de portador que se obtiene por extraccion acuosa del azufre irradiado en un reactor. IAEA.
Dahl, J B, and Birkelund, O R. 1962. "Investigations of the chemical states of carrier-free phosphorus-32 as extracted into water from pile-irradiated sulphur; Recherches sur les etats chimiques du phosphore-32 sans entraineur obtenu par extraction aqueuse a partir de soufre irradie dans un reacteur; Issledovanie khimicheskogo sostoyaniya svobodnogo ot nositelya fosfora-32 pri izvlechenii ego v vodu iz obluchennoj v yadernom reaktore sery; Estudio de los estados quimicos del fosforo-32 libre de portador que se obtiene por extraccion acuosa del azufre irradiado en un reactor." IAEA.
@misc{etde_22025698,
title = {Investigations of the chemical states of carrier-free phosphorus-32 as extracted into water from pile-irradiated sulphur; Recherches sur les etats chimiques du phosphore-32 sans entraineur obtenu par extraction aqueuse a partir de soufre irradie dans un reacteur; Issledovanie khimicheskogo sostoyaniya svobodnogo ot nositelya fosfora-32 pri izvlechenii ego v vodu iz obluchennoj v yadernom reaktore sery; Estudio de los estados quimicos del fosforo-32 libre de portador que se obtiene por extraccion acuosa del azufre irradiado en un reactor}
author = {Dahl, J B, and Birkelund, O R}
abstractNote = {One of the methods of producing carrier free phosphorus-32 today is by extraction into water from pile-irradiated sulphur. The present work gives information concerning the chemical states of P{sup 32} in aqueous solutions at different steps of the routine production-process. The variation in the chemical state of P{sup 32} compounds in the final product has also been examined as a function of storage time. P{sup 32} bound as orthophosphate was found to be the main component. During the chemical processing, the amount of orthophosphate increased from about 70% at the beginning of the extraction to about 98 % in the final carrier-free P{sup 32} product. The residual amount consisted of a mixture of pyro-, tri-, tetra-, and other long-chain polyphosphates (number of P {>=} 5). No metaphosphates (ring-formed) were found in the solutions during production and storage. The results indicate that the polyphosphorus compounds were formed in the target material during irradiation. Special attention was paid to the adsorption of carrier-free P{sup 32} compounds to glassware under the existing experimental conditions. (author) [French] L'une des methodes employee a l'heure actuelle pour obtenir du phosphore-32 sans entraineur consiste a l'extraire dans l'eau a partir de soufre irradie dans un reacteur. Les auteurs donnent des indications sur l'etat chimique du phosphore-32 dans des solutions aqueuses, a differentes etapes du processus de preparation courant. Us examinent aussi les changements de l'etat chimique des composes du phosphore-32 dans le produit final en fonction de la duree de stockage. On a constate que le {sup 32}P combine sous forme d'orthophosphate etait le principal composant. Au cours du traitement chimique, la teneur en orthophosphate est passee d'environ 70% au debut de l'extraction a environ 98% lors de l'obtention du produit final sans entraineur. Le reste etait constitue d'un melange de pyro-, tri-, tetra- et autres polyphosphates a chaine longue (P {>=} 5). Aucun metaphosphate (cyclique) n'a ete decele dans la solution lors de la production et du stockage. Les resultats indiquent que les composes de polyphosphore ont ete formes dans le materiau de cible au cours de l'irradiation. On a etudie plus particulierement l'adsorption des composes du phosphore-32 sans entraineur par le verre dans les conditions de l'experience. (author) [Spanish] Uno de los metodos que se emplean para obtener fosforo-32 libre de portador consiste en irradiar azufre en un reactor y extraer con agua el fosforo formado. La presente memoria informa sobre los estados quimicos del fosforo-32 en soluciones acuosas durante las diversas fases del proceso normal de obtencion. Los autores han estudiado tambien las modificaciones que el estado quimico de los compuestos de fosforo-32 experimenta en el producto final, en funcion del tiempo de almacenamiento. Han encontrado que el fosforo-32 aparece principalmente en forma de orto-fosfato. La proporcion de ortofosfato aumenta durante el tratamiento quimico; al comenzar la extraccion, es del orden del 70 por ciento, en tanto que alrededor del 98 por ciento del fosforo-32 libre de portador obtenido como producto final se encuentra bajo forma de ortofosfato. Los componentes restantes de la mezcla consisten en piro-, tri-, tetra- y polifosfatos de cadena larga (con un numero de atomos de fosforo {>=} 5). Durante la elaboracion y almacenamiento los autores no han encontrado metafosfatos (ciclicos) en ninguna de las soluciones. Los resultados obtenidos indican que los compuestos polifosforicos se formaron en el material del blanco durante la irradiacion. Los autores han prestado especial atencion al estudio de la adsorcion de compuestos de fosforo-32 libre de portador por el material de vidrio en las condiciones experimentales. (author) [Russian] Odnim iz sovremennykh metodov polucheniya svobodnogo ot nositelya fosfora-32 yavlyaetsya izvlechenie ego v vodu iz obluchennoj v yader- nom reaktore sery. V nastoyashchem doklade dayutsya svedeniya otnositel'no khimicheskogo sostoyaniya fosfora-32 v vodnykh rastvorakh na razlichnykh stadiyakh prinyatogo v praktike protsessa polucheniya ehtogo ehlementa. Byli rassmotreny takzhe izmeneniya khimicheskogo sostoyaniya slozhnykh soedine- nij fosfora-32 v konechnykh produktakh v funktsii ot vremeni khraneniya. Bylo obnaruzheno, chto glavnym sostavlyayushchim veshchestvom yavlyaetsya fosfor-32, svyazan- nyj v vide ortofosfata. Po mere khimicheskoj obrabotki kolichestvo ortofosfata uvelichi- los' priblizitel'no s 70% pri nachale izvlecheniya i priblizitel'no do 98% v konechnom produkte svobodnogo ot nositelya fosfora-32. Ostatok sostoyal iz smesi piro-, tri-, tetra- i polifosfatov s dlinnoj tsep'yu (chislo P {>=} 5). Ni vo vremya obrazovaniya, ni vo vremya khraneniya v rastvorakh ne bylo obnaruzheno (kol'tseobraznykh) metafosfatov. EHti rezul'taty pokazyvayut, chto polifosfornye slozhnye soedineniya obrazovalis' v materiale misheni vo vremya oblucheniya. Osoboe vnimanie bylo obrashcheno na adsorbtsiyu svobodnogo ot nositelya fosfora-32 steklyannoj laboratornoj posudoj pri sushchestvuyushchikh ehksperimental'nykh usloviyakh. (author)}
place = {IAEA}
year = {1962}
month = {Jan}
}