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The determination of the thermodynamic activity of antimony in alpha-iron; Determination de l'activite thermodynamique de l'antimoine dans le fer alpha; Opredelenie termodinamicheskoj aktivnosti sur'my v al'fa-zheleze; Determinacion de la actividad termodinamica del antimonio en el hierro alfa

Conference:

Abstract

In this paper a method is suggested for determining the thermodynamic activity of antimony dissolved in alpha-iron, based on the study of antimony distribution between the two phases: liquid lead and solid iron. By this method, it was found that solid solutions of antimony in alpha-iron can be distinguished by positive divergences from the ideal state. Over a fairly wide range of concentrations, solutions of antimony in iron obey Henry's law. Special experiments on the distribution of antimony between lead and liquid iron showed that in the liquid state also the iron-antimony system is marked by positive divergences from the ideal state when small concentrations of antimony are present. The heat required for the solution of antimony in alpha-iron, and the excess partial molar entropy, were calculated from the activity temperature. The results were used for accurately locating the line showing the solubility limit of antimony in alpha-iron. Since alloys of antimony with iron were obtained by diffusion saturation and not by cooling from the liquid state, there was no liquefaction. Thus the lattice constant of the alloys and its relation to the alloy concentration could be reliably determined. The solubility limit established from X-ray data agrees with that obtained  More>>
Authors:
Publication Date:
Jan 15, 1962
Product Type:
Conference
Resource Relation:
Conference: Conference on the Use of Radioisotopes in the Physical Sciences and Industry, Copenhagen (Denmark), 6-17 Sep 1960; Other Information: 6 figs, 2 tabs, 6 refs; Related Information: In: Radioisotopes in the Physical Sciences and Industry. Proceedings of the Conference on the Use of Radioisotopes in the Physical Sciences and Industry. V. 1| 556 p.
Subject:
36 MATERIALS SCIENCE; ALLOYS; ANTIMONY; ANTIMONY 124; DISTRIBUTION; ENTROPY; IRON-ALPHA; LEAD; LIQUEFACTION; LIQUIDS; SATURATION; SOLID SOLUTIONS; SOLIDS; SOLUBILITY; THERMODYNAMIC ACTIVITY; X RADIATION
OSTI ID:
22025629
Research Organizations:
International Atomic Energy Agency, Vienna (Austria); United Nations Educational, Scientific and Cultural Organization, Paris (France)
Country of Origin:
IAEA
Language:
Russian
Other Identifying Numbers:
Other: ISSN 0074-1884; TRN: XA12N1608112922
Submitting Site:
INIS
Size:
page(s) 225-233
Announcement Date:
Jan 17, 2013

Conference:

Citation Formats

Tomilin, I A. The determination of the thermodynamic activity of antimony in alpha-iron; Determination de l'activite thermodynamique de l'antimoine dans le fer alpha; Opredelenie termodinamicheskoj aktivnosti sur'my v al'fa-zheleze; Determinacion de la actividad termodinamica del antimonio en el hierro alfa. IAEA: N. p., 1962. Web.
Tomilin, I A. The determination of the thermodynamic activity of antimony in alpha-iron; Determination de l'activite thermodynamique de l'antimoine dans le fer alpha; Opredelenie termodinamicheskoj aktivnosti sur'my v al'fa-zheleze; Determinacion de la actividad termodinamica del antimonio en el hierro alfa. IAEA.
Tomilin, I A. 1962. "The determination of the thermodynamic activity of antimony in alpha-iron; Determination de l'activite thermodynamique de l'antimoine dans le fer alpha; Opredelenie termodinamicheskoj aktivnosti sur'my v al'fa-zheleze; Determinacion de la actividad termodinamica del antimonio en el hierro alfa." IAEA.
@misc{etde_22025629,
title = {The determination of the thermodynamic activity of antimony in alpha-iron; Determination de l'activite thermodynamique de l'antimoine dans le fer alpha; Opredelenie termodinamicheskoj aktivnosti sur'my v al'fa-zheleze; Determinacion de la actividad termodinamica del antimonio en el hierro alfa}
author = {Tomilin, I A}
abstractNote = {In this paper a method is suggested for determining the thermodynamic activity of antimony dissolved in alpha-iron, based on the study of antimony distribution between the two phases: liquid lead and solid iron. By this method, it was found that solid solutions of antimony in alpha-iron can be distinguished by positive divergences from the ideal state. Over a fairly wide range of concentrations, solutions of antimony in iron obey Henry's law. Special experiments on the distribution of antimony between lead and liquid iron showed that in the liquid state also the iron-antimony system is marked by positive divergences from the ideal state when small concentrations of antimony are present. The heat required for the solution of antimony in alpha-iron, and the excess partial molar entropy, were calculated from the activity temperature. The results were used for accurately locating the line showing the solubility limit of antimony in alpha-iron. Since alloys of antimony with iron were obtained by diffusion saturation and not by cooling from the liquid state, there was no liquefaction. Thus the lattice constant of the alloys and its relation to the alloy concentration could be reliably determined. The solubility limit established from X-ray data agrees with that obtained with Sb{sup 124}. (author) [French] Le memoire propose, pour determiner l'activite thermodynamique de l'antimoine dissous dans le fer alpha, une methode fondee sur l'etude de la distribution de l'antimoine entre deux phases: plomb liquide et fer solide. La methode a permis d'etablir que les solutions solides de l'antimoine dans le fer alpha se distinguent par des divergences positives par rapport a l'etat parfait. Dans une gamme assez etendue de valeurs de la concentration, les solutions de l'antimoine dans le fer sont regies par la loi de Henry. Des experiences sur la repartition de l'antimoine entre le plomb et le fer liquide ont montre qu'a l'etat liquide, le systeme ferantimoine est caracterise par des divergences positives par rapport a l'etat parfait lorsque les concentrations d'antimoine present sont peu importantes. L'auteur a calcule la quantite de chaleur necessaire pour dissoudre l'antimoine dans le fer, ainsi que l'excedent d'entropie molaire partielle d'apres la temperature d'activite. Il s'est servi des resultats obtenus pour determiner avec precision la ligne qui marque la limite de solubilite de l'antimoine dans le fer alpha. Etant donne que les ferroalliages d'antimoine avaient ete obtenus par voie de saturation de diffusion, et non par refroidissement a partir de l'etat liquide, il n'y a pas eu de liquefaction. L'auteur a donc pu determiner d'une facon sure la constante du reseau des alliages et la relation entre cette constante et la concentration de l'antimoine. La limite de solubilite determinee d'apres les donnees radiographiques correspond a celle que l'on obtient en employant l'antimoine-124. (author) [Spanish] La memoria propone un metodo para determinar la actividad termodinamica del antimonio disuelto en el hierro alfa, que se basa en el estudio de la reparticion de este metal entre dos fases: plomo liquido y hierro solido. El metodo permitio observar que las soluciones solidas de antimonio en hierro se desvian en sentido positivo del estado ideal. Las soluciones de este elemente en el hierro obedecen a la ley de Henry en un intervalo muy extenso de concentraciones. Los experimentos especiales realizados para estudiar la reparticion del antimonio entre el plomo y el hierro en estado liquido han demostrado que, en estado liquido, el sistema hierro-antimonio se caracteriza por su desviacion positiva respecto del estado ideal cuando la concentracion del segundo elemento es baja. Los autores calcularon el calor necesario para la disolucion del antimonio en el hierro alfa, y el incremento de entropia molar parcial a partir de la temperatura de activacion. Los resultados obtenidos han servido para establecer con precision el limite de solubilidad del antimonio en el hierro alfa. Como habian obtenido las aleaciones de antimonio y hierro saturandolas por difusion y no por enfriamiento a partir del estado liquido, no observaron fusion alguna. Esta circunstancia les permitio determinar con exactitud la constante de la red cristalina de las aleaciones y la medida en que esa constante depende de la concentracion de antimonio. El limite de solubilidad determinado por datos roentgenograficos concuerda con el hallado utilizando el {sup 124}Sb. (author) [Russian] V rabote predlozhen metod opredeleniya termodinamicheskoj aktivnosti sur'my, rastvorennoj v al'fa-zheleze, osnovannyj na izuchenii ee raspredeleniya mezhdu dvumya fazami - zhidkim svintsom i tverdym zhelezom. EHtim metodom bylo najdeno, chto tverdye rastvory sur'my v al'fa-zheleze otlichayutsya polozhitel'nymi otkloneniyami ot ideal'nosti. V dovol'no shirokoj oblasti kontsentratsij sur'my ee rastvory v zheleze podchinyayutsya zakonu Genri. Byli provedeny spetsial'nye opyty po izucheniyu raspredeleniya sur'my mezhdu svintsom i zhidkim zhelezom, kotorye pokazali, chto i v zhidkom sostoyanii sistema zhelezo-sur'ma, pri nebol'shikh kontsentratsiyakh poslednej, kharakterizuetsya polozhitel'nymi otkloneniyami ot ideal'nosti. Po temperaturnoj zavisimosti aktivnosti sur'my v al'fa-zheleze vychisleny teplota ee rastvoreniya i izbytochnaya partsial'naya molyarnaya ehntropiya. Poluchennye rezul'taty ispol'zovany dlya utochneniya polozheniya linii, ukazyvayushchej predel rastvorimosti sur'my v al'fa-zheleze. Blagodarya tomu, chto splavy sur'my s zhelezom byli polucheny putem diffuzionnogo nasyshcheniya, a ne okhlazhdeniya iz zhidkogo sostoyaniya, v nikh otsutstvovala likvatsiya. EHto obstoyatel'stvo pozvolilo nadezhno opredelit' postoyannuyu reshetki splavov i zavisimost' ee ot kontsentratsii sur'my. Opredelenie predela rastvorimosti po rentgenograficheskim dannym soglasuetsya s poluchennym pri ispol'zovanii Sb{sup 124}. (author)}
place = {IAEA}
year = {1962}
month = {Jan}
}