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Use of radioisotopes in studying the penetration of sulphur into iron during hydrogen cathode charging; Application des radioelements a l'etude de la penetration du soufre dans le fer lors du chargement en hydrogene cathodique; Ispol'zovanie radioehlementov dlya izucheniya proniknoveniya sery v zhelezo, kogda ona zaryazhaetsya katodnym vodorodom; Aplicacion de los radioelementos al estudio de la penetracion del azufre en el hierro durante la carga con hidrogeno catodico

Conference:

Abstract

Certain elements, such as arsenic for example, are commonly used in the laboratory to facilitate the penetration of hydrogen into iron. It has been found in industry that steel corrosion caused by hydrogen was aggravated by the presence of sulphurated hydrogen. It is an interesting question whether these elements, hitherto considered to be catalysts, merely permit a higher hydrogen absorption or whether they directly affect the metal. A study of this phenomenon is undertaken in the authors' laboratory, using electrolytic pure iron. Hydrogen supersaturation is effected by cathode charging. The addition element is S{sup 35}-labelled sodium sulphide. It is shown that, in half an hour, at -15 Degree-Sign C, the sulphur penetrates into the iron to a depth of some 120 {mu}m. A preferential localization of the sulphur at the grain boundaries is also noted. This result, which could not have been obtained without the help of radioactive tracers, has important consequences, especially for the oil industry. A similar study is made using phosphorus-32. (author) [French] Certains elements, comme l'arsenic par exemple, sont couramment utilises au laboratoire pour favoriser la penetration de l'hydrogene dans le fer. Dans l'industrie, on a constate que la corrosion des aciers due a l'hydrogene etait  More>>
Authors:
Besnard, S; Talbot, J [1] 
  1. Centre National de la Recherche Scientifique, Vitry (France)
Publication Date:
Jan 15, 1962
Product Type:
Conference
Resource Relation:
Conference: Conference on the Use of Radioisotopes in the Physical Sciences and Industry, Copenhagen (Denmark), 6-17 Sep 1960; Other Information: 7 figs, 5 refs; Related Information: In: Radioisotopes in the Physical Sciences and Industry. Proceedings of the Conference on the Use of Radioisotopes in the Physical Sciences and Industry. V. 1| 556 p.
Subject:
36 MATERIALS SCIENCE; ABSORPTION; ARSENIC; CATALYSTS; CATHODES; GRAIN BOUNDARIES; HYDROGEN; INDUSTRY; IRON; OILS; PHOSPHORUS 32; SULFUR; SUPERSATURATION
OSTI ID:
22025627
Research Organizations:
International Atomic Energy Agency, Vienna (Austria); United Nations Educational, Scientific and Cultural Organization, Paris (France)
Country of Origin:
IAEA
Language:
French
Other Identifying Numbers:
Other: ISSN 0074-1884; TRN: XA12N1606112920
Submitting Site:
INIS
Size:
page(s) 207-216
Announcement Date:
Jan 16, 2013

Conference:

Citation Formats

Besnard, S, and Talbot, J. Use of radioisotopes in studying the penetration of sulphur into iron during hydrogen cathode charging; Application des radioelements a l'etude de la penetration du soufre dans le fer lors du chargement en hydrogene cathodique; Ispol'zovanie radioehlementov dlya izucheniya proniknoveniya sery v zhelezo, kogda ona zaryazhaetsya katodnym vodorodom; Aplicacion de los radioelementos al estudio de la penetracion del azufre en el hierro durante la carga con hidrogeno catodico. IAEA: N. p., 1962. Web.
Besnard, S, & Talbot, J. Use of radioisotopes in studying the penetration of sulphur into iron during hydrogen cathode charging; Application des radioelements a l'etude de la penetration du soufre dans le fer lors du chargement en hydrogene cathodique; Ispol'zovanie radioehlementov dlya izucheniya proniknoveniya sery v zhelezo, kogda ona zaryazhaetsya katodnym vodorodom; Aplicacion de los radioelementos al estudio de la penetracion del azufre en el hierro durante la carga con hidrogeno catodico. IAEA.
Besnard, S, and Talbot, J. 1962. "Use of radioisotopes in studying the penetration of sulphur into iron during hydrogen cathode charging; Application des radioelements a l'etude de la penetration du soufre dans le fer lors du chargement en hydrogene cathodique; Ispol'zovanie radioehlementov dlya izucheniya proniknoveniya sery v zhelezo, kogda ona zaryazhaetsya katodnym vodorodom; Aplicacion de los radioelementos al estudio de la penetracion del azufre en el hierro durante la carga con hidrogeno catodico." IAEA.
@misc{etde_22025627,
title = {Use of radioisotopes in studying the penetration of sulphur into iron during hydrogen cathode charging; Application des radioelements a l'etude de la penetration du soufre dans le fer lors du chargement en hydrogene cathodique; Ispol'zovanie radioehlementov dlya izucheniya proniknoveniya sery v zhelezo, kogda ona zaryazhaetsya katodnym vodorodom; Aplicacion de los radioelementos al estudio de la penetracion del azufre en el hierro durante la carga con hidrogeno catodico}
author = {Besnard, S, and Talbot, J}
abstractNote = {Certain elements, such as arsenic for example, are commonly used in the laboratory to facilitate the penetration of hydrogen into iron. It has been found in industry that steel corrosion caused by hydrogen was aggravated by the presence of sulphurated hydrogen. It is an interesting question whether these elements, hitherto considered to be catalysts, merely permit a higher hydrogen absorption or whether they directly affect the metal. A study of this phenomenon is undertaken in the authors' laboratory, using electrolytic pure iron. Hydrogen supersaturation is effected by cathode charging. The addition element is S{sup 35}-labelled sodium sulphide. It is shown that, in half an hour, at -15 Degree-Sign C, the sulphur penetrates into the iron to a depth of some 120 {mu}m. A preferential localization of the sulphur at the grain boundaries is also noted. This result, which could not have been obtained without the help of radioactive tracers, has important consequences, especially for the oil industry. A similar study is made using phosphorus-32. (author) [French] Certains elements, comme l'arsenic par exemple, sont couramment utilises au laboratoire pour favoriser la penetration de l'hydrogene dans le fer. Dans l'industrie, on a constate que la corrosion des aciers due a l'hydrogene etait aggravee par la presence d'hydrogene sulfure. On pouvait se demander si ces corps, consideres jusqu'ici comme des catalyseurs, permettaient uniquement une plus grande absorption de l'hydrogene ou s'ils avaient une action directe sur le metal. L'etude de ce phenomene a ete entreprise dans notre laboratoire en utilisant du fer pur electrolytique. La sursaturation en hydrogene a ete realisee par chargement cathodique. L'element d'addition etait le sulfure de sodium marque au soufre-35. Nous avons pu montrer qu'en une demi-heure a -15 Degree-Sign C le soufre penetre dans le fer jusqu'a une profondeur de 120 {mu} environ. Par ailleurs, on a pu constater une localisation preferentielle du soufre aux joints des grains. Ce resultat, qui ne pouvait etre obtenu qu'avec l'aide des radiotraceurs, a des consequences importantes notamment dans l'industrie des petroles. Une etude analogue a ete faite en utilisant le radioisotope 32 du phosphore. (author) [Spanish] Determinados elementos, como por ejemplo el arsenico, se emplean corrientemente en el laboratorio para fomentar la penetracion del hidrogeno en el hierro. Por otra parte, se ha comprobado en la industria que la presencia de acido sulfhidrico intensifica la corrosion de los aceros por el hidrogeno. Cabia preguntarse si estas sustancias, que hasta ahora se consideraban como catalizadores, solo fomentan la absorcion del hidrogeno, o si ejercen una influencia directa sobre el metal. Los autores han estudiado este fenomeno en su laboratorio con ayuda de hierro electrolitico puro. Han efectuado la sobresaturacion con hidrogeno por carga catodica. Como sustancia de adicion emplearon sulfuro de sodio marcado con azufre-35. Lograron demostrar que en media hora a la temperatura de -15 Degree-Sign C, el azufre penetra en el hierro hasta una profundidad de unas 120 {mu}m. Han podido comprobar ademas que el azufre se localiza preferentemente en los limites intergranulares. Este resultado, que solo pudo obtenerse gracias a los indicadores radiactivos, tiene importantes consecuencias, en especial para la industria del petroleo. Los autores han realizado un estudio analogo utilizando el radioisotopo 32 del fosforo. (author) [Russian] Nekotorye ehlementy, kak naprimer mysh'yak, obychno ispol'zovalis' v laboratorii dlya oblegcheniya proniknoveniya vodoroda v zhelezo. V promyshlennosti bylo ustanovleno, chto korroziya stalej, vyzvannaya prisutstviem vodoroda, usilivaetsya pri nalichii sernistogo vodoroda. Voznikal vopros, dopuskali li ehti veshchestva, rassmatrivaemye do sikh por v kachestve katalizatorov, tol'ko samuyu bol'shuyu absorbtsiyu ili okazyvali neposredstvennoe vozdejstvie na metall. Izuchenie ehtogo yavleniya bylo predprinyato v nashej laboratorii s ispol'zovaniem chistogo ehlektroliticheskogo zheleza. Putem katodnoj nagruzki bylo polucheno vodorodnoe perenasyshchenie. EHlementom primesi byl sernistyj natrij, vystupayushchij kak ehlement sera-35. My smogli pokazat' chto v techenie poluchasa pri -15 Degree-Sign C sera pronikaet v zhelezo na glubinu okolo 120 mikronov. K tomu zhe bylo ustanovleno, chto sera preimushchestvenno razmeshchalas' na granulakh zeren. EHtot rezul'tat, kotoryj mog by byt' poluchen tol'ko s pomoshch'yu radioizotopov, imeet vazhnoe znachenie, osobenno v neftyanoj promyshlennosti. Podobnoe issledovanie bylo provedeno s ispol'zovaniem radioizotopa fosfor-32. (author)}
place = {IAEA}
year = {1962}
month = {Jan}
}