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Self-diffusion in volume and at the grain-boundaries of gamma-iron of high purity (99.99%); Autodiffusion en volume et aux joints de grains du fer gamma de haute purete (99,99 %); Ob'emnaya samodiffuziya i samodiffuziya na poverkhnosti granul zheleza u vysokoj chistoty (99,99%); Autodifusion en volumen y en los limites intergranulares del hierro gamma de elevada pureza (99,99 por ciento)

Conference:

Abstract

In view of the difficulty of measuring accurately self-diffusion coefficients, whether in the mass or at grain boundaries, within a given temperature range in which the two phenomena co-exist, the authors decided to reconsider the classical cutting method. The authors establish that, in the case of a semi-infinite solid, the post-diffusion concentration C(x{sub n}) of radioactive atoms at distance x{sub n} from the initial radioactive deposit is a simple function of the overall activity remaining in the sample after abrasion to depth x{sub n}. This conclusion is reached as a result of the general application of the GRUZIN formula which up to now had been applied only to diffusion in volume. The authors show that by measuring the remaining overall activity as a function of the depth of penetration they can distinguish the part of the activity due to self-diffusion in volume from that due to intergranular self-diffusion. The advantage of this method is, therefore, that it enables one to follow continuously on the same sample the passage from self-diffusion in volume to intergranular self-diffusion. The authors use this new method for measuring the self-diffusion constants in gamma iron in volume between 1260 and 918 Degree-Sign C and at grain  More>>
Authors:
Lacombe, P; Guiraldenq, P; Leymonie, C [1] 
  1. Centre de Recherches Metallurgiques, Ecole Nationale Superieure des Mines, Paris (France)
Publication Date:
Jan 15, 1962
Product Type:
Conference
Resource Relation:
Conference: Conference on the Use of Radioisotopes in the Physical Sciences and Industry, Copenhagen (Denmark), 6-17 Sep 1960; Other Information: 10 figs, 2 tabs, 14 refs; Related Information: In: Radioisotopes in the Physical Sciences and Industry. Proceedings of the Conference on the Use of Radioisotopes in the Physical Sciences and Industry. V. 1| 556 p.
Subject:
36 MATERIALS SCIENCE; ABRASION; DEPOSITS; GRAIN BOUNDARIES; IMPURITIES; IRON; SELF-DIFFUSION; SOLIDS
OSTI ID:
22025625
Research Organizations:
International Atomic Energy Agency, Vienna (Austria); United Nations Educational, Scientific and Cultural Organization, Paris (France)
Country of Origin:
IAEA
Language:
French
Other Identifying Numbers:
Other: ISSN 0074-1884; TRN: XA12N1604112918
Submitting Site:
INIS
Size:
page(s) 179-192
Announcement Date:
Jan 17, 2013

Conference:

Citation Formats

Lacombe, P, Guiraldenq, P, and Leymonie, C. Self-diffusion in volume and at the grain-boundaries of gamma-iron of high purity (99.99%); Autodiffusion en volume et aux joints de grains du fer gamma de haute purete (99,99 %); Ob'emnaya samodiffuziya i samodiffuziya na poverkhnosti granul zheleza u vysokoj chistoty (99,99%); Autodifusion en volumen y en los limites intergranulares del hierro gamma de elevada pureza (99,99 por ciento). IAEA: N. p., 1962. Web.
Lacombe, P, Guiraldenq, P, & Leymonie, C. Self-diffusion in volume and at the grain-boundaries of gamma-iron of high purity (99.99%); Autodiffusion en volume et aux joints de grains du fer gamma de haute purete (99,99 %); Ob'emnaya samodiffuziya i samodiffuziya na poverkhnosti granul zheleza u vysokoj chistoty (99,99%); Autodifusion en volumen y en los limites intergranulares del hierro gamma de elevada pureza (99,99 por ciento). IAEA.
Lacombe, P, Guiraldenq, P, and Leymonie, C. 1962. "Self-diffusion in volume and at the grain-boundaries of gamma-iron of high purity (99.99%); Autodiffusion en volume et aux joints de grains du fer gamma de haute purete (99,99 %); Ob'emnaya samodiffuziya i samodiffuziya na poverkhnosti granul zheleza u vysokoj chistoty (99,99%); Autodifusion en volumen y en los limites intergranulares del hierro gamma de elevada pureza (99,99 por ciento)." IAEA.
@misc{etde_22025625,
title = {Self-diffusion in volume and at the grain-boundaries of gamma-iron of high purity (99.99%); Autodiffusion en volume et aux joints de grains du fer gamma de haute purete (99,99 %); Ob'emnaya samodiffuziya i samodiffuziya na poverkhnosti granul zheleza u vysokoj chistoty (99,99%); Autodifusion en volumen y en los limites intergranulares del hierro gamma de elevada pureza (99,99 por ciento)}
author = {Lacombe, P, Guiraldenq, P, and Leymonie, C}
abstractNote = {In view of the difficulty of measuring accurately self-diffusion coefficients, whether in the mass or at grain boundaries, within a given temperature range in which the two phenomena co-exist, the authors decided to reconsider the classical cutting method. The authors establish that, in the case of a semi-infinite solid, the post-diffusion concentration C(x{sub n}) of radioactive atoms at distance x{sub n} from the initial radioactive deposit is a simple function of the overall activity remaining in the sample after abrasion to depth x{sub n}. This conclusion is reached as a result of the general application of the GRUZIN formula which up to now had been applied only to diffusion in volume. The authors show that by measuring the remaining overall activity as a function of the depth of penetration they can distinguish the part of the activity due to self-diffusion in volume from that due to intergranular self-diffusion. The advantage of this method is, therefore, that it enables one to follow continuously on the same sample the passage from self-diffusion in volume to intergranular self-diffusion. The authors use this new method for measuring the self-diffusion constants in gamma iron in volume between 1260 and 918 Degree-Sign C and at grain boundaries between 1020 and 918 Degree-Sign C. (author) [French] En raison des difficultes rencontrees dans la mesure precise des coefficients d'autodiffusion, soit massique, soit intergranulaire dans certains intervalles de temperature ou les deux phenomenes coexistent, les auteurs ont ete conduits a reconsiderer la methode classique de sectionnement. Ils ont en effet constate que pour un solide semi-infini, la concentration apres diffusion en atomes radioactifs C (x{sub n}) a la distance x{sub n} du depot radioactif initial est une fonction simple de l'activite globale restant dans l'echantillon apres son abrasion, jusqu'a la profondeur x{sub n}. Cette conclusion resulte de la generalisation de la formule de Gruzin, qui jusqu'ici avait ete appliquee uniquement a la diffusion en volume. En fait les auteurs montrent que l'on peut, par mesure de l'activite globale restante en fonction de la profondeur de penetration, distinguer la part de l'activite due a l'autodiffusion en volume de celle due a l'autodiffusion intergranulaire. L'interet de la methode est donc de suivre en continu sur un meme echantillon le passage de l'autodiffusion en volume a l'autodiffusion intergranulaire. Cette methode nouvelle a ete appliquee a la mesure des constantes d'autodiffusion en volume dans le fer gamma entre 1.260 Degree-Sign et 918 Degree-Sign C et celle aux joints des grains entre 1.020 Degree-Sign et 918 Degree-Sign C. (author) [Spanish] En vista de las dificultades que presenta la medicion exacta de los coeficientes de autodifusion, tanto masica como intergranular, en ciertos intervalos de temperatura en los que ambos fenomenos coexisten, los autores han vuelto a estudiar el metodo clasico de seccionamiento. Efectivamente, han comprobado que para un solido semi-infinito, la concentracion de atomos radiactivos C (x{sub n}), despues de la difusion, a la distancia x{sub n} del deposito radiactivo inicial es una funcion simple de la actividad global que queda en la muestra despues de una abrasion hasta la profundidad x{sub n}. Esta conclusion surge de la generalizacion de la formula de GRUZIN, que hasta ahora solo se habia aplicado a la difusion en volupien. Los autores han demostrado que, midiendo la actividad global que queda en funcion de la profundidad de penetracion, se puede distinguir la parte de la actividad debida a la autodifusion masica, de la actividad atribuible a la autodifusion intergranular. Por lo tanto, el interes del metodo estriba en que permite observar de modo continuo en una misma muestra la transicion de la autodifusion masica a la autodifusion intergranular. Los autores han aplicado este nuevo metodo a la medicion, en el hierro en fase gamma, de las constantes de autodifusion masica entre 1260 Degree-Sign y 918 Degree-Sign C, y de las constantes de autodifusion en las uniones intergranulares entre 1020 Degree-Sign y 918 Degree-Sign C. (author) [Russian] Vvidu trudnostej, s kotorymi vstretilis' pri tochnom izmerenii koehffitsientov samodiffuzii kak vnutri, tak i mezhdu samimi granulami v nekotorykh intervalakh temperatury, kogda sosushchestvuyut oba yavleniya, my byli vynuzhdeny pribegnut' k obychnomu metodu deleniya na chasti. V samom dele my uzhe ustanovili, chto dlya vyazkogo polutverdogo tela posle diffuzii kontsentratsiya radioaktivnykh atomov c (x{sub n}) na rasstoyanii x{sub n} ot pervonachal'nogo radioaktivnogo osadka yavlyaetsya prostoj funktsiej obshchej aktivnosti, kotoraya ostaetsya v obraztse posle abrazii na glubinu x{sub n}. EHtot vyvod yavlyaetsya rezul'tatom obobshcheniya formuly Gruzina, kotoraya do nastoyashchego vremeni primenyalas' tol'ko v ob{sup e}mnoj diffuzii. Takim obrazom my pokazali, chto mozhno putem izmereniya obshchej aktivnosti, ostayushchejsya v zavisimosti ot glubiny proniknoveniya razlichat' dolyu aktivnosti, kotoraya proiskhodit iz-za ob{sup e}mnoj samodiffuzii ot aktivnosti, proiskhodyashchej iz-za mezhgranulovoj samodiffuzii. Odnako tsennost' metoda zaklyuchaetsya v tom, chtoby prosledit' dal'she na tom zhe samom obraztse perekhod ob{sup e}mnoj samodiffuzii v mezhgranulovuyu samodiffuziyu. My primenili ehtot novyj metod dlya izmereniya konstant ob{sup e}mnoj samodiffuzii v zheleze u pri temperature 1260 Degree-Sign i 980 Degree-Sign C, a takzhe samodiffuzii na poverkhnosti granul pri temperature 1020 Degree-Sign i 918 Degree-Sign C. (author)}
place = {IAEA}
year = {1962}
month = {Jan}
}